Citation: GONG Wei, NIU Qiong, NIU He-Lin, HU Lin, MAO Chang-Jie, SONG Ji-Ming, ZHANG Sheng-Yi, ZHENG Jun, CHEN Qian-Wang. Synthesis, Structure and Properties of a Porous Ni(Ⅱ) Coordination Polymer Constructed from 1,1'-(1,4-Butanediyl)bis(imidazole) and o-Phthalate Acid[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(3): 642-648. doi: 10.3969/j.issn.1001-4861.2013.00.115 shu

Synthesis, Structure and Properties of a Porous Ni(Ⅱ) Coordination Polymer Constructed from 1,1'-(1,4-Butanediyl)bis(imidazole) and o-Phthalate Acid

1.
1. College of Chemistry & Chemical Engineering, Anhui University, Hefei 230039, China;

Received Date: 29 April 2012
Available Online: 23 October 2012
Fund Project: 国家自然科学基金(Nos.20905001, 21071002) (Nos.20905001, 21071002)安徽省自然科学基金(Nos.KJ2010A014) 和安徽大学“211”创新团队资助项目。 (Nos.KJ2010A014)

A coordination polymer [Ni(Pht)(bbim-4)]_n (Pht=o-phthalate acid anion,bbim-4=1, 1'-(1, 4-butanediyl)bis(imidazole) was synthesized by hydrothermal reaction and characterized by elemental analysis, powder X-ray diffraction, TGA and X-ray single crystal diffraction. The crystal belongs to monoclinic system, space group C2/c. Coordination polymer [Ni(Pht)(bbim-4)]_n is a three-dimensional porous coordination polymer with triangular channels. The coordination polymer shows an overall ferromagnetic behavior. Gas sorption studies suggest that the coordination polymer has selectivity in adsorption of N₂ and CO₂ gas. CCDC: 818068.
- nickel coordination polymer;1, 1'-(1,4-butanediyl)bis(imidazole);o-phthalate acid anion;hydrothermal synthesis;crystal structure;gas sorption
1. [1]
  [1] Xue D X, Lin Y Y, Cheng X N, et al. Cryst. Growth Des., 2007,7(7):1332-1336
2. [2]
  [2] Zhu A X, Lin J B, Zhang J P, et al. Inorg. Chem., 2009,48: 3882-3889
3. [3]
  [3] Shimomura S, Horike S, Matsuda R, et al. J. Am. Chem. Soc., 2007,129:10990
4. [4]
  [4] Millward A R, Yaghi O M. J. Am. Chem. Soc., 2005,127: 1799817999
5. [5]
  [5] Furukawa H, Yaghi O M. J. Am. Chem. Soc., 2009,131:8875-8883
6. [6]
  [6] Noro S I, Kitagawa S, Nakamura T, et al. Inorg. Chem., 2005, 44:39603971
7. [7]
  [7] Wen L L, Lu Z D, Ren X M, et al. Cryst. Growth Des., 2009, 1:227-238
8. [8]
  [8] Notash B, Safari N, Khavasi H R. Inorg. Chem., 2010,49: 11415-11420
9. [9]
  [9] Chen J X, Ohba M, Zhao D Y, et al. Cryst. Growth Des., 2006,6(3):664-668
10. [10]
  [10] Zheng P Q, Ren Y P, Long L S, et al. Inorg. Chem., 2005,44:1190-1192
11. [11]
  [11] Zingiryan A, Zhang J, Bu X H. Inorg. Chem., 2008,47: 8607-8609
12. [12]
  [12] Kathalikkattil A C, Bisht K K, Alcalde N A, et al. Cryst. Growth Des., 2011,11:1631-1641
13. [13]
  [13] Wei G H, Yang J, Ma J F, et al. Dalton Trans., 2008:3038-3039
14. [14]
  [14] Zhang L P, Ma J F, Pang Y Y, et al. CrystEngComm, 2010,12:4433-4442
15. [15]
  [15] Zhang L P, Ma J F, Yang J, et al. Cryst. Growth Des., 2009,11:4660-4673
16. [16]
  [16] Zhang W L, Liu Y Y, Ma J F, et al. Polyhedron, 2008,27: 3351-3358
17. [17]
  [17] Ma J F, Liu Y Y, Xing Y, et al. J. Chem. Soc., Dalton Trans., 2000:2403-2407
18. [18]
  [18] Ma J C, Liu Y Y, Yang J, et al. CrystEngComm, 2011,13: 3498-3505
19. [19]
  [19] Liu Y Y, Ma J F, Yang J, et al. CrystEngComm, 2008,10: 565-572
20. [20]
  [20] Jiang H, Ma J F, Zhang W L, et al. Eur. J. Inorg. Chem., 2008:745-755
21. [21]
  [21] Yang J, Ma J F, Liu Y Y , et al. CrystEngComm, 2009,11: 151-159
22. [22]
  [22] LIU Jia-Cheng(刘家成), CAO Jing(曹靖), DENG Wen-Ting (邓文婷). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(2):343-346
23. [23]
  [23] ZHANG Ju-Zhou(张居舟). Thesis for the Doctorate of University Science and Technology of China (中国科学技术大学博士论文). 2009.
24. [24]
  [24] Li J R, Sculley J, Zhou H C. Chem. Rev., 2012,112(2):869-932
25. [25]
  [25] CHU Chao-Xia(楚超霞). Thesis for the Master of Jiangsu University of Science and Technology(江苏科技大学硕士论文). 2009.
26. [26]
  [26] Swain D, Row T N G. Inorg. Chem., 2007,46:4411-4421
27. [27]
  [27] Maji T K, Matsuda R, Kitagawa S. Nat. Mater., 2007,6:142
1. [1]
  Hexing SONG , Zan SUN . Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe³⁺ of an Mn(Ⅱ) complex based on 1-naphthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 885-892. doi: 10.11862/CJIC.20240402
2. [2]
  Yahui HAN , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Synthesis, crystal structure, thermal decomposition mechanism, and fluorescence properties of benzoic acid and 4-hydroxy-2, 2′: 6′, 2″-terpyridine lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 969-982. doi: 10.11862/CJIC.20240395
3. [3]
  Hongjie SHEN , Haozhe MIAO , Yuhe YANG , Yinghua LI , Deguang HUANG , Xiaofeng ZHANG . Synthesis, crystal structure, and fluorescence properties of two Cu(Ⅰ) complexes based on pyridyl ligand. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 855-863. doi: 10.11862/CJIC.20250009
4. [4]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
5. [5]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
6. [6]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
7. [7]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
8. [8]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
9. [9]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
10. [10]
  Hui Wang , Abdelkader Labidi , Menghan Ren , Feroz Shaik , Chuanyi Wang . 微观结构调控的g-C₃N₄在光催化NO转化中的最新进展：吸附/活化位点的关键作用. Acta Physico-Chimica Sinica, 2025, 41(5): 100039-. doi: 10.1016/j.actphy.2024.100039
11. [11]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
12. [12]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
13. [13]
  Yuxin CHEN , Yanni LING , Yuqing YAO , Keyi WANG , Linna LI , Xin ZHANG , Qin WANG , Hongdao LI , Wenmin WANG . Construction, structures, and interaction with DNA of two Sm^Ⅲ₄ complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1141-1150. doi: 10.11862/CJIC.20240258
14. [14]
  Han ZHANG , Jianfeng SUN , Jinsheng LIANG . Hydrothermal synthesis and luminescent properties of broadband near-infrared Na₃CrF₆ phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 349-356. doi: 10.11862/CJIC.20240098
15. [15]
  Linjie ZHU , Xufeng LIU . Synthesis, characterization and electrocatalytic hydrogen evolution of two di-iron complexes containing a phosphine ligand with a pendant amine. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 939-947. doi: 10.11862/CJIC.20240416
16. [16]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
17. [17]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
18. [18]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
19. [19]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
20. [20]
  Ruiying WANG , Hui WANG , Fenglan CHAI , Zhinan ZUO , Benlai WU . Three-dimensional homochiral Eu(Ⅲ) coordination polymer and its amino acid configuration recognition. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 877-884. doi: 10.11862/CJIC.20250052

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(305)
HTML views(14)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142