Citation: ZHANG Fu-Xing, WANG Jian-Qiu, KUANG Dai-Zhi, FENG Yong-Lan, CHEN Zhi-Ming, XU Zhi-Feng, YU Jiang-Xi. Synthesis, Crystal Structure and Photoluminescence Properties of Dibenzyl Tin Complex with Salicylidene-2-aminophenol[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1442-1446. doi: 10.3969/j.issn.1001-4861.2013.00.206 shu

Synthesis, Crystal Structure and Photoluminescence Properties of Dibenzyl Tin Complex with Salicylidene-2-aminophenol

1.
Department of Chemistry and Material Science, Hengyang Normal University; Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hunan Province; Hengyang, Hunan 421008, China

Received Date: 24 August 2012
Available Online: 3 February 2013
Fund Project: 湖南省高校创新平台开放基金项目(No.12K124) (No.12K124)湖南省自然科学基金项目(No.11JJ3021) (No.11JJ3021)湖南省重点学科基金和湖南省高校重点实验室开放基金(No.11K01)资助项目。 (No.11K01)

Dibenzyl tin complex with salicylidene-2-aminophenol was synthesised by the reaction of dibenzyl tin dichloride with salicylidene-2-aminophenol Schiff Bases. The crystal structures have been determined by X-ray diffraction. It belongs to monoclinic system, space group P2₁/n with a=1.110 03(3) nm, b=1.719 87(5) nm, c=1.176 09(3) nm, β=100.564 0(10)°, V=2.207 23(10) nm³, Z=4, D_c=1.541 g·cm^-3, μ(Mo Kα)=11.81 cm^-1,F(000)= 1 023, R₁=0.026 8, wR₂=0.061 9. The tin atom is rendered five-coordination in a distorted tigonal bipyram idal-structure. The study on the title complex has been performed with quantum chemistry calculation. The stabilities, the orbital energies and composition characteristics of some frontier molecular orbitals of the complex have been investigated. The photoluminescent property of complexes was investigated. CCDC: 934721.
- organotin;crystal structure;quantum chemistry;fluorescence properties
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沈阳化工大学材料科学与工程学院沈阳 110142