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Citation: XU Min, ZHOU Ai-Jü, LI Dong-Xiang, HUANG Hui-Yi, XIE Guo-Biao, DONG Wen. Synthesis, Structure and Magnetic Properties of a Mixed-Valence Heptanuclear Manganese Complex with Triethanolamine and Thiocyanate {K[MnⅡMn6Ⅲ(teaH)3(tea)3(NCS)6]}n[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 826-830. doi: 10.3969/j.issn.1001-4861.2013.00.109 shu

Synthesis, Structure and Magnetic Properties of a Mixed-Valence Heptanuclear Manganese Complex with Triethanolamine and Thiocyanate {K[MnⅡMn6Ⅲ(teaH)3(tea)3(NCS)6]}n

  • 1.

    School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou 510006, China

  • Received Date: 11 September 2012
    Available Online: 1 December 2012

    Fund Project: 国家自然科学基金(No.21001032)资助项目。 (No.21001032)

  • A mixed-valence heptanuclear manganese complex {K[MnⅡMn6Ⅲ(teaH)3(tea)3(NCS)6]}n (1) (teaH3=triethanolamine) has been synthesized by the reaction of MnCl2 (or Mn(NO3)2) with mixed ligands of teaH3 and KSCN and structurally characterized by IR, elemental analysis, single crystal X-ray diffraction. The anion of 1 consists of a Mn7 unit and compose wheel structure, in which a central MnⅡ ion surrounded by six MnⅢ ions. The result based on direct current magnetic susceptibility showed 1 a spin ground state S=29/2. The magnetic behavior of 1 indicates a ferromagnetic interaction between the high-spin MnⅡ and MnⅢ ions. CCDC: 843079.
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