Citation: MAO Yan, ZHANG Chuan-Hui, ZHANG Yang, WANG Qi, XU Gui-Liang, HUANG Ling, LI Jun-Tao, SUN Shi-Gang. Synthesis and Electrochemical Performance of Novel Expanded Graphite Oxide/Sulfur Composite Cathodes for Lithium-Sulfur Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(5): 889-895. doi: 10.3969/j.issn.1001-4861.2013.00.141 shu

Synthesis and Electrochemical Performance of Novel Expanded Graphite Oxide/Sulfur Composite Cathodes for Lithium-Sulfur Batteries

1.
Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005, China

Corresponding author: HUANG Ling,
Received Date: 1 December 2012
Available Online: 6 January 2013
Fund Project: 国家“973”计划(No.2009CB220102) (No.2009CB220102)国家基础科学人才培养计划(No.J1210014)资助项目。 (No.J1210014)

The expanded graphite oxides were prepared by modified Hummers method. The expanded graphite oxide/sulfur (E-GO/S) composites have been successfully prepared by a new chemical reaction method based on comproportionation in the acidic aqueous solution. FT-IR, XPS were characterized the existence of functional groups on the surface of expanded graphite oxide. XRD results showed that the as-prepared sulfur belongs to orthorhombic system. SEM and TEM results indicated the uniform distribution of the sulfur in the composite. The electrochemical test showed that the expanded graphite oxide/sulfur (E-GO/S) composites can deliver the highest discharge capacity of 1 020 mAh·g^-1 at the first cycle, after 100 cycles of charge-discharge, the discharge capacity of the composites keep the capacity of ca. 650 mAh·g^-1, and have the excellent rate performance and coulombic efficiency that may be attributed to the homogeneous distribution of sulfur in the composites and the chemical approach to fix sulfur and the lithium polysulfides via the chemical bonds with the functional groups on the surface of expanded graphite oxide.
- elemental sulfur;comproportionation;lithium-sulfur battery;expanded graphite oxide
1. [1]
  [1] Marmorstein D, Yu T H, Striebel K A, et al. J. Power Sources, 2000,89:219-226
2. [2]
  [2] Peled E, Gorenshtain A, Segal M, et al. J. Power Sources, 1989,26:269-271
3. [3]
  [3] Jin B, Kim J, Gu H, J. Power Sources, 2003,117:148-152
4. [4]
  [4] Liang C, Dudney N. J, Howe N. J, Chem. Mater., 2009,21: 4724-4730
5. [5]
  [5] Hassoun J, Scrosati B. Angew. Chem. Int. Ed., 2010,49:2371- 2374
6. [6]
  [6] Cheon S E, Ko K S, Cho J H, et al. J. Electrochem. Soc., 2003,150:A800-A805
7. [7]
  [7] Zheng G Y, YuanY, Cha J J, et al. Nano Lett., 2011,11:4462 -4467
8. [8]
  [8] WU Ying-Lei(伍英蕾), YANG Jun(杨军), WANG Jiu-Lin(王久林), et al. Acta. Phys.-Chim. Sin.(Wuli Huaxue Xuebao), 2010,26(2):283-290
9. [9]
  [9] Zheng W, Liu Y W, Hu X G, et al. Electro. Acta, 2006,51: 1330-1335
10. [10]
  [10] MA Ping(马萍), ZHANG Bao-Hong(张宝宏), XU Yu-Hong (徐宇虹), et al. Mod. Chem. Ind.(Xiandai Huagong), 2007, 27(3):30-33
11. [11]
  [11] Wang J, Chen J, Konstantinov K, et al. Electrochim. Acta, 2006,51:4634-4638
12. [12]
  [12] Liang X, Wen Z Y, Liu Y, et al. Solid State Ionics, 2011, 192:347-350
13. [13]
  [13] Ji X L, Lee K T, Nazar L F, Nat. Mater., 2009,8:500-506
14. [14]
  [14] Chen S R, Zhai Y P, Xu G L, et al. Electrochim. Acta, 2011,56:9549-9555
15. [15]
  [15] Wang J Z, Lu L, Choucairc M, et al. J. Power Sources, 2011,196:7030-7034
16. [16]
  [16] Aurbach D, Pollak E, Elazari R, et al. J. Electrochem. Soc., 2009,156:A694-A702
17. [17]
  [17] Liang X, Wen Z Y, Liu Y, et al. J. Power Sources, 2011, 196:9839-9843
18. [18]
  [18] Ji L W, Rao M, Zheng H M, et al. J. Am. Chem. Soc., 2011, 133:18522-18525
19. [19]
  [19] Hirata M, Gotou T, Horiuchi S, et al. Carbon, 2004,42:2929 -2937
20. [20]
  [20] Ji L, Tan Z, Kuykendall T R, et al. Phys. Chem. Chem. Phys., 2011,13:7170-7177
21. [21]
  [21] Ji F, Li Y L, Feng J M, et al. J. Mater. Chem., 2009,19: 9063-9067
22. [22]
  [22] Lee K R, Lee K U, Lee J W, et al. Electrochem. Commun., 2010,12:1052-1055
23. [23]
  [23] Tischer R P. Sulfur Electrode. New York: Academic Press, 1983:220
24. [24]
  [24] Wagner C D, Riggs W H, Davis L E, et al. A Reference Book of Standard Data for Use in X-ray Photoelectron Spectroscopy, Perkin Elmer Corp., Eden-Prairie, 1979.
25. [25]
  [25] Pietrzak R, Wachowska H, Fuel Processing Technology, 2006,87:1021-1029
26. [26]
  [26] Littlejohn D, Chang S G, J. Electron Spectrosc. Related Phenomena, 1995,71:47-50
27. [27]
  [27] Demir-Cakan R, Morcrette M, Nouar M, et al. J. Am. Chem. Soc., 2011,133:16154-16160
28. [28]
  [28] Sun M M, Zhang S C, Jiang T, et al. Electrochem. Commun., 2008,10:1819-1822
29. [29]
  [29] Aurbach D, Gamolsky K, Markovsky B, Electrochim. Acta, 2002,47:1423-1439
30. [30]
  [30] Wang Y X, Huang L, Sun L C,et al. J. Mater. Chem., 2012, 22:4744-4750
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沈阳化工大学材料科学与工程学院沈阳 110142