Citation: YANG Li-Guo, ZHANG Dao-Peng, LI Da-Cheng, DOU Jian-Min. Synthesis, Spectra Characterization and Crystal Structure of Three Nickle(Ⅱ) Complexes Containing Nido-carborane Disphosphine Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 875-882. doi: 10.3969/j.issn.1001-4861.2013.00.114
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Three nickel carborane disphosphine complexes [NiCl(Py){7, 8-(PPh2)2-7,8-C2B9H10}]CH2Cl2(1), [Ni{7, 8-(PPh2)2-7, 8-C2B9H10}2](2) and [Ni{7, 8-(OPPh2)-7, 8-C2B9H10}{7, 8-(PPh2)-7, 8-C2B9H10}](3) have been synthesized and characterized by elemental analysis, FTIR, 1H and 13C NMR spectroscopy and X-ray structure determination. Single crystal analysis shows that the coordination environment of the Ni atom is a slightly distorted square-planar in the complexes 1~3, in which the four positions are occupied by two P atoms, one Cl atom and one N atom of pyridine in 1, four P atoms in 2 and two P atoms and two O atoms in 3, respectively. One dimensional chain structure can be formed depending on C-H…Cl or dihydrogen bonding interactions in these three complexes. CCDC: 749848, 1; 749846, 2; 799937, 3.
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