Citation: LV Xu-Yan, LIU Jian-Feng, LIU Yan, GAO Ling-Ling, XIAO Li-Qun, HU Tuo-Ping. Syntheses and Crystal Structures of Zn(Ⅱ) and Cd(Ⅱ) Complexes Based on 2,3,5,6-Tetrabromoterephthalic Acid and 1,3-Bis(4-pyridyl)propane[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(5): 1096-1102. doi: 10.3969/j.issn.1001-4861.2013.00.175 shu

Syntheses and Crystal Structures of Zn(Ⅱ) and Cd(Ⅱ) Complexes Based on 2,3,5,6-Tetrabromoterephthalic Acid and 1,3-Bis(4-pyridyl)propane

1.
Department of Chemistry, College of Science, North University of China, Taiyuan 030051, China

Corresponding author: HU Tuo-Ping,
Received Date: 26 July 2012
Available Online: 23 January 2013
Fund Project: 国家国际科技合作(No.2011DFA51980) (No.2011DFA51980)省自然科学基金(No.2011081022)资助项目。 (No.2011081022)

The complexes of [Zn(TBTA)(BPP)]_n (1) and [Cd(TBTA)(BPP)₂(H₂O)₂]_n (2) based on 2,3,5,6-tetrabromo-terephthalic acid (H₂TBTA) and 1,3-bis(4-pyridyl)propane (BPP) have been constructed in CH3OH/H₂O solution at room temperature. The structures and properties were characterized by the single-crystal X-ray diffraction, elemental analyses, IR spectra and thermogravimetric analyses. The results indicate the complex 1 is two dimension (2D) wave-like layer network, and the complex 2 is one dimension (1D) chain structure, and the carboxyl groups in H₂TBTA ligands coordinate with metal ions in monodentate mode, and the H-bonding interactions contribute to the stabilities of the structures of the complexes. CCDC: 854381, 1; 854380, 2.
- 2,3,5,6-tetrabromoterephthalic acid;1,3-bis(4-pyridyl)propane;Zn(Ⅱ) complex;Cd(Ⅱ) complex;H-bonding interactions
1. [1]
  [1] Surblé S, Serre C, Mellot-Draznieks C, et al. Chem. Commun., 2006,6:284-286
2. [2]
  [2] Yaghi O M, O'Keeffe M, Ockwig N W, et al. Nature, 2003, 423(6941):705-714
3. [3]
  [3] Huang Y G, Wu B L, Yuan D Q, et al. Inorg. Chem., 2007, 46(4):1171-1176
4. [4]
  [4] Wu C D, Hu A, Zhang L, et al. J. Am. Chem. Soc., 2005, 127(25):8940-8941
5. [5]
  [5] Gao X M, Li D S, Wang J J, et al. Cryst. Eng. Commun., 2008,10:479-482
6. [6]
  [6] Zhang J P, Chen X M. J. Am. Chem. Soc., 2008,130:6010- 6017
7. [7]
  [7] Kahn O. Acc. Chem. Res., 2000,33(10):647-657
8. [8]
  [8] Kesanli B, Lin W. Coord. Chem. Rev., 2003,246:305-326
9. [9]
  [9] Kitagawa S, Kitaura R, Noro S. Angew. Chem. Int. Ed., 2004,43(18):2334-2375
10. [10]
  [10] Le Bozec H, Le Bouder T, Maury O, et al. J. Opt. A. P : Pure Appl. Opt., 2002,4:S189-S196
11. [11]
  [11] Maury O, Le Bozec H. Acc. Chem. Res., 2005,38(9):691- 704
12. [12]
  [12] Evans O R, W Lin. Acc. Chem. Res., 2002,35(7):511-522
13. [13]
  [13] Liu Y L, Eubank J F, Cairns A J, et al. Angew. Chem. Int. Ed., 2007,46:3278-3283
14. [14]
  [14] Maspoch D, Ruiz-Molina D, Veciana J. Chem. Soc. Rev., 2007,36:770-818
15. [15]
  [15] Férey G. Chem. Soc. Rev., 2008,37(1):191-214
16. [16]
  [16] Kitagawa S, Matsuda R. Coord. Chem. Rev., 2007,251:2490 -2509
17. [17]
  [17] Hao H Q, Liu W T, Lin Z J, et al. CrystEngComm., 2009, 11:967-971
18. [18]
  [18] Ye B H, Tong M L, Chen X M. Coord. Chem. Rev., 2005, 249(5-6):545-565
19. [19]
  [19] Huang Y G, Yuan D Q, Pan L, et al. Inorg. Chem., 2007, 46:9609-9615
20. [20]
  [20] Hu S, Chen J C, Tong M L, et al. Angew. Chem. Int. Ed., 2005,44:5471-5475
21. [21]
  [21] An H Y, Wang E B, Xiao D R, et al. Angew. Chem. Int. Ed., 2006,45:904-908
22. [22]
  [22] Sun D F, Collins D J, Ke Y X, et al. Chem.-Eur. J., 2006, 12:3768-3776
23. [23]
  [23] Brammer L. Chem. Soc. Rev., 2004,33:476-489
24. [24]
  [24] Li X L, Chen K, Liu Y, et al. Angew. Chem, Int. Ed., 2007, 46(36):6820-6823
25. [25]
  [25] Du M, Li C P, Zhao X J. Cryst. Growth Des., 2006,6(1):335- 341
26. [26]
  [26] Li C P, Chen J, Du M. CrystEngComm., 2010,12:4392-4402
27. [27]
  [27] Li C P, Tian Y L, Guo Y M. Polyhedron, 2009,28:505-510
28. [28]
  [28] JIN Mei-Fang(靳梅芳), DAI Fang-Na(戴昉纳), SUN Dao- Feng(孙道峰). Chinese J. Struct. Chem.(Jiegou Huaxue), 2010,29(12):1834-1840
29. [29]
  [29] Sheldrick G M. SHELXS97, Program for the Solution of Crystal Structure, Germany: University of Gottingen, 1997.
30. [30]
  [30] Sheldrick G M. SHELXL97, Program for the Refinement of Crystal Structure, Germany: University of Gottingen, 1997.
31. [31]
  [31] Marinho M V, Yoshida M I, Guedes K J, et al. Inorg. Chem., 2004,43(4):1539-1544
32. [32]
  [32] Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordination Compounds. 5th Ed. New York: Wiley Inters- cience, 1997.
33. [33]
  [33] Miao M M, Liao D Z, Jiang Z H, et al. Transition Met. Chem., 1997,22(1):39-41
1. [1]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
2. [2]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
3. [3]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
4. [4]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
5. [5]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
6. [6]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
7. [7]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
8. [8]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
9. [9]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
10. [10]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
11. [11]
  Zongfei YANG , Xiaosen ZHAO , Jing LI , Wenchang ZHUANG . Research advances in heteropolyoxoniobates. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 465-480. doi: 10.11862/CJIC.20230306
12. [12]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
13. [13]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
14. [14]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
15. [15]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
16. [16]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
17. [17]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
18. [18]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
19. [19]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
20. [20]
  Xinyu ZENG , Guhua TANG , Jianming OUYANG . Inhibitory effect of Desmodium styracifolium polysaccharides with different content of carboxyl groups on the growth, aggregation and cell adhesion of calcium oxalate crystals. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1563-1576. doi: 10.11862/CJIC.20230374

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(150)
HTML views(0)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142