Citation: LI Cai-Yun, WANG Yong-Ming. Theoretical Analyses of Vacuum Ultraviolet Absorption Spectra of Ho³⁺ Doped in LiYF₄ Crystal[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 735-738. doi: 10.3969/j.issn.1001-4861.2013.00.136 shu

Theoretical Analyses of Vacuum Ultraviolet Absorption Spectra of Ho³⁺ Doped in LiYF₄ Crystal

1.
Department of Basic Course, the Armed Police Academy, Langfang, Hebei 065000, China

Received Date: 19 October 2012
Available Online: 27 November 2012

Spectral terms and J-spectral multiplet of low-spin 4f⁹5d configuration of Ho³⁺ were obtained with the method of ligand field theory. According to the selection rules for dipole transitions, the absorption spectra of Ho³⁺ doped in LiYF₄ in vacuum ultraviolet region (120~160 nm) of the spectrum were theoretically interpreted by applying the crystal field model, and the four main bands were assigned to the spin-allowed transitions from the ground state (⁵I₈) to J-spectral multiplet of low-spin 4f⁹5d configuration of Ho³⁺ ion.
- LiYF₄ crystal;Ho³⁺ ion;VUV absorption spectra;theoretical analysis
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Theoretical Analyses of Vacuum Ultraviolet Absorption Spectra of Ho3+ Doped in LiYF4 Crystal

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通讯作者: 陈斌, bchen63@163.com

Theoretical Analyses of Vacuum Ultraviolet Absorption Spectra of Ho³⁺ Doped in LiYF₄ Crystal