Citation:
JIANG Qi-Bai, JI Yi-Fei, SHEN Xu-Jie, YAN Hong. Synthesis and Characterization of Ni(Ⅱ) and Ir(Ⅰ) Complex with o-Carborane [O,P] or [O,O] Ligand[J]. Chinese Journal of Inorganic Chemistry,
;2013, 29(5): 910-914.
doi:
10.3969/j.issn.1001-4861.2013.00.168
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The reactions of o-carborane [P,P] ligand L1 with NiCl2(PPh3)2 and [IrCl(COD)]2 under an open atmosphere lead to two nido-carborane species 1 and 2 containing [O,P] or [O,O] ligands. All these complexes have been characterized by NMR, MS, IR and X-ray diffraction analyses. Complex 1 with solvent CHCl3 formed the normal Cl…H interaction and novel CH…π interaction. Complex 2 is the first Ir(Ⅰ) compound containing [O,P] o-carborane ligand. However, due to the difference of metal (Ni and Ir), the [P,P] ligand L1 was oxizided to novel [P,O] ligand and [O,O] ligand, respectively. CCDC: 927419, 1; 927420, 2.
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Keywords:
- carborane;nickel;iridium;[P,O] ligands
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