Citation: CAO Ping, YANG Xian-Gui, XIN Yang, WANG Gong-Ying. Mo-Ti Composite Oxide Catalyst for Transesterification of Dimethyl Carbonate and Phenyl Acetate to Diphenyl Carbonate[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 747-752. doi: 10.3969/j.issn.1001-4861.2013.00.047
-
The Mo-Ti composite oxide catalyst was prepared by sol-gel method and used for the transesterification of dimethyl carbonate (DMC) and phenyl acetate (PA) to diphenyl carbonate (DPC). The effect of the molar ratio of Mo/Ti and reaction conditions on the catalytic performance was investigated. The catalyst with a Mo/Ti molar ratio of 2.5 shows the highest activity. When the reaction is carried out at 180℃, with a molar ratio of PA to DMC of 2:1, the reaction time of 4 h, a catalyst amount of 0.08 (weight ratio to PA), the conversion of DMC is 74.0%, and the selectivity of DPC and MPC is 45.5% and 51.0%, respectively. According to the surface and X-ray diffraction results, lager specific areas result in improved catalytic performance by the addition of TiO2. The Mo-Ti composite oxide is composed of α-MoO3 and highly dispersed amorphous titania and/or new crystal phase of Mo-Ti composite oxide.
-
-
[1]
[1] Tundo P, Selva M. Acc. Chem. Res., 2002,35(9):706-716
-
[2]
[2] Kim W B, Joshi U A, Lee J S. Ind. Eng. Chem. Res., 2004, 43(9):1897-1914
-
[3]
[3] Gong J L, Ma X B, Wang S P. Appl. Catal. A, 2007,316(1): 1-21
-
[4]
[4] Toniolo L. J. Mol. Catal. A, 1999,139(2/3):109-119
-
[5]
[5] Ishii H, Goyal M, Ueda M, et al. Catal. Lett., 2000,65(1/2/3): 57-60
-
[6]
[6] CAO Ping(曹平), YANG Xian-Gui(杨先贵), WANG Gong- Ying(王公应), et al. Nat. Gas Chem. Ind. (Tianranqi Huagong), 2008,33:43-46
-
[7]
[7] Illuminati G, Romano U, Tesei R. US 4182726.1980
-
[8]
[8] CAO Ping(曹平), SHI Wei-Bing(石卫兵), WANG Gong-Ying (王公应). Petrochem. Tech. (Shiyou Huagong), 2010,39(3): 346-351
-
[9]
[9] CAO Ping(曹平), YANG Jian(杨建), WANG Gong-Ying (王公应), et al. Chin. J. Catal. (Cuihua Xuebao), 2009,30 (9):65-68
-
[10]
[10] CAO Ping(曹平), YANG Xian-Gui(杨先贵), WANG Gong-Ying(王公应), et al. Petrochem. Tech. (Shiyou Huagong), 2011,40(10):1037-1041
-
[11]
[11] HAN Wei-Ping(韩维屏), YIN Xi-Lin(尹喜林), LI Yong-Zhan(李永战). Chin. J. Catal. (Cuihua Xuebao), 1992,13(1): 19-24
-
[12]
[12] ZHAN She-Xia(湛社霞), FAN Shan-Hu(范山湖), LIN Zuo- Mei(林作梅). Acta Scientiarum Naturalium Universitis Sunyatseni (Zhongshan Daxue Xuebao), 2001,40(2):125-126
-
[13]
[13] YANG Ying(杨莹), LI Xin-Jun(李新军), CHEN Jun-Tao (陈俊涛). Chin. J. Nonfer. Metals (Zhongguo Youse Jinshu Xuebao), 2004,14(3):509-514
-
[14]
[14] WANG Yu-Ping(王玉萍), WANG Lian-Jun(王连军), YUAN Jun-Xiu(袁俊秀). Appl. Chem. (Yingyong Huaxue), 2007,24 (1):53-57
-
[15]
[15] CAI Bin-Xin(蔡炳新), ZHAN Yong-Gong(詹拥共), YANG Ying-Ying(杨莹莹). J. Chem. Ind. Eng. (Huagong Xuebao), 2007,58(6):1451-1456
-
[16]
[16] CHEN Gui-Hua(陈桂华), YAN Rui-Qiang(闫瑞强), LIANG Hua-Ding(梁华定). Bull. Chin. Ceram. Soc. (Guisuanyan Tongbao), 2009,28(5):944-950
-
[1]
-
-
[1]
Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
-
[2]
Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO2-0.39IrOx composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
-
[3]
Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
-
[4]
Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO2 with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
-
[5]
Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
-
[6]
Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn2+ doped quasi-two-dimensional perovskites (PEA)2PbyMn1-yBr4. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
-
[7]
Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo2O4/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
-
[8]
Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
-
[9]
Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
-
[10]
Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO2 by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
-
[11]
Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
-
[12]
Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
-
[13]
Yujia LI , Tianyu WANG , Fuxue WANG , Chongchen WANG . Direct Z-scheme MIL-100(Fe)/BiOBr heterojunctions: Construction and photo-Fenton degradation for sulfamethoxazole. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 481-495. doi: 10.11862/CJIC.20230314
-
[14]
Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO2 mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
-
[15]
Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
-
[16]
Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
-
[17]
Zongfei YANG , Xiaosen ZHAO , Jing LI , Wenchang ZHUANG . Research advances in heteropolyoxoniobates. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 465-480. doi: 10.11862/CJIC.20230306
-
[18]
Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I2 interface modification engineering on the performance of all-inorganic CsPbBr3 perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
-
[19]
Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO4/NiMoS4 composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
-
[20]
Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
-
[1]
Metrics
- PDF Downloads(216)
- Abstract views(609)
- HTML views(84)