Citation: LIU Ning. Influence of ZnCl2 Activation on Structure and Electrochemical Performance of Carbon Aerogel Spheres[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(3): 551-556. doi: 10.3969/j.issn.1001-4861.2013.00.123 shu

Influence of ZnCl2 Activation on Structure and Electrochemical Performance of Carbon Aerogel Spheres

  • Received Date: 31 October 2012
    Available Online: 7 December 2012

    Fund Project: 新型聚合物材料设计合成与应用广东省高校重点实验室课题(No.0110106) (No.0110106)广东省中医药局科研项目(No.2010416)资助项目。 (No.2010416)

  • Carbon aerogel spheres were activated by zinc chloride (ZnCl2), and the activated products were made into the electrodes of supercapacitor. The pore structure of carbon aerogel spheres was investigated by SEM and N2 adsorption. The electrochemical properties were tested by cyclic voltammetry (CV), AC impedance and constant current charge/discharge methods. The experimental results showed that the pore structure of carbon aerogel spheres was improved after ZnCl2 activation, then the surface area and porosity were increased through the increasing of micropore surface area and volume. Consequently the capacitance properties of the prepared electrodes were enhanced, the resistance decreased and the capacitance were increased twice.
  • 加载中
    1. [1]

      [1] Jurewicz K, Vix-Guterl C, Frackowiak E, et al. J. Phys. Chem. Solids, 2004,65(2/3):287-293

    2. [2]

      [2] Raymundo-Pinero E, Leroux F, Beguin F. Adv. Mater., 2006, 18(14):1877-1882

    3. [3]

      [3] Obreja V V N. Physica E, 2008,40(7):2596-2605

    4. [4]

      [4] Dong B, He B L, Xu C L, et al. Mater. Sci. Eng. B, 2007, 143(1-3):7-13

    5. [5]

      [5] SI Wei-Jiang(司维江), SUN Feng-Jiang(孙丰江), YUAN Xun (袁勋), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(2):219-225

    6. [6]

      [6] Hanzawa Y, Kaneko K, Pekala R W, et al. Langmuir, 1996, 12(26):6167-6169

    7. [7]

      [7] Wu D C, Fu R W, Dresselhaus M S, et al. Carbon, 2006,44 (4):675-681

    8. [8]

      [8] Zhu Y D, Hu H Q, Li W C, et al. J. Power Sources, 2006, 162(1):738-742

    9. [9]

      [9] Wu D C, Sun Z Q, Fu R W. J. Appl. Polym. Sci., 2006,99 (5):2263-2267

    10. [10]

      [10] Liu N, Zhang S T, Fu R W, et al. Carbon, 2006,44(12):2430-2436

    11. [11]

      [11] Liu N, Zhang S T, Fu R W, et al. J. Appl. Polym. Sci., 2007,104(5):2849-2855

    12. [12]

      [12] ZHANG Wen-Feng(张文峰), CAO Gao-Ping(曹高萍), DING Yu-Zhen(丁玉珍), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2007,23(4):698-702

    13. [13]

      [13] LIU Chun-Ling(刘春玲), WEN Yue-Hua(文越华), CHENG Jie(程杰), et al. Acta Phys.-Chim. Sin.(Wuli Huaxue Xuebao), 2005, 21(7):786-791

    14. [14]

      [14] Maciá-Agulló J A, Moore B C, Czzorla-Amorós D, et al. Carbon, 2004,42(7):1367-1370

    15. [15]

      [15] XU Bing(徐斌), WU Feng(吴峰), CAO Gao-Ping(曹高萍), et al. New Carbon Mater.(Xinxing Tan Cailiao), 2006,21(1): 14-18

    16. [16]

      [16] ZHOU De-Feng(周德凤), ZHAO Yan-Ling(赵艳玲), MA Yue(马越), et al. Acta Chim. Sinica(Huaxue Xuebao), 2004, 62(14):1333-1338

    17. [17]

      [17] Yue Z R, Christian L M, James E. Carbon, 2002,40(8):1181-1191

    18. [18]

      [18] Liou T H. Chem. Eng. J., 2010,158(2):129-142

    19. [19]

      [19] Jagtoyen M, Derbyshire F. Carbon, 1998,36(7-8):1085-1097

    20. [20]

      [20] XIE Chun-Lin(谢春林), LIU Ying-Liang(刘应亮), SUN Li-Xian(孙立贤), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(12):2395-2400

    21. [21]

      [21] FU Xiao-Ting(付晓亭), JIA Fan(贾凡), LI Wen-Bin(李文 斌), et al. Acta Phys.-Chim. Sin.(Wuli Huaxue Xuebao), 2012,28(8):1906-1912

    22. [22]

      [22] Wang D W, Li F, Chen Z G, et al. Chem. Mater., 2008,20 (22):7195-7200

    23. [23]

      [23] Chmiola J, Yushin G, Gogotsi, Y, et al. Science, 2006,313 (5794):1760-1763

    24. [24]

      [24] Caturla F, Molina-Sabio M, Rodriguez-Reinoso F. Carbon, 1991,29(7):999-1007

    25. [25]

      [25] Ibarra J V, Molinera R, Palacios J M. Fuel, 1991,70(6):727-732

  • 加载中
    1. [1]

      Jiahong ZHENGJiajun SHENXin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO4/NiMoS4 composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253

    2. [2]

      Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)2. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108

    3. [3]

      Zhaomei LIUWenshi ZHONGJiaxin LIGengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404

    4. [4]

      Qi Li Pingan Li Zetong Liu Jiahui Zhang Hao Zhang Weilai Yu Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030

    5. [5]

      Yanhui XUEShaofei CHAOMan XUQiong WUFufa WUSufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183

    6. [6]

      Xinpeng LIULiuyang ZHAOHongyi LIYatu CHENAimin WUAikui LIHao HUANG . Ga2O3 coated modification and electrochemical performance of Li1.2Mn0.54Ni0.13Co0.13O2 cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488

    7. [7]

      Peng ZHOUXiao CAIQingxiang MAXu LIU . Effects of Cu doping on the structure and optical properties of Au11(dppf)4Cl2 nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047

    8. [8]

      Zhihuan XUQing KANGYuzhen LONGQian YUANCidong LIUXin LIGenghuai TANGYuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447

    9. [9]

      Qin ZHUJiao MAZhihui QIANYuxu LUOYujiao GUOMingwu XIANGXiaofang LIUPing NINGJunming GUO . Morphological evolution and electrochemical properties of cathode material LiAl0.08Mn1.92O4 single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022

    10. [10]

      Qingtang ZHANGXiaoyu WUZheng WANGXiaomei WANG . Performance of nano Li2FeSiO4/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115

    11. [11]

      Yuanchao LIWeifeng HUANGPengchao LIANGZifang ZHAOBaoyan XINGDongliang YANLi YANGSonglin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn0.8Fe0.2PO4/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252

    12. [12]

      Maitri BhattacharjeeRekha Boruah SmritiR. N. Dutta PurkayasthaWaldemar ManiukiewiczShubhamoy ChowdhuryDebasish MaitiTamanna Akhtar . Synthesis, structural characterization, bio-activity, and density functional theory calculation on Cu(Ⅱ) complexes with hydrazone-based Schiff base ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1409-1422. doi: 10.11862/CJIC.20240007

    13. [13]

      Lu XUChengyu ZHANGWenjuan JIHaiying YANGYunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431

    14. [14]

      Hongyi LIAimin WULiuyang ZHAOXinpeng LIUFengqin CHENAikui LIHao HUANG . Effect of Y(PO3)3 double-coating modification on the electrochemical properties of Li[Ni0.8Co0.15Al0.05]O2. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480

    15. [15]

      Wen LUOLin JINPalanisamy KannanJinle HOUPeng HUOJinzhong YAOPeng WANG . Preparation of high-performance supercapacitor based on bimetallic high nuclearity titanium-oxo-cluster based electrodes. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 782-790. doi: 10.11862/CJIC.20230418

    16. [16]

      Yingchun ZHANGYiwei SHIRuijie YANGXin WANGZhiguo SONGMin WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078

    17. [17]

      Tiantian MASumei LIChengyu ZHANGLu XUYiyan BAIYunlong FUWenjuan JIHaiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351

    18. [18]

      Jing SUBingrong LIYiyan BAIWenjuan JIHaiying YANGZhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414

    19. [19]

      Xiaoning TANGJunnan LIUXingfu YANGJie LEIQiuyang LUOShu XIAAn XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191

    20. [20]

      Yonghui ZHOURujun HUANGDongchao YAOAiwei ZHANGYuhang SUNZhujun CHENBaisong ZHUYouxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373

Metrics
  • PDF Downloads(542)
  • Abstract views(502)
  • HTML views(7)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address:Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return