Citation: YANG Ying, CUI Jia-Rui, YI Peng-Fei, XIAO Si, GUO Xue-Yi. Effect of NiO Nanoparticles on Magnetic Quasi-Solid Dye-Sensitized Solar Cells[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(5): 1007-1012. doi: 10.3969/j.issn.1001-4861.2013.00.076 shu

Effect of NiO Nanoparticles on Magnetic Quasi-Solid Dye-Sensitized Solar Cells

YANG Ying ¹ ,
CUI Jia-Rui ¹ ,
YI Peng-Fei ¹ ,
XIAO Si ² ,
GUO Xue-Yi ^1,,

1.
1. School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China;

Corresponding author: GUO Xue-Yi,
Received Date: 14 September 2012
Available Online: 30 October 2012
Fund Project:

A magnetic polymer electrolyte using agarose as polymer matrix, NMP as solvent and NiO nanoparticles as modifier was investigated and employed in the dye-sensitized solar cell (DSSC) in this paper. The influence of NiO nanoparticles content on magnetic polymer electrolyte was characterized by SEM and ionic conductivity test. The photovoltaic properties of the corresponding DSSCs with different concentrations of NiO nanoparticles were studied by photovoltaic performance tests and electrochemical impedance spectra (EIS). The results showed that the optimal concentration of NiO nanoparticles was 1.0wt%, in which concentration the surface morphology of the polymer electrolyte was smooth and this magnetic polymer electrolyte showed the maximum conductivity (2.43×10^-3 S·cm^-1). The photoelectric efficiency and electron lifetime of DSSCs increased initially and then decreased with the increasing of the NiO nanoparticles content, the optimal photoelectric efficiency as well as the longest electron lifetime were achieved at the NiO nanoparticles content of 1.0wt%. At this optimal content, the photoelectric efficiency of DSSC was 1.63%, the voltage, current density and the filling factor of the DSSC was 0.57 V, 5.8 mA·cm^-2 and 0.53, respectively.
- magnetic polymer electrolyte;dye-sensitized solar cell;NiO nanoparticles;ionic conductivity;electrochemical impedance
1. [1]
  [1] ORegan B, Grtzel M. Nature 1991,353:737-740
2. [2]
  [2] Nazeeruddin M K, Kay A, Rodicio I, et al. Chem. Soc., 1993,115(14):6382-6390
3. [3]
  [3] YANG Shu-Ming(杨术明). Dye-sensitized Nanocrystalline Solar Cells(染料敏化纳米晶太阳能电池). Zhengzhou: Zhengzhou University Press, 2007.
4. [4]
  [4] Yella A, Lee H W, Tsao H N, et al. Science, 2011,334 (6056):629-634
5. [5]
  [5] WANG Wei-Jia(王惟嘉), YANG Ying(杨英), GUO Xue-Yi (郭学益), et al. Chemistry (Huaxue Tongbao), 2011,74(2): 144-149
6. [6]
  [6] Kumara R A G, Kancko S, Okuya M, et al. Langmuir, 2002,18(26):10493-10495
7. [7]
  [7] Meng Q B, Takahashi K, Zhang X T, et al. Langmuir, 2003, 19(9):3572-3574
8. [8]
  [8] Bach U, Lupo D, Comte P, et al. Nature, 1998,395:583-585
9. [9]
  [9] Nogueria A F, Durrant J R, Depaoli M A, et al. Adv. Mater., 2001,13(11):826-830
10. [10]
  [10] Wang P, Zakeeruddin S M, Grtzel M. J. Fluorine Chem., 2004,125(8):1241-1245
11. [11]
  [11] Wang H X, Li H, Xue B F, et al. J. Am. Chem. Soc., 2005, 127(17):6394-6401
12. [12]
  [12] Xue B F, Wang H X, Hu Y S, et al. Photochem. Photobiol. Sci., 2004,3(10):918-919
13. [13]
  [13] Yang M R, Teng T H, Wu S H. J. Power Sources, 2006,159 (1):307-311
14. [14]
  [14] Yang Y , Zhou C H , Xu S, et al. Nanotechnology, 2009,20 (10):105204(9pp)
15. [15]
  [15] SHI Yan-Tao(史彦涛), SUN Xiao-Dan(孙晓丹), WENG Duan(翁端), et al. World SCI-Tech R&D(Shijie Keji Yanjiu Yu Fazhan), 2006,28(3):45-50
16. [16]
  [16] QIU Wei-Li(邱玮丽), YANG Qing-He(杨清河), MA Xiao- Hua(马晓华), et al. Chin. J. Power Sources(Dianyuan Jishu), 2004,28(7):440-448
17. [17]
  [17] DU Hong-Yan(杜洪彦), CHENG Hu(程琥), YANG Yong (杨勇). Electrochemistry (Dianhuaxue), 2004,10(2):215-221
18. [18]
  [18] Han H W, Liu W, Zhang J, et al. Adv. Funct. Mater., 2005, 15(12):1940-1944
19. [19]
  [19] Khan S A, Baker G L, Colson S. Chem. Mater., 1994,6(12): 2359-2363
20. [20]
  [20] Croce F, Appetecchi G B, Persi L, et al. Nature, 1998,394 (28818):456-458
21. [21]
  [21] Wang Y P, Zhu J W, Yang X J, et al. Thermochmica Acta, 2005,437(1):106-109
22. [22]
  [22] Golodnitsky D, Livshits E, Kovarsky R, et al. Electrochem. Solid-State Lett., 2004,7(11):412-415
23. [23]
  [23] Livshits E, Kovarsky R, Lavie N, et al. Electrochim. Acta, 2005,50(19):3805-3814
24. [24]
  [24] Ash B J, Schadler L S, Siegel R W. Mater. Lett., 2002,55 (1):83-87
25. [25]
  [25] Choi B K, Kim Y W, Shin K H. J. Power Sources, 1997,68 (2):357-360
26. [26]
  [26] Fuke N, Fukui A, Komiya R, et al. Chem. Mater., 2008,20 (15):4974-4979
27. [27]
  [27] Wang M, Lin Y, Zhou X W, et al. Mater. Chem. Phys., 2008,107(1):61-66
28. [28]
  [28] Wang W J, Guo X Y, Yang Y. Electrochim. Acta, 2011,56 (21):7347-7351
29. [29]
  [29] Kern R, Sastrawan R, Ferber J, et al. Electrochim. Acta, 2002,47(26):4213-4225
30. [30]
  [30] LIANG Lin-Yun(梁林云), DAI Song-Yuan(戴松元), HU Lin-Hua(胡林华), et al. Acta Phys. Sin.(Wuli Xuebao), 2009,58(2):1338-1343
31. [31]
  [31] Nakade S, Saito Y, Kubo W, et al. J. Phys. Chem. B, 2003, 107(33):8607-8611
32. [32]
  [32] FU Ping-Feng(傅平丰), ZHANG Peng-Yi(张彭义). Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2009,25(11):2026-2030
33. [33]
  [33] WANG Zhong-Chang(王中长), LIU Tian-Mou(刘天模), LI Jia-Ming(李家鸣). J. Chongqing Univ. (Chongqing Daxue Xuebao), 2003,26(11):52-55
34. [34]
  [34] He J J, Benk G, Korodi F, et al. J. Am. Chem. Soc., 2002, 124(17):4922-4932
35. [35]
  [35] Zhang Z P, Zakeeruddin S M, O'Regan B, et al. J. Phys. Chem. B 2005,109(46):21818-21824
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