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Citation: YANG Xiao-Jing, BAO Song-Song, ZHENG Li-Min. Structures and Magnetic Properties of Metal Phosphonates Based on 2-(Benzoimidazol-2-yl)phenylphosphonic Acid: [Mn(2-bppH2)2(H2O)]n and [Cu(2-bppH2)2]·xCH3OH[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(3): 621-627. doi: 10.3969/j.issn.1001-4861.2013.00.037 shu

Structures and Magnetic Properties of Metal Phosphonates Based on 2-(Benzoimidazol-2-yl)phenylphosphonic Acid: [Mn(2-bppH2)2(H2O)]n and [Cu(2-bppH2)2]·xCH3OH

  • 1.

    State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

  • Received Date: 16 February 2012
    Available Online: 25 September 2012

    Fund Project: 江苏省自然科学基金 (No.BK2009009)资助项目。 (No.BK2009009)

  • This paper reports two metal phosphonates [Mn(2-bppH2)2(H2O)]n (1) and [Cu(2-bppH2)2]·xCH3OH (2) based on 2-(benzoimidazol-2-yl)phenylphosphonic acid (2-bppH3). Compound 1 has a one-dimensional chain structure in which Mn atoms are bridged by O-P-O units to form infinite chains. While compound 2 shows discrete mononuclear structure. Antiferromagnetic interactions are mediated between the MnⅡ ions through the O-P-O bridge in compound 1. CCDC: 913645, 1; 913643, 2.
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