Citation: FENG Guo-Dong, JIANG Luan, YANG De-Suo, CHEN Qiang, WANG Min-Juan, LUO Xiao-Lin, ZHAO Wei-Xing, LI Zong-Xiao. Synthesis, Structure, and Luminescent Property of a Cobalt (Ⅱ) Compound with a 1D Double-Zigzag Chain Structure Using Rigid Aromatic Dicarboxylate Acids and Flexible Bis(2-benzimidazolyl)alkanes Linkers[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 831-837. doi: 10.3969/j.issn.1001-4861.2013.00.116
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By using the bis(2-benzimidazolyl)alkanes as the N-donor ligand and 1,4-benzenedicarboxylic acid as the second metal linker, a novel cobalt(Ⅱ) compound with a 1D double-zigzag chain structure, namely, [Co(BDC)(H2C3PIm)(H2O)]n (1) (H2C3PIm=2,2-(1,3-propanediyl)-bis(1H-benzimidazole), BDC=1,4-benzenedicarboxylic acid) has been synthesized under hydrothermal conditions and characterized by elemental analysis, thermal analysis, X-ray single-crystal diffraction. The crystal belongs to the orthorhombic system, space group Pca21 with a=1.488 6(5) nm, b=1.791 7(5) nm, c=1.894 3(5) nm, V=5.052(3) nm3, Dc=1.360 g·cm-3, Z=8, F(000)=2 136, Goof=0.986, R1=0.042 5, wR2=0.068 7. In compound 1, the distorted tetrahedral Co(Ⅱ) ion is bridged by the carboxylic oxygen atoms of the BDC ligand and chelated by the nitrogen atoms of the H2C3PIm ligand. Owning to the different of the distorted angles from the BDC ligand, the compound units are linked into 1D double-zigzag chain structure (mode A; mode B) via the C-H…π interactions and N-H…O, O-H…O hydrogen bonding between uncoordinated carboxylate and the nitrogen atoms of H2C2EIm as well as the free water molecules and further extended into a 3D supramolecular structure through the intermolecular hydrogen bonds between the adjacent A and the adjacent B zigzag chains. The luminescent property of compound 1 has also been studied. CCDC: 839239.
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