高性能三元NASICON型Na3.5-xMn0.5V1.5-xZrx(PO4)3/C钠离子电池正极材料

引用本文: 梅建宝, 李贝, 张舒, 肖东东, 胡朴, 张更. 高性能三元NASICON型Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C钠离子电池正极材料[J]. 物理化学学报, 2024, 40(12): 240702. doi: 10.3866/PKU.WHXB202407023 shu

Citation: Jianbao Mei, Bei Li, Shu Zhang, Dongdong Xiao, Pu Hu, Geng Zhang. Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries[J]. Acta Physico-Chimica Sinica, 2024, 40(12): 240702. doi: 10.3866/PKU.WHXB202407023 shu

高性能三元NASICON型Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C钠离子电池正极材料

梅建宝 ^1, ,
李贝 ^1, ,
张舒 ^2, ,
肖东东 ^3, ,
胡朴 ^{1,
,} ,
张更 ^{4,
,}

1.
武汉工程大学材料科学与工程学院, 湖北省等离子体化学与先进材料重点实验室, 武汉 430205;
2.
中国科学院青岛生物能源与生物过程技术研究所, 山东青岛 266101;
3.
中国科学院物理研究所, 北京 101400;
4.
湖南理工学院机械工程学院, 湖南岳阳 414006

通讯作者: 胡朴,Email:hupu@wit.edu.cn,Tel.:+86-15695688093; 张更,Email:zhangziying04@163.com,Tel.:+86-19310196711

基金项目:
国家自然科学基金项目(52172227),湖北省自然科学基金项目(2023AFA114),启动基金(20QD80),武汉工程大学创新基金(CX2023068)项目资助

摘要: 钠离子电池被广泛研究用于储能应用，但实现同时具有高能量密度、稳定性和快速充放电性能的正极材料仍然是一个关键的挑战。本研究合成了一系列NASICON型Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C材料，并掺入Mn、V和Zr元素探讨其对电化学性能的影响。通过在Mn和V的基础上引入Zr，提出一种激活V⁴⁺/V⁵⁺氧化还原反应新的策略，从而提升能量密度。此外，Zr掺入通过拓宽离子通道并产生额外的钠离子空位，显著促进钠离子迁移，增强电极反应动力学和整体性能。结果表明，Na_3.4Mn_0.5V_1.4Zr_0.1(PO₄)₃/C材料表现出优异的循环稳定性，在800次循环后保持90%的容量，并具备高倍率性能(20C时，放电比容量为84 mAh∙g^-1)，显著优于原始的Na_3.5Mn_0.5V_1.5(PO₄)₃/C材料。该研究为开发高效且可持续钠离子电池提供了有效途径。

关键词:

English

Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries

Jianbao Mei ^1, ,
Bei Li ^1, ,
Shu Zhang ^2, ,
Dongdong Xiao ^3, ,
Pu Hu ^{1,
,} ,
Geng Zhang ^{4,
,}

1.
Hubei Key Laboratory of Plasma Chemistry and Advanced Materials, School of Materials Science and Engineering, Wuhan Institute of Technology, Wuhan 430205, China;
2.
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, Shandong Province, China;
3.
Institute of Physics, Chinese Academy of Sciences, Beijing 101400, China;
4.
College of Mechanical Engineering, Hunan Institute of Science and Technology, Yueyang 414006, Hunan Province, China

Corresponding author: Pu Hu, ; Geng Zhang,

Received Date: 25 July 2024
Accepted Date: 12 September 2024
Revised Date: 12 September 2024
Available Online: 23 September 2024
Fund Project:
This work was financially supported by the National Natural Science Foundation of China (52172227) and Natural Science Foundation of Hubei Province (2023AFA114). The authors are grateful to the Startup Fund (20QD80) and Graduated Innovative Fund of Wuhan Institute of Technology (CX2023068) for supporting this work.

Abstract: Sodium-ion batteries (SIBs) are widely studied for energy storage applications, but achieving cathode materials with balanced high energy density, stability, and fast charge/discharge performance remains a key challenge. In this study, we successfully synthesized a series of NASICON-type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C, incorporating Mn, V, and Zr to investigate their impact on electrochemical performance. By introducing Zr alongside Mn and V, we developed a novel strategy to activate V⁴⁺/V⁵⁺ redox reactions, achieving high energy density. Moreover, this substitution promotes Na-ion migration by widening the migration pathways and generating additional Na vacancies, which greatly enhances electrode reaction kinetics and boosts overall performance. Na_3.4Mn_0.5V_1.4Zr_0.1(PO₄)₃/C demonstrates superior stability, retaining 90% of its capacity after 800 cycles, and delivers high-rate performance (84 mAh∙g^-1 at 20C), significantly outperforming pristine Na_3.5Mn_0.5V_1.5(PO₄)₃/C. These advancements highlight a potential approach for developing efficient and sustainable SIBs.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

高性能三元NASICON型Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C钠离子电池正极材料

通讯作者: 胡朴,Email:hupu@wit.edu.cn,Tel.:+86-15695688093; 张更,Email:zhangziying04@163.com,Tel.:+86-19310196711

English

Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries

Corresponding author: Pu Hu, ; Geng Zhang,

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