Citation: WANG Zheng, ZHOU Gang, GAN Yun, ZHANG Dun-Ming. Synthesis of a Carboxyl-Containing Silicone and Its Curing Kinetics[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 810-816. doi: 10.3969/j.issn.1001-4861.2013.00.129 shu

Synthesis of a Carboxyl-Containing Silicone and Its Curing Kinetics

1.
School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Received Date: 15 October 2012
Available Online: 14 December 2012

A new carboxyl-containing silicone (CCS) was synthesized by condensation reaction of chloropropylmethylsiloxane and excess amount of terephthalic acid. The CCS cured with a bisphenol A type epoxy resin, and the kinetics of curing reaction of the CCS/epoxy resin composites was investigated by employing differential scanning calorimetry (DSC) basing on the Kissinger′s and Crane′s approaches. As a result, the apparent activation energy and reaction order of the curing reaction are 71.41 kJ·mol^-1 and 0.911, respectively. The curing kinetic equation at a heating rate of 10℃·min^-1 was given.
- silicones;composites;crosslinking;differential scanning calorimetry (DSC);activation energy
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沈阳化工大学材料科学与工程学院沈阳 110142