Citation: JIANG Qi-Bai, JI Yi-Fei, SHEN Xu-Jie, YAN Hong. Synthesis and Characterization of Ni(Ⅱ) and Ir(Ⅰ) Complex with o-Carborane [O,P] or [O,O] Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(5): 910-914. doi: 10.3969/j.issn.1001-4861.2013.00.168 shu

Synthesis and Characterization of Ni(Ⅱ) and Ir(Ⅰ) Complex with o-Carborane [O,P] or [O,O] Ligand

1.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering Nanjing University, Nanjing 210093, China

Corresponding author: YAN Hong,
Received Date: 4 January 2013
Available Online: 12 March 2013
Fund Project: 国家自然科学基金(No.20925104,21271102,21021062)资助项目。 (No.20925104,21271102,21021062)

The reactions of o-carborane [P,P] ligand L1 with NiCl₂(PPh₃)₂ and [IrCl(COD)]₂ under an open atmosphere lead to two nido-carborane species 1 and 2 containing [O,P] or [O,O] ligands. All these complexes have been characterized by NMR, MS, IR and X-ray diffraction analyses. Complex 1 with solvent CHCl₃ formed the normal Cl…H interaction and novel CH…π interaction. Complex 2 is the first Ir(Ⅰ) compound containing [O,P] o-carborane ligand. However, due to the difference of metal (Ni and Ir), the [P,P] ligand L1 was oxizided to novel [P,O] ligand and [O,O] ligand, respectively. CCDC: 927419, 1; 927420, 2.
- carborane;nickel;iridium;[P,O] ligands
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沈阳化工大学材料科学与工程学院沈阳 110142