Citation: QIU Yan-Xuan, YANG Meng, YAN Hua, GAO Fei-Xian, OUYANG Zhen-Jie, DONG Wen. Hydrothermal Synthesis and Crystal Structure of Sm³⁺ Complex with Mononuclear Structure Based Bis(tetrazoly)amine Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(5): 1072-1076. doi: 10.3969/j.issn.1001-4861.2013.00.163 shu

Hydrothermal Synthesis and Crystal Structure of Sm³⁺ Complex with Mononuclear Structure Based Bis(tetrazoly)amine Ligand

1.
Department of Chemistry, Guangzhou University, Guangzhou 510006, China

Corresponding author: DONG Wen,
Received Date: 3 August 2012
Available Online: 1 March 2013
Fund Project: 国家自然科学基金(No.21271052)资助项目。 (No.21271052)

A new Sm³⁺ complex [Sm₂(BTA)₃·(H₂O)₁₀]·5H₂O (1) (H₂BTA=5, 5-bis(1H-tetrazoly)amine, CAS No. 127661-01-2) was synthesized by the hydrothermal reaction of SmCl₃·6H₂O and bis(tetrazoly)amine, and characterized by X-ray diffraction and elemental analysis. The crystal of 1 is triclinic with space group P1. In 1, two Sm³⁺ ions are coordinated to the chelated N atoms of BTA anions and water molecules to give two different mononuclear units with a distorted tetragonal antiprism structure. A 3D supermolecular structure is formed by three different intermolecular hydrogen bonding interactions of O-H…N, O-H…O and N-H…N in this complex. CCDC: 894688
- hydrothermal synthesis;coordination mode;H₂BTA;Sm³⁺ complex;crystal structure
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沈阳化工大学材料科学与工程学院沈阳 110142

Hydrothermal Synthesis and Crystal Structure of Sm3+ Complex with Mononuclear Structure Based Bis(tetrazoly)amine Ligand

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通讯作者: 陈斌, bchen63@163.com

Hydrothermal Synthesis and Crystal Structure of Sm³⁺ Complex with Mononuclear Structure Based Bis(tetrazoly)amine Ligand