Citation: FU Wei-Wei, KUANG Dai-Zhi, ZHANG Fu-Xing, LIU Yang, LI Wei, KUANG Yun-Fei. Synthesis, Crystal Structure and Properties of the Nickel(Ⅱ) 4'-(p-methoxylphenyl)-2, 2':6',2″-terpyridine Complex[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(3): 654-658. doi: 10.3969/j.issn.1001-4861.2013.00.099
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The title complex has been synthesized with 4'-(p-methoxylphenyl)-2,2':6',2″-terpyridine (meophtpy) and zinc sulfate heptahydrate (NiSO4·7H2O), sodium perchlorate (NaClO4) with solvothermal method and characterized by IR, UV and X-ray diffraction. It crystallizes in monoclinic space group P21/c. The crystal structure shows that the nickel atom is coordinated with six nitrogen atoms from two terpyridine molecules, forming six-coordinated octahedral coordination geometry. There are three abosrpsion peaks 235.5, 278.5 and 342 nm which are the typical absorption spectrum of terpyridine complexes. The fluerescence are peaked at 396 nm. Following a cyclic voltammetry measurement a typical reduction peak of Ni2+ at -0.82 V was found. CCDC: 899537.
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