Citation: ZHANG Dong-Teng, ZHU Ying-Ying, LUO Guang-Ming, CAI Hu. Synthesis and Characterization of Tert-butylimido Tetra-chloro Tantalum(Ⅴ) Anion Complex [IPrH]⁺[^tBuN=TaCl₄(py)]^-[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(5): 953-957. doi: 10.3969/j.issn.1001-4861.2013.00.162 shu

Synthesis and Characterization of Tert-butylimido Tetra-chloro Tantalum(Ⅴ) Anion Complex [IPrH]⁺[^tBuN=TaCl₄(py)]^-

1.
Department of Chemistry, Nanchang University, Nanchang 330031, China

Received Date: 18 April 2012
Available Online: 24 February 2013
Fund Project: 国家自然科学基金(No.20861007) (No.20861007)江西省教育厅基金(No.GJJ08026)资助项目。 (No.GJJ08026)

[IPrH]⁺[^tBuN=TaCl₄(py)]^- (1) (IPr=1,3-bis(2,6-diisoproylphenyl)imidazol-2-ylidene) was obtained unexpe-ctedly by the reaction of ^tBuN=TaCl₃(py)₂ and IPr. Complex 1 was structurally characterized by NMR, IR, fluores-cence spectra, elemental analysis and single-crystal X-ray diffraction. The crystal structure of 1 shows that the Ta(Ⅴ) center is octahedrally coordinated by four chlorides and two nitrogen atoms from imido and pyridyl ligands, respectively. CCDC: 873803.
- imido complex;N-heterocyclic-carbene;Ta complex;luminescence
1. [1]
  [1] Nugent W A, Mayer J M. Metal-Ligand Multiple Bonds. New York: Wiley, 1988.
2. [2]
  [2] Wigley D E. Progress in Inorganic Chemistry: Vol.42. New York: Wiley, 1994:239-482
3. [3]
  [3] Miguel G, Carlos G, Mannuel G, et al. Dalton Trans., 2011, 40:2797-2804
4. [4]
  [4] Ragone F, Poater A, Cavallo L, J. Am. Chem. Soc., 2010, 132:4249-4258
5. [5]
  [5] Gonzalez D C, Savariar E N, Thayumanavan S. J. Am. Chem. Soc., 2009,131:7708-7716
6. [6]
  [6] Marion N, Nolan S P. Acc. Chem. Res., 2008,41:1440-1449
7. [7]
  [7] Würtz S, Glorius F. Acc. Chem. Res., 2008,41:1523-1533
8. [8]
  [8] Xi Z, Liu B, Chen W. J. Org. Chem., 2008,73:3954-3957
9. [9]
  [9] Arrowsmith M, Hill M S, Kociok-Kohn G. Organometallics, 2009,28:1730-1738
10. [10]
  [10] John A, Ghosh P. Dalton Trans., 2010,39:7183-7260
11. [11]
  [11] WANG Zhi-Guo(王志国), BIAN Qing-Quan(边清泉), HUANG Bao-Mei(黄宝美), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012,28:191-194
12. [12]
  [12] CHEN Chao(陈超), QIU Hua-Yu(邱化玉), LIU Ai-Ling(刘爱玲), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27:1423-1430
13. [13]
  [13] Melaimi M, Soleilhavoup M, Bertrand G. Angew. Chem., Int. Ed., 2010,49:8810-8849
14. [14]
  [14] Markó I E, Stérin S, Buisine O, et al. Science, 2002,298: 204-206
15. [15]
  [15] Markó I E, Michaud G, Berthon-Gelloz G, et al. Adv. Synth. Catal., 2004,346:1429-1434
16. [16]
  [16] Mas-Marza E, Sanau M, Peris E. Inorg. Chem., 2005,44: 9961-9967
17. [17]
  [17] Dragutan V, Dragutan I, Delaude L, et al. Coord. Chem. Rev., 2007,251:765-794
18. [18]
  [18] Kandepi V V K M, Cardoso J M S, Peris E, et al. Organo- metallics, 2010,29:2777-2782
19. [19]
  [19] Jain K R, Herrmann W A, Kühn F E. Curr. Org. Chem., 2008,12:1468-1478
20. [20]
  [20] Herrmann W Α, Öfele K, Elison M, et al. J. Organomet. Chem., 1994,480:C7-C9
21. [21]
  [21] Kuhn N, Kratz T, Bläser D, et al. Inorg. Chim. Acta, 1995, 238:179-181
22. [22]
  [22] Abernethy C D, Codd G M, Spicer M D, et al. J. Am. Chem. Soc., 2003,125:1128-1129
23. [23]
  [23] Shukla P, Johnson J Α, Vidovic D, et al. Chem. Commun., 2004:360-361
24. [24]
  [24] Lorber C, Vendier L. Dalton Trans., 2009,35:6972-6984
25. [25]
  [25] Romain C, Miqueu K, Sotiropoulos J M, et al. Angew. Chem. Inter. Ed., 2010,49:2198-2201
26. [26]
  [26] Spencer L P, Beddle C, Hall M B, et al. J. Am. Chem. Soc., 2006,128:12531-12543
27. [27]
  [27] Willams D S, Korolev A V. Inorg. Chem., 1998,37:3809- 3819
28. [28]
  [28] Hintermann L, Beilstein J. Organomet. Chem., 2007,3:1-5
29. [29]
  [29] Jafarpour L, Stevens E D, Nolan S P. J. Organomet. Chem., 2000,606:49-54
30. [30]
  [30] Chiu H T, Chuang S H, Tsai C E, et al. Polyhedron, 1998, 17:2187-2190
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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Characterization of Tert-butylimido Tetra-chloro Tantalum(Ⅴ) Anion Complex [IPrH]+[tBuN=TaCl4(py)]-

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Characterization of Tert-butylimido Tetra-chloro Tantalum(Ⅴ) Anion Complex [IPrH]⁺[^tBuN=TaCl₄(py)]^-