Citation: LIU Guang-Xiang. Synthesis, Crystal Structure and Fluorescent Properties of a Cadmium(Ⅱ) Coordination Polymer Constructed from Camphor Acid and 1,3,5-Tris (imidazol-1-ylmethyl)-2,4,6-trimethylbenzene[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2251-2256. doi: 10.3969/j.issn.1001-4861.2013.00.210 shu

Synthesis, Crystal Structure and Fluorescent Properties of a Cadmium(Ⅱ) Coordination Polymer Constructed from Camphor Acid and 1,3,5-Tris (imidazol-1-ylmethyl)-2,4,6-trimethylbenzene

LIU Guang-Xiang

1.
School of Biochemical and Environmental Engineering, Nanjing Xiaozhuang University, Nanjing 211171, China

Received Date: 25 September 2012
Available Online: 5 February 2013
Fund Project: 国家自然科学基金(No.21271106) (No.21271106)教育部科学技术重点项目(No.210102)资助项目 (No.210102)

Anew three-dimensional coordination polymer of {[Cd₂(titmb)(CAM)₂]·2H₂O}_n (1) (H₂CAM=camphor acid, and titmb=1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene) has been prepared and characterized by elemental analysis, IR spectroscopy, TGAand single-crystal X-ray diffraction. The crystal is of monoclinic, space group Pl with a=1.23825(15) nm, b=1.30128(16) nm, c=1.53729(19) nm, α=91.351 (2)°, β=94.864 (3)°, γ=98.730 (2)°, V=2.4379(5) nm³, D_c=1.386 g·cm^-3, Z=2, F(000)=1040, Goof=1.027, R₁=0.0545, wR₂=0.1210. Complex 1 displays an unusual three-dimensional (3, 4, 6)-connected network with (4.6⁴.8)₂(4².6⁴.8⁹)(6².8)₂ topology. Moreover, their luminescent properties have been investigated in the solid state. CCDC: 834854.
- cadmium(Ⅱ) complex; hydrothermal synthesis; crystal structure; luminescence
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沈阳化工大学材料科学与工程学院沈阳 110142