Citation:
CHEN Xiao-Juan, ZHONG Hai-Min, YU Xiao-Lan, LAI Shu-Hui, CHEN Liu-Ping. Measurement of Infinite Dilution Diffusion Coefficients of Organics in Supercritical Carbon Dioxide[J]. University Chemistry,
;2016, 31(1): 41-47.
doi:
10.3866/pku.DXHX20160141
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Making use of the modified supercritical fluid chromatograph,we measured the infinite dilution diffusion coefficients of benzene and acetone in supercritical carbon dioxide under different temperatures and pressures,and further develop an opening experiment in order to reinforce students' understanding of the supercritical fluid and properties.The depth and breadth of students' perspective will be developed.Their experimental skills will be enhanced on the basis of learning operational principle,instrumental structure,application and manipulating method of supercritical liquid chromatograph,which is beneficial to cultivate the high quality chemistry talent.
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[1]
[1] 聂凌鸿,周如金,彭华松,宁正祥.林产化工通讯,2003,37(3),29.
-
[2]
[2] 杨长龙,胡浩权,张维冰,张玉奎.分析科学学报,2005,21(4),444.
-
[3]
[3] 何华,倪坤仪.现代色谱分析.北京:化学工业出版社,2004.
-
[4]
[4] 陈青,刘志敏.分析化学研究报告,2004,8,1104.
-
[5]
[5] 师萱,贾雪峰,钟耕.中国食品添加剂开发应用,2006,138.
-
[6]
[6] Juan,J.S.;Julio,L.B.;Ignacio,M.Chem.Eng.Sci.1993,48(13),2419.
-
[7]
[7] 石剑,张敏华,董秀芹.高等学校化学学报,2007,28(3),518.
-
[8]
[8] 梅东海,刘洪勤,汪文川.化工学报,1995,46(3),357.
-
[9]
[9] Medina,I.J.Chromatogr.A 2012,1250,124.
-
[10]
[10] Taylor,G.Proc.R.Soc.London 1953,A219,186.
-
[11]
[11] Funazukuri,T.;Kong,C.Y.;Kagei,S.Int.J.Thermophys.2001,22,1643.
-
[12]
[12] Funazukuri,T.;Kong,C.Y.;Kagei,S.Int.J.Thermophys.2000,21,651.
-
[13]
[13] Funazukuri,T.;Kong,C.Y.;Kagei,S.Int.J.Thermophys.2000,21,1279.
-
[14]
[14] NIST.NIST Standard Reference Database 69s February 2000(Release:NIST Chemistry Web Book);2000.
-
[15]
[15] Fenghour,A.;Wakeham W.A.;Vesovic,V.J.Phys.Chem.Ref.Data 1998,27,31.
-
[16]
[16] Luis,M.G.;Julio,L.B.;Ignacio,M.J.Supercrit.Fluids 2002,24,219.
-
[17]
[17] Tyrrell,H.J.V.;Harris,K.R.Diffusion in Liquids.A Theoretical and Experimental Study;Butterworths:London,1984.
-
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