Citation: HU Wen-Ting, ZHU Long-Guan. Study on the Synthesis, Crystal Structure and Catalytic Activity for Thioanisol of a Ruthenium Complex with 3-Sulfobenzoate and 2,2'-Bipyridine Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(6): 1109-1114. doi: 10.3969/j.issn.1001-4861.2013.00.191 shu

Study on the Synthesis, Crystal Structure and Catalytic Activity for Thioanisol of a Ruthenium Complex with 3-Sulfobenzoate and 2,2'-Bipyridine Ligands

1.
Department of Chemistry, Zhejiang University, Hangzhou 310027, China

Received Date: 15 November 2012
Available Online: 4 February 2013
Fund Project: 国家自然科学基金(No．21073157)资助项目。 (No．21073157)

The 2,2'-bipyridine-based ruthenium complex with sulfobenzoate ligand was synthesized, [Ru(2,2'-bipy)₃](3-Hsb)(3-sb)·5H₂O (1), where 2,2'-bipy is 2,2'-bipyridine and 3-sb^2- is 3-sulfobenzoate dianion, and characterized by elemental analysis, IR, UV-Vis, fluorescence spectrum, DTA-TG and single crystal X-ray analysis. The structural analysis showed that 1 is a cation-anion complex and the anions and water molecules form the three-dimensional hydrogen-bonding network with cavities occupied by cations. Cyclic voltammetry of 1 shows a one electron Ru(Ⅳ)/Ru(Ⅲ) reversible couple with E_1/2 of 1.350 V. The oxidation of thioanisol catalyzed by 1 together with the acid produced high yield and selectivity for the sulfoxide. CCDC: 910779.
- ruthenium complex;thioanisol;oxidation;crystal structure;cyclic voltammetry
1. [1]
  [1] Carreno M C. Chem. Rev., 1995,95:1717-1760
2. [2]
  [2] GAO Ai-Ping(高爱平), WANG Mei(王梅), WANG Dong- Ping(王东平), et al. Chin. J. Catal.(Cuihua Xuebao), 2006, 27:743-748
3. [3]
  [3] Romanelli G P, Villabrille P I, Caceres C V, et al. Catal. Commun., 2011,12:726-730
4. [4]
  [4] Shi X Y, Wei J F. J. Mol. Catal. A: Chem., 2008,280:142- 147
5. [5]
  [5] Shi X Y, Han X Y, Ma W J, et al. J. Mol. Catal. A: Chem., 2011,341:57-62
6. [6]
  [6] Maurya M R, Bisht M, Avecilla F. J. Mol. Catal. A: Chem., 2011,344:18-27
7. [7]
  [7] Maurya M R, Saini P, Haldar C, et al. Polyhedron, 2012,31: 710-720
8. [8]
  [8] Maurya M R, Chandrakar A K, Chand S. J. Mol. Catal. A: Chem., 2007,274:192-201
9. [9]
  [9] Maurya M R, Chandrakar A K, Chand S. J. Mol. Catal. A: Chem., 2007,278:12-21
10. [10]
  [10] Maurya M R, Saini P, Kumar A, et al. Eur. J. Inorg. Chem., 2011:4846-4861
11. [11]
  [11] Maurya M R, Singh B, Adao P, et al. Eur. J. Inorg. Chem., 2007:5720-5734
12. [12]
  [12] Lippold I, Vlay K, Gorls H, et al. J. Inorg. Biochem., 2009, 103:480-486
13. [13]
  [13] Maurya M R, Kumar M, Arya A. Cat. Commun., 2008,10: 187-191
14. [14]
  [14] Prasanth K L, Maheswaran H. J. Mol. Catal. A: Chem., 2007,268:45-49
15. [15]
  [15] Maurya M R, Arya A, Kumar A, et al. Dalton Trans., 2009: 2185-2195
16. [16]
  [16] Maurya M R, Kumar M, Kumar U. J. Mol. Catal. A: Chem., 2007,273:133-143
17. [17]
  [17] Dybtsev D N, Nuzhdin A L, Chun H, et al. Angew. Chem. Int. Ed., 2006,45:916-920
18. [18]
  [18] Miao X H, Zhu L G. CrystEngComm, 2009,11:2500-2509
19. [19]
  [19] Yuan R X, Xiong R G, Xie Y L, et al. Inorg. Chem. Commun., 2001,4:384-387
20. [20]
  [20] Thuery P. Cryst. Growth Des., 2012,12:1632-1640
21. [21]
  [21] Li X F, Huang Y B, Cao R. Dalton Trans., 2012,41:6195- 6205
22. [22]
  [22] Zheng X F, Zhu L G. Cryst. Growth Des., 2009,9:4407-4414
23. [23]
  [23] Zheng X F, Zhu L G. CrystEngComm, 2010,12:2878-2884
24. [24]
  [24] Zheng X F, Zhu L G. Polyhedron, 2011,30:666-675
25. [25]
  [25] Claustro I, Abate G, Sanchez E, et al. Inorg. Chim. Acta, 2003,342:28-36
26. [26]
  [26] SAINT, Version 6.02a, Bruker AXS Inc., Madison, WI, 2002.
27. [27]
  [27] Sheldrick G M. SHELXL-97, Program for Crystal Structure Refinement, University of Göttingen, Göttingen, Germany, 1997.
28. [28]
  [28] Farrugia L. J. Appl. Crystallogr., 1999,32:837
29. [29]
  [29] Spek A L. Acta Crystallogr., 2009,D65:148-155
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沈阳化工大学材料科学与工程学院沈阳 110142