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Citation: CHU Zhao-Hua, XIE Qing-Fan, CHEN Yan-Min. Synthesis, Crystal Structures and Properties of 1D Zinc(Ⅱ) Coordination Polymer {[Zn(H2O)2(L)(phen)]·3H2O}n[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1893-1896. doi: 10.3969/j.issn.1001-4861.2013.00.222 shu

Synthesis, Crystal Structures and Properties of 1D Zinc(Ⅱ) Coordination Polymer {[Zn(H2O)2(L)(phen)]·3H2O}n

  • 1.

    1 Department of Chemistry, Hanshan Normal University, Chaozhou, Guangdong 521041, China;

  • Received Date: 24 October 2012
    Available Online: 11 March 2013

    Fund Project: 广东省科技厅科技项目(No.2011B090400521) (No.2011B090400521)福建省科技厅科技项目(No.2008F5053)资助项目。 (No.2008F5053)

  • A zinc polymer {[Zn(H2O)2(L)(phen)]·3H2O}n (1, H2L=1-hydroxy-8-amino-naphthahne-3,6-disulfonic acid, phen=1,10-phenanthroline) has been synthesized and structurally characterized by elemental analysis, IR, UV, PL, TG and single crystal X-ray diffraction. The title complex crystallized in orthorhombic with space group Pnma, a=1.698 90(12) nm, b=0.661 88(11) nm, c=2.480 40(14) nm, V=2.789 1(5) nm3, Z=4, Mr=634.92, Dc=1.512 g·cm-3, the final R=0.058 6, wR=0.121 4 for 1 994 observed reflections (I>2σ(I)). In 1, L2- ligands bridge the six-coordinated zinc(Ⅱ) ions forming 1D chains, which are further connected by intermolecular hydrogen-bonding interactions, generating a 2D supramolecular network. Moreover, aromatic π-π stacking interactions between phenyl rings of L2- dianion and phenanthrolines were detected. CCDC: 900913.
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