Citation: JIN Jing, LIU Yong-Hua, LIU Jia-Cao, NIU Shu-Yun. Synthesis, Structure and Comparison of Photo-electric Properties of Co(Ⅱ) Complexes with Benzoic Derivatives Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(3): 455-464. doi: 10.3969/j.issn.1001-4861.2013.00.108 shu

Synthesis, Structure and Comparison of Photo-electric Properties of Co(Ⅱ) Complexes with Benzoic Derivatives Ligand

1.
School of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029, China

Received Date: 21 June 2012
Available Online: 22 November 2012
Fund Project: 国家自然科学基金(No.21133005) (No.21133005)辽宁省教育厅项目(No.2011193)资助项目。 (No.2011193)

Four Co(Ⅱ) complexes [Co(btec)_0.5(pz)₂]_n (1), [Co(btec)_0.5(pz)₃]_n (2), [Co(phen)(Hbtc)(H₃btc) (H₂O)₂]·3H₂O (3), [Co(Imh)₂(anis)₂(H₂O)] (4), (H₄btec=1,2,4,5-benzenetetracarboxylic acid, pz=pyrazole, H₃btc=1,3,5-benzene-tricarboxylic acid, phen=1,10-phenanthroline, Imh=imidazole, Hanis=p-anisic acid) were synthesized by hydrothermal method. They were characterized by X-ray single crystal diffraction, IR, elemental analysis, UV-Vis-NIR diffuse reflection spectrum and surface photovoltage spectroscopy (SPS). The structural analyses indicate that 1 is a Co(Ⅱ) polymer with 2D structure. The Co(Ⅱ) ion is four-coordinate in 1; the ones in 2～4 are both six-coordinate. 2 possesses 1D structure, connected by hydrogen bonds into 2D layer. 3 and 4 are molecular complexes, which are networked into 3D and 2D structures by hydrogen bonds, respectively. Four complexes all exhibit obvious surface photovoltage responses within 300～600 nm in SPS, which indicates that they possess certain photo-electric conversion properties. The influences of structure, dimension of complex and coordination micro-environment of center metal ion on the SPS were discussed emphatically. The energy band theory of semiconductor and crystal field theory are combined to analyze and assign SPS response bands. CCDC: 883535, 1; 883536, 2; 883537, 3; 883538, 4.
- Co(Ⅱ) complexe;synthesis;crystal structure;hydrogen bond;surface photoelectric property
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沈阳化工大学材料科学与工程学院沈阳 110142