Citation: CAI Shu-Lan, XIE Bin, WANG Yan-Mei, WANG Jun, ZOU Li-Ke, CHENG Jie, ZHU Sha-Sha, LAI Chuan, ZENG Ni. Synthesis, Crystal Structure, Thermal Stability Property and Antibactericidal Activity of Binuclear Lead Complex of O,O′-Di(p-tert-butylphenyl)dithiophosphate[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 779-785. doi: 10.3969/j.issn.1001-4861.2013.00.113 shu

Synthesis, Crystal Structure, Thermal Stability Property and Antibactericidal Activity of Binuclear Lead Complex of O,O′-Di(p-tert-butylphenyl)dithiophosphate

CAI Shu-Lan ¹ ,
XIE Bin ^1,2 ,
WANG Yan-Mei ³ ,
WANG Jun ¹ ,
ZOU Li-Ke ¹ ,
CHENG Jie ¹ ,
ZHU Sha-Sha ³ ,
LAI Chuan ^3,4 ,
ZENG Ni ³

1.
1 Institute of Functional Materials, Sichuan University of Science & Engineering, Zigong, Sichuan 643000, China;

Received Date: 5 June 2012
Available Online: 25 December 2012
Fund Project: 材料腐蚀与防护四川省重点实验室开放基金项目(No.2011CL03) (No.2011CL03)四川理工学院培育项目(No.2012PY14) (No.2012PY14)四川理工学院研究生创新基金(No.y2011015和No.y2011019)资助项目。 (No.y2011015和No.y2011019)

A new binuclear lead complex [Pb₂(S₂P(OR¹)₂)₂(μ-S₂P(OR¹)₂)₂] (R1 is p-tert-butylphenyl group) was synthesized and characterized by elemental analysis, IR, UV-Vis, TG-DSC, and single crystal X-ray diffraction analysis. The crystal structure study shows that the title complex is dinuclear structure which form an chair conformation of eight-membered ring [Pb₂S₄P₂], and the lead atom is in a distorted ψ-pentagonal bipyramidal coordination environment Pb(S₅ArE) by means of the weak π coordination from an aryl group of the bridging (R¹O)₂PS₂-ligand to lead atom and a lone pair of stereochemically active electrons originating from the lead atom. The antibacterial activities of the raw material (R¹O)₂PS₂NH₂Et₂ and complex were studied against E. Coli, B. Subtilis, and S. Aureus. The bioactivity test shows that both the raw material and complex can inhibit three kinds of bacteria, and the complex has higher antibacterial activity being compared with the raw material against E. Coli and B. Subtilis. CCDC: 870009.
- O,O′-Dialkyldithiophosphate;Pb complex;synthesis;crystal structure;thermal stable property;antibacterial activity
1. [1]
  [1] XIANGYang-Guang(相阳光). Master Degree Thesis of Sichuan University of Science & Engineering(四川理工学院硕士论文). 2011.
2. [2]
  [2] Rusanova D, Pike K J, Persson I, et al. Polyhedron, 2006,25 (18):3569-3580
3. [3]
  [3] Biricik N, Gümgüm B. Thermochim. Acta, 2004,417(2):43-45
4. [4]
  [4] XIE Bin(谢斌), WU Shi-Ye(吴士业). Chem. J. Chinese Univ.(Gaodeng Xuexiao Huaxue Xuebao), 1998,19(1):74-77
5. [5]
  [5] Ivanov A V, Gerasimenko A V, Antzutkin O N, et al. Inorg. Chim. Acta, 2005,358(9):2585-2594
6. [6]
  [6] Larsson A C, Ivanov A V, Forsling W, et al. J. Am. Chem. Soc., 2005,127(9):2218-2230
7. [7]
  [7] Jain P U, Munshi P, Walawalkar M G, et al. Polyhedron, 2000,19(7):801-808
8. [8]
  [8] Bajia S, Mishra A, Butcher R, et al. India J. Coord. Chem., 2010,63(24):4271-4279
9. [9]
  [9] Ta M, Yagan M, Bat H, et al. Phosphorus, Sulfur Silicon Relat. Elem., 2010,185(1):242-248
10. [10]
  [10] XIE Bin(谢斌), XIANG Yang-Guang(相阳光), LAI Chuan (赖川), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(5):886-890
11. [11]
  [11] Addison A W, Rao T N, Reedijik J, et al. J. Chem. Soc., Dalton Trans., 1984,7:1349-1356
12. [12]
  [12] Sharma P K, Singh Y. Phosphorus, Sulfur Silicon Relat. Elem., 2007,182(6):1183-1190
13. [13]
  [13] Gupta A, Sharma R K, Bohra R, et al. J. Organomet. Chem., 2003,678(1-2):122-127
14. [14]
  [14] Maltez H F, Borges D L G, Carasek E, et al. Talanta, 2008, 74(4):800-805
15. [15]
  [15] Harrison P G, Steel A, Pelizzi G, et al. Main Group Met. Chem., 1988,11(4):181-204
16. [16]
  [16] Harrison P G, Kikabhai T. Wear, 1987,116(1):25-31
17. [17]
  [17] Ito T. Acta Crystallogr., Sect. B, 1972,28:1034
18. [18]
  [18] Lawton S L, Kokotailo G T. Inorg. Chem., 1972,11(1):363-368
19. [19]
  [19] Larsson A C, Ivanov A V, Antzutkin O N, et al. Inorg. Chim. Acta, 2004,357(9):2510-2518
20. [20]
  [20] Harrison P G, Begley M G, Kikabhai T, et al. J. Chem. Soc., Dalton Trans., 1989(12):2443-2448
21. [21]
  [21] Larsson A C, Ivanov A V, Pike K J, et al. J. Magn. Reson., 2005,177(1):56-66
22. [22]
  [22] Sheldrick G M. SHELXS-97, Program for the Solution of Crystal Structures, Germany, University of Göttingen, 1997.
23. [23]
  [23] Sheldrick G M. SHELXL-97, Program for the Refinement of Crystal Structures, Germany, University of Göttingen, 1997
24. [24]
  [24] HU Cheng-zhi(胡盛志), ZHOU Chao-Hui(周朝晖), CAI Qi-Duan(蔡启端). Acta Phys.-Chim. Sin.(Wuli Huaxue Xuebao), 2003,19(11):1073-1077
25. [25]
  [25] Silvestru C, Haiduc I, Cea-Olivares R, et al. Inorg. Chim. Acta, 1995,233(1/2):151-154
26. [26]
  [26] Gillespie R J, Nyholm R S. Quart. Rev. Chem. Soc., 1957, 11:339-380
27. [27]
  [27] Maheshwari S, Drake J E, Kori K, et al. Polyhedron, 2009, 28(4):689-694
28. [28]
  [28] XIE Bin(谢斌), LAI Chuan(赖川), XIANG Yang-Guang(相阳光), et al. Chinese J. Appl. Chem.(Yingyong Huaxue), 2012,29(2):200-208
1. [1]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
2. [2]
  Lifang HE , Wenjie TANG , Yaoze LUO , Mingsheng LIANG , Jianxin TANG , Yuxuan WU , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two dialkyltin complexes constructed based on 2, 2′-bipyridin-6, 6′-dicarboxylic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1601-1609. doi: 10.11862/CJIC.20250012
3. [3]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
4. [4]
  Hongjie SHEN , Haozhe MIAO , Yuhe YANG , Yinghua LI , Deguang HUANG , Xiaofeng ZHANG . Synthesis, crystal structure, and fluorescence properties of two Cu(Ⅰ) complexes based on pyridyl ligand. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 855-863. doi: 10.11862/CJIC.20250009
5. [5]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
6. [6]
  Xuewei BA , Cheng CHENG , Huaikang ZHANG , Deqing ZHANG , Shuhua LI . Preparation and luminescent performance of Sr_1-xZrSi₂O₇∶xDy³⁺ phosphor with high thermal stability. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 357-364. doi: 10.11862/CJIC.20240096
7. [7]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
8. [8]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
9. [9]
  Hexing SONG , Zan SUN . Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe³⁺ of an Mn(Ⅱ) complex based on 1-naphthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 885-892. doi: 10.11862/CJIC.20240402
10. [10]
  Yahui HAN , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Synthesis, crystal structure, thermal decomposition mechanism, and fluorescence properties of benzoic acid and 4-hydroxy-2, 2′: 6′, 2″-terpyridine lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 969-982. doi: 10.11862/CJIC.20240395
11. [11]
  Linjie ZHU , Xufeng LIU . Synthesis, characterization and electrocatalytic hydrogen evolution of two di-iron complexes containing a phosphine ligand with a pendant amine. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 939-947. doi: 10.11862/CJIC.20240416
12. [12]
  Yuxin CHEN , Yanni LING , Yuqing YAO , Keyi WANG , Linna LI , Xin ZHANG , Qin WANG , Hongdao LI , Wenmin WANG . Construction, structures, and interaction with DNA of two Sm^Ⅲ₄ complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1141-1150. doi: 10.11862/CJIC.20240258
13. [13]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
14. [14]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
15. [15]
  Bin SUN , Heyan JIANG . Glucose-modified bis-Schiff bases: Synthesis and bio-activities in Alzheimer′s disease therapy. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1338-1350. doi: 10.11862/CJIC.20240428
16. [16]
  Xiaotong LU , Pan ZHANG , Zijie ZHAO , Lei HUANG , Hongwei ZUO , Lili LIANG . Antitumor and antibacterial activities of pyridyl Schiff base indium and dysprosium complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1523-1532. doi: 10.11862/CJIC.20250073
17. [17]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093
18. [18]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
19. [19]
  Chunling Qin , Shuang Chen , Hassanien Gomaa , Mohamed A. Shenashen , Sherif A. El-Safty , Qian Liu , Cuihua An , Xijun Liu , Qibo Deng , Ning Hu . Regulating HER and OER Performances of 2D Materials by the External Physical Fields. Acta Physico-Chimica Sinica, 2024, 40(9): 2307059-0. doi: 10.3866/PKU.WHXB202307059
20. [20]
  Lei Feng , Ze-Min Zhu , Ying Yang , Zongbin He , Jiafeng Zou , Man-Bo Li , Yan Zhao , Zhikun Wu . Long-Pursued Structure of Au₂₃(S-Adm)₁₆ and the Unexpected Doping Effects. Acta Physico-Chimica Sinica, 2024, 40(5): 2305029-0. doi: 10.3866/PKU.WHXB202305029

Get Citation

PDF

XML

Metrics

PDF Downloads(270)
Abstract views(823)
HTML views(35)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142