Citation: XIANG Hua, JIANG Long, LI Huan-Yong, ZHENG Xiao-Dan, LI Yu. Synthesis, Structure and CD Spectra of Chiral Dinuclear Nickel(Ⅱ) Complex[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(5): 1084-1088. doi: 10.3969/j.issn.1001-4861.2013.00.165 shu

Synthesis, Structure and CD Spectra of Chiral Dinuclear Nickel(Ⅱ) Complex

XIANG Hua ^1,, ,
JIANG Long ² ,
LI Huan-Yong ² ,
ZHENG Xiao-Dan ² ,
LI Yu ^3,,

1.
1. Department of Media and Communication, Guangdong Industry Technical College, Guangzhou 510300, China;

Corresponding author: XIANG Hua, LI Yu,
Received Date: 1 August 2012
Available Online: 5 February 2013
Fund Project: 广东省高等学校高层次人才(No.2011QY01) (No.2011QY01)国家自然科学基金(No.21001119)资助项目。 (No.21001119)

L-[Ni₂(van)(Hvap)₂(MeOH)₂]ClO₄·2.5MeOH·H₂O (1) was prepared via the reaction of Ni(ClO₄)₂·H₂O with o-vanillin and L-2-amino-3-phenyl-1-propanol in the presence of triethylamine. The structure of 1 was characterized by elemental analysis, IR, TGA, solid-state CD spectra and single-crystal X-ray diffraction analyses. The X-ray diffraction analyses reveal that the complex crystallizes in the monoclinic chiral space group P2₁ with Z=1. Two nickel (Ⅱ) ions are bridged by the deprotonated o-vanillin molecule, forming a {Ni₂O} dinuclear structure. The solid-state CD spectra comfirm the chiral nature of 1. CCDC: 928211.
- chiral polynuclear complex;nickel(Ⅱ) complex;crystal structure;CD spectra
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沈阳化工大学材料科学与工程学院沈阳 110142