Citation: ZHOU Xiao-Shuang, YOU Zhong-Lu, XIAN Dong-Mei, DONG Da-Peng. Synthesis, Crystal Structure, Thermal Stability, and Magnetic Property of an End-to-End Azido-Bridged Dinuclear Schiff Base Copper(Ⅱ) Complex[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 850-854. doi: 10.3969/j.issn.1001-4861.2013.00.111 shu

Synthesis, Crystal Structure, Thermal Stability, and Magnetic Property of an End-to-End Azido-Bridged Dinuclear Schiff Base Copper(Ⅱ) Complex

1.
Department of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029, China

Received Date: 12 July 2012
Available Online: 21 December 2012
Fund Project: 国家自然科学基金(No.20901036) (No.20901036) 辽宁省高校优秀青年人才支持计划(No.LJQ2011114)资助项目。 (No.LJQ2011114)

A new dinuclear azido-bridged copper(Ⅱ) complex [Cu₂L₂( μ_1,3-N₃)₂] bearing crystallographic two-fold rotation axis symmetry has been synthesized from the tridentate Schiff base ligand 5-(ethylmethylamino)-2-[(2-morpholin-4-ylethylimino)methyl]phenol (HL) and sodium azide with copper(Ⅱ) acetate in methanol. The complex was characterized by elemental analyses, infrared spectroscopy, and X-ray single crystal determination. Crystal of the complex is crystallize as orthorhombic space group P2₁2₁2, with a=0.974 6(1), b=1.378 4(2), c=1.504 1(2) nm, V=2.023 3(5) nm³, Z=2, R₁=0.063 8, wR₂=0.166 8. Thermal stability and magnetic property of the complex were studied. CCDC: 890948.
- synthesis;crystal structure;copper(Ⅱ) complex;Schiff base;thermal stability;magnetic property
1. [1]
  [1] CHEN Man-Sheng(陈满生), LUO Li(罗莉), CHEN Shui-Sheng(陈水生), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(12):2227-2232
2. [2]
  [2] XIE Li-Xia(谢黎霞), WEI Mei-Lin(魏梅林), SUN Qiao-Zhen (孙巧珍), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2007,23(3):484-488
3. [3]
  [3] YIN Ping(殷平), ZHENG Li-Min(郑丽敏), GAO Song(高松), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2003, 19(1):49-53
4. [4]
  [4] Carranza J, Sletten J, Lloret F, et al. Polyhedron, 2009,28: 2249-2257
5. [5]
  [5] WANG Ling(王玲), CHEN Yan(陈岩), LIAN Hong-Lei(廉红蕾), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(4):725-729
6. [6]
  [6] ZHANG Ji-Cai(张吉才), LU Yao(芦瑶), LI Xiao-Hui(李晓辉), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(6):1259-1264
7. [7]
  [7] You Z L, Zhang M, Xian D M. Dalton Trans., 2012,41:2515-2524
8. [8]
  [8] Zhang J C, Zhou X S, Wang X L, et al. Transition Met. Chem., 2011,36:93-98
9. [9]
  [9] BAI Shi-Qiang(白士强), FANG Chen-Jie(房晨婕), YAN Chun-Hua(严纯华). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2006,22(12):2123-2134
10. [10]
  [10] Xian D M, You Z L, Zhang M, et al. J. Coord. Chem., 2011, 64:3265-3272
11. [11]
  [11] You Z L, Wang X L, Zhang J C, et al. Struct. Chem., 2011, 22:1297-1302
12. [12]
  [12] Shen Z, Zuo J L, Gao S, et al. Angew. Chem. Int. Ed., 2000, 39:3633-3635
13. [13]
  [13] Escuer A, Harding C J, Dussart Y, et al. Dalton Trans., 1999,2:223-227
14. [14]
  [14] Hong C S, Do Y. Angew. Chem. Int. Ed., 1999,38:193-195
15. [15]
  [15] You Z L, Shi D H, Zhang J C, et al. Inorg. Chim. Acta, 2012,384:54-61
16. [16]
  [16] Bruker, SMART and SAINT. Bruker AXS Inc., Madison, 2002.
17. [17]
  [17] Sheldrick G M. SADABS, University of Göttingen, Germany, 1996.
18. [18]
  [18] Sheldrick G M. SHELXTL V5.1, Software Reference Manual, Bruker AXS Inc., Madison, 1997.
19. [19]
  [19] Song X Y, Li W, Li L C, et al. Inorg. Chem. Commun., 2007,10:567-570
20. [20]
  [20] You Z L, Jiao Q Z, Niu S Y, et al. Z. Anorg. Allg. Chem., 2006,632:2481-2485
21. [21]
  [21] Addison A W, Rao T N, Reedijk J, et al. J. Chem. Soc., Dalton Trans., 1984,7:1349-1356
1. [1]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
2. [2]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
3. [3]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
4. [4]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
5. [5]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
6. [6]
  Jinlong YAN , Weina WU , Yuan WANG . A simple Schiff base probe for the fluorescent turn-on detection of hypochlorite and its biological imaging application. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1653-1660. doi: 10.11862/CJIC.20240154
7. [7]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
8. [8]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
9. [9]
  Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
10. [10]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
11. [11]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
12. [12]
  Maitri Bhattacharjee , Rekha Boruah Smriti , R. N. Dutta Purkayastha , Waldemar Maniukiewicz , Shubhamoy Chowdhury , Debasish Maiti , Tamanna Akhtar . Synthesis, structural characterization, bio-activity, and density functional theory calculation on Cu(Ⅱ) complexes with hydrazone-based Schiff base ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1409-1422. doi: 10.11862/CJIC.20240007
13. [13]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
14. [14]
  Ning LI , Siyu DU , Xueyi WANG , Hui YANG , Tao ZHOU , Zhimin GUAN , Peng FEI , Hongfang MA , Shang JIANG . Preparation and efficient catalysis for olefins epoxidation of a polyoxovanadate-based hybrid. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 799-808. doi: 10.11862/CJIC.20230372
15. [15]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
16. [16]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
17. [17]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
18. [18]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
19. [19]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
20. [20]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(341)
HTML views(35)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142