Citation: ZHANG Fu-Xing, WANG Jian-Qiu, KUANG Dai-Zhi, FENG Yong-Lan, XU Zhi-Feng, YU Jiang-Xi. Synthesis, Crystal Structure and Properties of Novel Dicyclohexyltin Quinoline-2-Carboxylate[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(3): 537-543. doi: 10.3969/j.issn.1001-4861.2013.00.100
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Dicyclohexyltin quinoline-2-carboxylate [Cy4Sn2(μ-OH)2(C9NH6CO2)2]·2[Cy2Sn(C9NH6CO2)2]·2H2O was synthesised by the reaction of tricyclohexyltin hydroxide with quinolinecarboxylic acid. The crystal structures have been determined by X-ray diffraction. It belongs to triclinic system, space group P1. In the unit cell, there are two different kinds of composition and structure of the dicyclohexyltin quinoline-2-carboxylate complex molecules. some of the tin atoms are five-coordination distorted tigonal bipyramidal structure, others are six coordinated distorted octahedron. The study on the title complex has been performed with quantum chemistry calculation. The stabilities, the orbital energies and composition characteristics of some frontier molecular orbitals of the complex have been investigated.The thermal stability,electrochemical properties and, photoluminescent property of complexes have been investigated. CCDC: 865659.
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