Citation: SUN Zhen, GUO Jia, YU Jian-Guo, HUANG Hua, CHEN Juan, LI Guo-Dong, ZHAO Yong-Nan. Preparation and Photoluminescence Properties of Perovskite BaZr1-xAlxO3 (x=0~0.08) Hollow Microspheres[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(5): 936-940. doi: 10.3969/j.issn.1001-4861.2013.00.131
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BaZr1-xAlxO3 (x=0~0.08) hollow microspheres with different Al contents were synthesized by hydrothermal method. The samples were characterized by XRD, SEM, TEM, PL, FTIR. XRD data indicated that Al3+ was successfully introduced into the lattice and replaced the Zr4+ cation at B position. Replacing Zr4+ by Al3+ aroused the decrease of cell parameters. TEM observations confirmed the hollow feature and gave a mean particle size of 150 nm. When excited by 355 nm laser, all of the hollow microspheres emitted 423 nm violet light at room temperature. Compared with that of pure BaZrO3, the cell shrinkage that stemmed from Al3+ doping directed to weakened photoluminescence. The non-equivalent doping also led to the variation of oxygen vacancies, which directed to a slightly enhanced photoluminescence with Al3+ doping contents in the range of 1% to 2%.
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