Citation: FU Wei-Wei, KUANG Dai-Zhi, ZHANG Fu-Xing, LIU Yang, LI Wei, KUANG Yun-Fei. Synthesis, Crystal Structure and Properties of the Nickel(Ⅱ) 4'-(p-methoxylphenyl)-2, 2':6',2″-terpyridine Complex[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(3): 654-658. doi: 10.3969/j.issn.1001-4861.2013.00.099 shu

Synthesis, Crystal Structure and Properties of the Nickel(Ⅱ) 4'-(p-methoxylphenyl)-2, 2':6',2″-terpyridine Complex

1.
Department of Chemistry and Materials Science, Hengyang Normal University, Key Laboratory of Functional Organometallic Materials of Gerneral Institutes of Higher Education In Hunan Province, Hengyang, Hunan 421008, China

Received Date: 1 April 2012
Available Online: 10 October 2012
Fund Project: 衡阳市科技计划项目(No.2011KJ21) (No.2011KJ21)衡阳师范学院科研启动基金(No.09B02) (No.09B02)

The title complex has been synthesized with 4'-(p-methoxylphenyl)-2,2':6',2″-terpyridine (meophtpy) and zinc sulfate heptahydrate (NiSO₄·7H₂O), sodium perchlorate (NaClO₄) with solvothermal method and characterized by IR, UV and X-ray diffraction. It crystallizes in monoclinic space group P2₁/c. The crystal structure shows that the nickel atom is coordinated with six nitrogen atoms from two terpyridine molecules, forming six-coordinated octahedral coordination geometry. There are three abosrpsion peaks 235.5, 278.5 and 342 nm which are the typical absorption spectrum of terpyridine complexes. The fluerescence are peaked at 396 nm. Following a cyclic voltammetry measurement a typical reduction peak of Ni²⁺ at -0.82 V was found. CCDC: 899537.
- nickel(Ⅱ) complex;terpyridine;fluerescence;cyclic voltammetry
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沈阳化工大学材料科学与工程学院沈阳 110142