Citation: TIAN Li, ZHOU Shang-Yong. Crystal Structures and Properties of Two Novel Copper Compounds Constructed from Bistriazole Methane[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(6): 1255-1262. doi: 10.3969/j.issn.1001-4861.2013.00.178 shu

Crystal Structures and Properties of Two Novel Copper Compounds Constructed from Bistriazole Methane

TIAN Li ,
ZHOU Shang-Yong

1.
Tianjin Key Laboratory of Structure and Performance for Functional Molecules; Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education; College of Chemistry, Tianjin Normal University, Tianjin 300387, China

Received Date: 6 July 2012
Available Online: 1 March 2013
Fund Project: 天津市自然科学基金(No.12JCZDJC27600)资助项目。 (No.12JCZDJC27600)

Using a flexible bis-triazole ligand bis(1,2,4-triazol-1-y1)metane (btm), two new copper(Ⅱ) coordination polymers [Cu_0.5(btm)Cl]_n (1) and [Cu(btm)Cl₂]_n (2) have been synthesized under hydrothermal conditions. The coordinating mode of chlorine anions can be tuned as a result of changing the metal/ligand ratio in the reaction system, which ultimately forms two novel structures. 1 possesses infinite 1D chain structure, and uncommonly four-fold Cl…H-C hydrogen bonds help the chains form a 3D supramolecular architecture. 2 features 2D (4.4) net framewok. Hydrogen bonds (Cl…H-C) reside among the 2D layers, which link the 2D layers to lead to a 3D supramolecular architecture. For 1 and 2, X-ray crystallography, elemental analysis, thermal stability and EPR spectra have been carried out. CCDC: 932333, 1; 932332, 2.
- Cu(Ⅱ) complex;crystal structure;bis(1,2,4-triazol-1-y1)metane
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