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Citation: Jianbao Mei,  Bei Li,  Shu Zhang,  Dongdong Xiao,  Pu Hu,  Geng Zhang. Enhanced Performance of Ternary NASICON-Type Na3.5-xMn0.5V1.5-xZrx(PO4)3/C Cathodes for Sodium-Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2024, 40(12): 240702. doi: 10.3866/PKU.WHXB202407023 shu

Enhanced Performance of Ternary NASICON-Type Na3.5-xMn0.5V1.5-xZrx(PO4)3/C Cathodes for Sodium-Ion Batteries

  • 1.

    Hubei Key Laboratory of Plasma Chemistry and Advanced Materials, School of Materials Science and Engineering, Wuhan Institute of Technology, Wuhan 430205, China;

  • 2.

    Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, Shandong Province, China;

  • 3.

    Institute of Physics, Chinese Academy of Sciences, Beijing 101400, China;

  • 4.

    College of Mechanical Engineering, Hunan Institute of Science and Technology, Yueyang 414006, Hunan Province, China

  • Corresponding author: Pu Hu,  Geng Zhang, 
  • Received Date: 25 July 2024
    Revised Date: 12 September 2024
    Accepted Date: 12 September 2024

    Fund Project: This work was financially supported by the National Natural Science Foundation of China (52172227) and Natural Science Foundation of Hubei Province (2023AFA114). The authors are grateful to the Startup Fund (20QD80) and Graduated Innovative Fund of Wuhan Institute of Technology (CX2023068) for supporting this work.

  • Sodium-ion batteries (SIBs) are widely studied for energy storage applications, but achieving cathode materials with balanced high energy density, stability, and fast charge/discharge performance remains a key challenge. In this study, we successfully synthesized a series of NASICON-type Na3.5-xMn0.5V1.5-xZrx(PO4)3/C, incorporating Mn, V, and Zr to investigate their impact on electrochemical performance. By introducing Zr alongside Mn and V, we developed a novel strategy to activate V4+/V5+ redox reactions, achieving high energy density. Moreover, this substitution promotes Na-ion migration by widening the migration pathways and generating additional Na vacancies, which greatly enhances electrode reaction kinetics and boosts overall performance. Na3.4Mn0.5V1.4Zr0.1(PO4)3/C demonstrates superior stability, retaining 90% of its capacity after 800 cycles, and delivers high-rate performance (84 mAh∙g-1 at 20C), significantly outperforming pristine Na3.5Mn0.5V1.5(PO4)3/C. These advancements highlight a potential approach for developing efficient and sustainable SIBs.
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