Citation: HU Wei-Ji, WU Xiao-Yong, LIU Jian-Feng, ZHAO Guo-Liang. Synthesis, Crystal Structure and Biological Activity of Lanthanum(Ⅲ) Coordination Polymer Constructed with p-Hydroxyphenylacetic Acid Anion[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 861-866. doi: 10.3969/j.issn.1001-4861.2013.00.134 shu

Synthesis, Crystal Structure and Biological Activity of Lanthanum(Ⅲ) Coordination Polymer Constructed with p-Hydroxyphenylacetic Acid Anion

1.
1 Zhejiang Normal University Xingzhi College, Jinhua, Zhejiang 321004, China;

Received Date: 8 September 2012
Available Online: 22 November 2012
Fund Project: 浙江省自然科学基金(No.Y4080256)资助项目。 (No.Y4080256)

A coordination polymer of {[La(HPAA)₃(H₂O)₂]·2(bipy)·H₂O}_n (1) (HHPAA=p-hydroxyphenylacetic acid, bipy=4,4′-bipyridine) was synthesized and characterized by elemental analysis, IR and TG-DTG. Its crystal structure was determined by single crystal X-ray diffraction method. The complex crystallizes in triclinic with space group P1, cell parameters: a=0.910 52(2) nm, b=1.284 78(3) nm, c=1.958 69(4) nm, α=78.586 0(1)°, β=76.656 0(1)°, γ=73.097 0(1)°, cell volume: V=2.111 98(8) nm³, number of molecules inside the cell: Z=2, relative molecular mass: M_r=958.73. The La(Ⅲ) cation is coordination with oxygen atoms from p-hydroxyphenylacetic acid anions and water molecules, forming a distorted two-capped square antiprism coordination geometry. The adjacent La(Ⅲ) clusters linked by carboxylic groups are connected by HPAA^- to form a 1D chain, and the bipyridine is uncoordinated to La(Ⅲ) center. Moreover, the interaction of complex with DNA was also studied by ethidium bromide (EB) fluorescence spectroscopy. CCDC: 900442.
- La(Ⅲ) complex;p-hydroxyphenylacetic acid;crystal structure;DNA
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沈阳化工大学材料科学与工程学院沈阳 110142