Citation: HU Jin-Song, LIU Xi-Hui, SHI Jian-Jun, XING Hong-Long, HE Jie. Structure and Fluorescence Property of 2D Bilayer Zn(Ⅱ) Coordination Polymer Induced by H-Bonding and π-π Interaction[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(3): 444-448. doi: 10.3969/j.issn.1001-4861.2013.00.130
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Solvothermal reaction of 1,3-dipyridyl benzene (1,3-dpb) with 4,4'-oxybis(benzoic acid) (H2oba) produced a two dimensional (2D) zinc(Ⅱ) coordination polymer {[Zn(oba)(dpb)]·H2O}n (1). The complex was characterized by elemental analysis, IR spectroscopy, and X-ray single-crystal diffraction. It crystallizes in the monoclinic system, space group C2/c. The neighboring Zn(Ⅱ) ions are linked by oba2- anions and 1,3-dpb to form infinitely 2D sheet, two 2D sheets are interlocked each other to form 2D→2D structure, and these two 2D sheets were linked each other by H-bonding. Two groups of interlocked structures further linked to form bilayer 2D supermolecule network by π-π interaction. In addition, the fluorescence property of 1 was also studied. CCDC: 917714.
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