Citation: WANG Xu-Yang, YE Xue-Hai, ZHI Xiao-Ke, HE Ai-Zhen, ZHAO Zhen, ZHANG Su, SHI Jie. Effects of AlF3 Coating on the Electrochemical Performance of Li1.2Mn0.534Ni0.133Co0.133O2 Cathode Materials[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 774-778. doi: 10.3969/j.issn.1001-4861.2013.00.067
-
Li1.2Mn0.534Ni0.133Co0.133O2 cathode material of lithium ion batteries was prepared by co-precipitation method, and then the cathode material was coated by AlF3. The experiment results showed that the electrochemical properties of AlF3-coated material were improved obviously. Before coating, the initial discharge capacity was 253 mAh·g-1 at 0.2C with a charge/discharge efficiency of only 88.8%. However, after coating, the initial discharge capacity was 294 mAh·g-1 at 0.2C with a charge/discharge efficiency of 96.4%. Similarly, the capacity retention was also improved through AlF3 coating. The pristine material delivered a discharge capacity of only 185 mAh·g-1 (with capacity retention of 82.2%) after 50 charge/discharge cycles at 1.0C. Meanwhile, the AlF3-coated material delivered a discharge capacity of 222 mAh·g-1 (with capacity retention of 96.5%) after 50 charge/discharge cycles at 1.0C.
-
-
[1]
[1] LI Jie-Bin(李节宾), XU You-Long(徐友龙), DONG Xin(董 鑫), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(6):1125-1130
-
[2]
[2] DU Ke(杜柯), ZHAO Jun-Feng (赵军峰), WANG Wei-Gang (王伟刚), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(1):74-80
-
[3]
[3] ZHENG Jian-Ming(郑建明), WU Xiao-Biao(吴晓彪), YANG Yong(杨勇). Chinese J. Power Sources(Dianyuan Jishu), 2011,35(10):1188-1192
-
[4]
[4] Johson C S, Li N C, Lefief C, et al. Chem. Mater., 2008,20 (19):6095-6106
-
[5]
[5] Thackeray M, Kang S H, Johnson C S, et al. J. Mater. Chem., 2007,17(3):112-3125
-
[6]
[6] DU Ke(杜 柯), HUANG Xia(黄霞), YANG Fei(杨菲), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(5): 983-988
-
[7]
[7] XIN Sen(辛森), GUO Yu-Guo(郭玉国), WAN Li-Jun(万立 骏). Scientia Sinica Chimica(Zhongguo Kexue: Huaxue), 2011,41(8):1229-1239
-
[8]
[8] He W, Qian J F, Cao Y L, et al. RSC Advances, 2012,2: 3423-3429
-
[9]
[9] Jung Y S, Cavanagh A S, Yan Y F, et al. J. Electrochem. Soc., 2011,158(12):A1298-1302
-
[10]
[10] Wu Y, Manthiram A. Solid State Ionics, 2009,180(1):50-56
-
[11]
[11] Lee E S, Manthiram A. J. Electrochem. Soc., 2011,158(1): A47-A50
-
[12]
[12] HU Chuan-Yue(胡传跃), GUO Jun(郭军), WANG Xing-Yan (汪形艳), et al. J. Xiangtan Normal Univ.(Xiangtan Shifan Xueyuan Xuebao), 2009,31(3):15-17
-
[13]
[13] Zheng J M, Zhang Z R, Wu X B, et al. J. Electrochem. Soc., 2008,155(10):A775-A782
-
[14]
[14] Deng H, Belharouak I, Yoon C S, et al. J. Electrochem. Soc., 2012,157(10):A1035-A1039
-
[15]
[15] Sun Y K, Cho S W, Lee S W, et al. J. Electrochem. Soc., 2007,154(3):A168-A172
-
[16]
[16] Liu B, Zhang Q, He S C, et al. Electrochim. Acta, 2011,56 (19):6748-6751
-
[17]
[17] Shi J Y, Yi C W, Kim K. J. Power Sources, 2010,195:6860-6866
-
[18]
[18] Woo S U, Yoon C S, Amine K, et al. J. Electrochem. Soc., 2007,154(10):A1005-A1009
-
[19]
[19] Lee D J, Lee K S, Sun Y K. J. Power Sources, 2011,196: 1353-1357
-
[20]
[20] Yang K, Fan L Z, Guo J, et al. Electrochim. Acta, 2012,63: 363-368
-
[21]
[21] Gao J, Manthiram A. J. Power Sources, 2009,191(2):644-647
-
[22]
[22] LI Jie(李劼), ZHENG Jian-Ming(郑建明), GUO Xiao-Jian(郭 晓健). Chem. J. Chinese Universities(Gaodeng Xuexiao Huaxue Xuebao), 2006,27(7):1311-1314
-
[23]
[23] Robertson A D, Bruce P G. Chem. Mater., 2003,15(10):1984 -1992
-
[24]
[24] Li G R, Feng X, Gao X P, et al. Electrochim. Acta, 2012, 78:308-315
-
[25]
[25] Kim J H, Parka M S, Song J H, et al. J. Alloys Compd., 2012,517:20-25
-
[1]
-
-
[1]
Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga2O3 coated modification and electrochemical performance of Li1.2Mn0.54Ni0.13Co0.13O2 cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
-
[2]
Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li2FeSiO4/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
-
[3]
Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
-
[4]
Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
-
[5]
Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO2/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
-
[6]
Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
-
[7]
Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn0.8Fe0.2PO4/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
-
[8]
Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO3)3 double-coating modification on the electrochemical properties of Li[Ni0.8Co0.15Al0.05]O2. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
-
[9]
Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
-
[10]
Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
-
[11]
Mingjiao Lu , Zhixing Wang , Gui Luo , Huajun Guo , Xinhai Li , Guochun Yan , Qihou Li , Xianglin Li , Ding Wang , Jiexi Wang . Boosting the performance of LiNi0.90Co0.06Mn0.04O2 electrode by uniform Li3PO4 coating via atomic layer deposition. Chinese Chemical Letters, 2024, 35(5): 108638-. doi: 10.1016/j.cclet.2023.108638
-
[12]
Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
-
[13]
Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171
-
[14]
Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I2 interface modification engineering on the performance of all-inorganic CsPbBr3 perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
-
[15]
Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H2O and Its Intermediates on Electron-Deficient Mn(3+δ)+ for Efficient Photocatalytic H2O2 Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007
-
[16]
Huyi Yu , Renshu Huang , Qian Liu , Xingfa Chen , Tianqi Yu , Haiquan Wang , Xincheng Liang , Shibin Yin . Te-doped Fe3O4 flower enabling low overpotential cycling of Li-CO2 batteries at high current density. Chinese Journal of Structural Chemistry, 2024, 43(3): 100253-100253. doi: 10.1016/j.cjsc.2024.100253
-
[17]
Maomao Liu , Guizeng Liang , Ningce Zhang , Tao Li , Lipeng Diao , Ping Lu , Xiaoliang Zhao , Daohao Li , Dongjiang Yang . Electron-rich Ni2+ in Ni3S2 boosting electrocatalytic CO2 reduction to formate and syngas. Chinese Journal of Structural Chemistry, 2024, 43(8): 100359-100359. doi: 10.1016/j.cjsc.2024.100359
-
[18]
Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)2. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
-
[19]
Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO2 with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
-
[20]
Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co3O4 as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
-
[1]
Metrics
- PDF Downloads(239)
- Abstract views(622)
- HTML views(32)