Citation: WANG Zheng, ZHOU Gang, GAN Yun, ZHANG Dun-Ming. Synthesis of a Carboxyl-Containing Silicone and Its Curing Kinetics[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 810-816. doi: 10.3969/j.issn.1001-4861.2013.00.129 shu

Synthesis of a Carboxyl-Containing Silicone and Its Curing Kinetics

1.
School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Received Date: 15 October 2012
Available Online: 14 December 2012

A new carboxyl-containing silicone (CCS) was synthesized by condensation reaction of chloropropylmethylsiloxane and excess amount of terephthalic acid. The CCS cured with a bisphenol A type epoxy resin, and the kinetics of curing reaction of the CCS/epoxy resin composites was investigated by employing differential scanning calorimetry (DSC) basing on the Kissinger′s and Crane′s approaches. As a result, the apparent activation energy and reaction order of the curing reaction are 71.41 kJ·mol^-1 and 0.911, respectively. The curing kinetic equation at a heating rate of 10℃·min^-1 was given.
- silicones;composites;crosslinking;differential scanning calorimetry (DSC);activation energy
1. [1]
  [1] May C A. Epoxy resins chemistry and technology. New York: Marcel Dekker, 1988.
2. [2]
  [2] Kinjo N, Ogata M, Nishi K, et al. Adv. Polym. Sci., 1989,88: 1-48
3. [3]
  [3] Chiu Y S, Liu Y L, Wei W L, et al. J. Polym. Sci., Part A, 2003,41:432-440
4. [4]
  [4] Zheng S X, Wang H Q, Dai Q Z, et al. Macromol. Chem. Phys., 1995,196:269-278
5. [5]
  [5] Crivello J V, Narayan R. Macromolecules, 1996,29:433-438
6. [6]
  [6] Agag T, Takeichi T. Polymer, 1999,40:6557-6563
7. [7]
  [7] Park S J, Kim H C, Lee H I, et al. Macromolecules, 2001,34:7573-7575
8. [8]
  [8] Kim W G, Nam T Y. J. Polym. Sci. Part A, 1996,34:957-962
9. [9]
  [9] Musto P, Martuscelli E, Ragosta G, et al. J. Appl. Polym. Sci., 1998,69:1029-1042
10. [10]
  [10] Lee T M, Ma C M, Hsu C W, et al. J. Appl. Polym. Sci., 2006,99:3491-3499
11. [11]
  [11] Tao Z Q, Yang S Y, Chen J S, et al. Eur. Polym. J., 2007, 43:1470-1479
12. [12]
  [12] Zou H, Wu S S, Shen J. Chem. Rev., 2008,108:3893-3957
13. [13]
  [13] Crivello J V, Song K Y, Ghoshal R. Chem. Mater., 2001,13: 1932-1942
14. [14]
  [14] Cho Y H, Shin C W, Kim N, et al. Chem. Mater., 2005,17: 6263-6271
15. [15]
  [15] Grunlan M A, Lee N A, Cai G, et al. Chem. Mater., 2004, 16:2433-2441
16. [16]
  [16] ZHANG Pei-Pei(张培培), CHEN You-Shuang(陈有双), TANG Zhong-Feng(唐忠锋). Polym. Bull.(Gaofenzi Tongbao), 2010,(12):84-89
17. [17]
  [17] LI Xiao-Ru(李晓茹), CONG Li-Xiao(丛丽晓), ZHANG Sheng-You(张圣有), et al. Silicone Mater. (Youjigui Cailiao), 2005,19(5):33-36
18. [18]
  [18] Wang Z, Jiang J, Zhang D M, et al. J. Appl. Polym. Sci., 2012,123:2485-2491
19. [19]
  [19] Wang W J, Perng L H, Hsiue G H, et al. Polymer., 2000,41: 6113-6122
20. [20]
  [20] Hsiue G G, Wang W J, Chang F C. J. Appl. Polym. Sci., 1999,73:1231-1238
21. [21]
  [21] Tian S B, Pak Y S, Xu G. J. Polym. Sci., Part B, 1994,32: 2019-2023
22. [22]
  [22] Kambour R P. J. Appl. Polym. Sci., 1981,26:861-877
23. [23]
  [23] Lee S S, Kim S C. J. Appl. Polym. Sci., 1997,64:941-955
24. [24]
  [24] Kissinger H E. Analy. Chem., 1957,29:1702-1706
25. [25]
  [25] Crane L W, Dynes P J, Kaelble D H. J. Polym. Sci, Polym. Lett. Ed., 1973,11:533-540
26. [26]
  [26] Sheng X, Akinc M, Kessler M R. J. Thermal. Anal. Calorim., 2008,93:77-85
1. [1]
  Hongxia Yan , Rui Wu , Weixu Feng , Yan Zhao , Yi Yan . Innovation Inspired by Classical Chemistry: Luminescent Hyperbranched Polysiloxanes. University Chemistry, 2025, 40(4): 154-159. doi: 10.12461/PKU.DXHX202409010
2. [2]
  Fa Wang , Yu Chen , Hui Chao . Ruthenium(II) Complexes as Photoactivated Chemo-Prodrugs for Hypoxic Tumor Therapy. University Chemistry, 2025, 40(7): 200-212. doi: 10.12461/PKU.DXHX202410024
3. [3]
  Zongfei YANG , Xiaosen ZHAO , Jing LI , Wenchang ZHUANG . Research advances in heteropolyoxoniobates. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 465-480. doi: 10.11862/CJIC.20230306
4. [4]
  Tingting Yu , Si Chen , Lianglong Sun , Tongtong Shi , Kai Sun , Xin Wang . Comprehensive Experimental Design for the Photochemical Synthesis, Analysis, and Characterization of Difluoropyrroles. University Chemistry, 2024, 39(11): 196-203. doi: 10.3866/PKU.DXHX202401022
5. [5]
  Meiyu Lin , Yuxin Fang , Songzhang Shen , Yaqian Duan , Wenyi Liang , Chi Zhang , Juan Su . Exploration and Implementation of a Dual-Pathway Blended Teaching Model in General Chemistry Experiment Course: A Case Study of Copper Glycine Synthesis and Its Thermal Analysis. University Chemistry, 2024, 39(8): 48-53. doi: 10.3866/PKU.DXHX202312042
6. [6]
  Xinxin YU , Yongxing LIU , Xiaohong YI , Miao CHANG , Fei WANG , Peng WANG , Chongchen WANG . Photocatalytic peroxydisulfate activation for degrading organic pollutants over the zero-valent iron recovered from subway tunnels. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 864-876. doi: 10.11862/CJIC.20240438
7. [7]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
8. [8]
  Jinfeng Chu , Yicheng Wang , Ji Qi , Yulin Liu , Yan Li , Lan Jin , Lei He , Yufei Song . Comprehensive Chemical Experiment Design: Convenient Preparation and Characterization of an Oxygen-Bridged Trinuclear Iron(III) Complex. University Chemistry, 2024, 39(7): 299-306. doi: 10.3866/PKU.DXHX202310105
9. [9]
  Xin Han , Zhihao Cheng , Jinfeng Zhang , Jie Liu , Cheng Zhong , Wenbin Hu . Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2025, 41(4): 100033-. doi: 10.3866/PKU.WHXB202404023
10. [10]
  Zufeng Qiu , Jie Ouyang , Yiru Wang , Hengting Yang , Xin Liao , Chi Zhang , Xuanyao Jiang , Shunliu Deng , Zhiwei Lin . 综合运用分析仪器解析“盲盒”样品——未知物的剖析. University Chemistry, 2025, 40(6): 296-302. doi: 10.12461/PKU.DXHX202405167
11. [11]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
12. [12]
  Simin Fang , Hong Wu , Wei Liu , Wei Wei , Hongyan Feng , Wan Li . Construction and Application of Teaching Resources for Inorganic and Analytical Chemistry Experimental Course in the Context of Digital Empowerment. University Chemistry, 2024, 39(10): 156-163. doi: 10.3866/PKU.DXHX202402053
13. [13]
  Jiaxun Wu , Mingde Li , Li Dang . The R eaction of Metal Selenium Complexes with Olefins as a Tutorial Case Study for Analyzing Molecular Orbital Interaction Modes. University Chemistry, 2025, 40(3): 108-115. doi: 10.12461/PKU.DXHX202405098
14. [14]
  Liangliang Song , Haoyan Liang , Shunqing Li , Bao Qiu , Zhaoping Liu . Challenges and strategies on high-manganese Li-rich layered oxide cathodes for ultrahigh-energy-density batteries. Acta Physico-Chimica Sinica, 2025, 41(8): 100085-0. doi: 10.1016/j.actphy.2025.100085
15. [15]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
16. [16]
  Hongbo Zhang , Yihong Tang , Suxia Zhang , Yuanting Li . Electrochemical Monitoring of Photocatalytic Degradation of Phenol Pollutants: A Recommended Comprehensive Analytical Chemistry Experiment. University Chemistry, 2024, 39(6): 326-333. doi: 10.3866/PKU.DXHX202310013
17. [17]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
18. [18]
  Hexing SONG , Zan SUN . Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe³⁺ of an Mn(Ⅱ) complex based on 1-naphthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 885-892. doi: 10.11862/CJIC.20240402
19. [19]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023
20. [20]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(463)
HTML views(61)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142