Citation: CHEN Shu-Yang, ZHAO Wei, GUO Ying-Chen. Hydrothermal Synthesis, Crystal Structure and Luminescence of a Iron Coordination Polymer with Terephthalate and o-Phenanthroline[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(6): 1165-1170. doi: 10.3969/j.issn.1001-4861.2013.00.201 shu

Hydrothermal Synthesis, Crystal Structure and Luminescence of a Iron Coordination Polymer with Terephthalate and o-Phenanthroline

1.
College of Chemistry and Pharmacy Engineering, Nanyang Normal University, Nanyang, Henan 473061, China

Received Date: 12 August 2012
Available Online: 12 February 2013
Fund Project: 河南省教育厅自然科学基金(No.2011B150025)资助项目。 (No.2011B150025)

A new coordination polymer [Fe(phen)(bdc)(H₂O)]_n has been hydrothermally synthesized and structurally characterized by elemental analysis, IR, UV-Vis, TG and single crystal X-ray diffraction analysis. It crystallizes in triclinic, space group P1, C₂₀H₁₄N₂FeO₅, with a=0.9308(6) nm, b=1.022 6(7) nm, c=1.134 1(5) nm,α=112.790(15)°, β=94.720(14)°, γ=113.417(10)°, V=0.876 9(9) nm³, Z=2, the final R₁=0.0346, wR₂=0.078 8. The Fe(Ⅱ) is coordinated with two nitrogen atoms and three oxygen atoms making a highly distorted trigonal bipyramidal. A 1D chain structure is constructed and further extended into a 3D structure through O-H…O intermolecular hydrogen bonding interactions. The polymer shows a fluorescence-emission at around 368 nm. CCDC: 894820.
- iron complex;crystal structure;luminescent property
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沈阳化工大学材料科学与工程学院沈阳 110142