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Citation: BIAN Chang-Xin, WANG Pu-Yu, SONG YU-Min, YAO Xiao-Qiang. Synthesis, Crystal Structure and Photoluminescence Property of a 3D Coordination Polymer [Cd(BIMB)0.5(glu)]n Constructed by 1,4-Bis(imidazol-1-yl)benzene and Glutaric Acid[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1369-1374. doi: 10.3969/j.issn.1001-4861.2013.00.205 shu

Synthesis, Crystal Structure and Photoluminescence Property of a 3D Coordination Polymer [Cd(BIMB)0.5(glu)]n Constructed by 1,4-Bis(imidazol-1-yl)benzene and Glutaric Acid

  • 1.

    Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China

  • Received Date: 3 November 2012
    Available Online: 16 February 2013

    Fund Project: 国家自然科学基金(No.21062017) (No.21062017)甘肃省教育厅(110105) (110105)

  • A new complex [Cd(BIMB)0.5(glu)]n based on rigid ligand BIMB (BIMB=1,4-bis(imidazol-1-yl)benzene) and flexible ligand H2glu (H2glu=glutaric acid) has been synthesized by hydrothermal method and characterized by IR and elemental analysis. The complex crystallizes in the monoclinic system P21/c space group, a=0.822 06(5) nm,b=0.774 38(5) nm, c=1.877 93(10) nm, β=107.966°, V=1.137 nm3, Z=4, F(000)=684. In complex, the adjacent Cd(Ⅱ) atoms are connected by two glu2-ligands to result in 1D chains, which are further linked by another glu2-ligand to generate a 2D layers, and the adjacent 2D layers are linked by BIMB ligand to result in a 3D framework. The TGA analysis shows the complex has good thermal stability. The fluorescence analysis reveals the complex has good fluorescence property. CCDC: 891527.
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