Citation: LI Hai-Hua, ZHOU Xiao-Xia, YOU Zhong-Lu. Synthesis, Crystal Structure, Thermal Stability, and Antimicrobial Activity of a Hexanuclear Iron(Ⅲ) Complex Derived from 2-[1-(2-Hydroxyethylimino)ethyl]phenol[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(3): 649-653. doi: 10.3969/j.issn.1001-4861.2013.00.080 shu

Synthesis, Crystal Structure, Thermal Stability, and Antimicrobial Activity of a Hexanuclear Iron(Ⅲ) Complex Derived from 2-[1-(2-Hydroxyethylimino)ethyl]phenol

1.
Department of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029, China

Received Date: 30 June 2012
Available Online: 19 November 2012
Fund Project: 国家自然科学基金(No.20901036) (No.20901036)辽宁省高校优秀青年人才支持计划(No.LJQ2011114)资助项目。 (No.LJQ2011114)

A new centrosymmetric hexanuclear iron(Ⅲ) complex [NaFe₆L₆(MeO)₆]Cl has been synthesized from the tridentate Schiff base ligand 2-[1-(2-hydroxyethylimino)ethyl]phenol (H₂L) and sodium dicyanamide with iron(Ⅲ) chloride in methanol. The complex was characterized by elemental analyses, infrared spectroscopy, and X-ray single crystal determination. The crystal of the complex crystallizes as triclinic space group P1, with a=1.162 5(2) nm, b=1.396 4(2) nm, c=1.504 2(2) nm, α=66.154(7)°, β=68.809(7)°, γ=73.296(7)°, V=2.053 6(5) nm³, Z=1, R₁=0.059 3, wR₂=0.156 4. Thermal stability and antimicrobial activity of the complex were studied. CCDC: 889111.
- synthesis;crystal structure;iron complex;Schiff base;thermal stability;antimicrobial activity
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沈阳化工大学材料科学与工程学院沈阳 110142