Citation: Kaihui Huang, Dejun Chen, Xin Zhang, Rongchen Shen, Peng Zhang, Difa Xu, Xin Li. Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production[J]. Acta Physico-Chimica Sinica, ;2024, 40(12): 240702. doi: 10.3866/PKU.WHXB202407020 shu

Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production

Kaihui Huang ^{1, 2, †} ,
Dejun Chen ^{2, †} ,
Xin Zhang ^3,, ,
Rongchen Shen ^{1, 2,,} ,
Peng Zhang ^4,, ,
Difa Xu ⁵ ,
Xin Li ^{1, 2,,}

1.
Institute of Biomass Engineering, Key Laboratory of Energy Plants Resource and Utilization, Ministry of Agriculture and Rural Affairs, South China Agricultural University, Guangzhou 510642, China
2.
Key Laboratory for Biobased Materials and Energy of Ministry of Education, College of Materials and Energy, South China Agricultural University, Guangzhou 510642, China
3.
Hubei Key Lab Low Dimens Optoelect Mat ₂ Devices, Hubei University of Arts and Science, Xiangyang 441053, Hubei Province, China
4.
State Centre for International Cooperation on Designer Low-Carbon ₂ Environmental Materials (CDLCEM), School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China
5.
Hunan Key Laboratory of Applied Environmental Photocatalysis, Changsha University, Changsha 410022, China

Corresponding author: Xin Zhang, xinzhang@hbuas.edu.cn Rongchen Shen, shenrongchenscau@163.com Peng Zhang, zhangp@zzu.edu.cn Xin Li, xinli@scau.edu.cn
Received Date: 21 July 2024
Revised Date: 18 September 2024
Accepted Date: 19 September 2024
Available Online: 10 October 2024
Fund Project: The project was supported from the National Natural Science Foundation of China 22378148The project was supported from the National Natural Science Foundation of China 21975084The project was supported from the National Natural Science Foundation of China 2230082074Natural Science Foundation of Guangdong Province 2024A1515012433

The development of efficient photocatalysts for hydrogen production is crucial in sustainable energy research. In this study, we designed and prepared a Covalent Triazine Framework (CTF)-Cu₂O@NC composite featuring an S-scheme heterojunction structure aimed at enhancing the photocatalytic hydrogen production. The light absorption capacity, electron-hole separation efficiency and H₂-evolution activity of the composite were significantly enhanced due to the synergistic effects of the nitrogen-doped carbon (NC) layer and the S-scheme heterojunction. Structural and photoelectrochemical characterization of the system reveal that the S-scheme heterojunctions not only enhance the separation efficiency of photogenerated carriers but also maintain the strong redox capabilities to further promote the photocatalytic reactions. Moreover, the NC layer could simultaneously reduce the photocorrosion of Cu₂O and promote the electron transfer. Experimental results demonstrate that the CTF-7% Cu₂O@NC composite shows outstanding hydrogen-production performance under visible light, achieving 15645 μmol∙g⁻¹∙h⁻¹, significantly surpassing the photocatalytic activity of pure CTF (2673 μmol∙g⁻¹∙h⁻¹). This study introduces a novel approach to the development of efficient and innovative photocatalytic materials, strongly supporting the advancement of sustainable hydrogen energy.
- Photocatalytic hydrogen evolution,
- Cu₂O@NC,
- Covalent triazine frameworks (CTF),
- S-scheme heterojunction,
- Nitrogen doped carbon
1. [1]
  Hisatomi, T.; Domen, K. Nat. Catal. 2019, 2, 387. doi: 10.1038/s41929-019-0242-6 doi: 10.1038/s41929-019-0242-6
2. [2]
  Zhang, L. J.; Wu, Y. L.; Li, J. K.; Jin, Z. L.; Li, Y. J.; Tsubaki, N. Mater. Today Phys. 2022, 27, 100767. doi: 10.1016/j.mtphys.2022.100767 doi: 10.1016/j.mtphys.2022.100767
3. [3]
  Liu, H.; Zhang, Y. Y.; Li, D. J.; Li, Y. J.; Jin, Z. L. ACS Appl. Energy Mater. 2022, 5, 2474. doi: 10.1021/acsaem.1c03967 doi: 10.1021/acsaem.1c03967
4. [4]
  Meng, C.; Huang, M.; Li, Y. Chem. Res. Chin. Univ. 2023, 39, 697. doi: 10.1007/s40242-023-3124-z doi: 10.1007/s40242-023-3124-z
5. [5]
  Wu, X.; Tan, L.; Chen, G.; Kang, J.; Wang, G. Sci. China. Mater. 2024, 67, 444. doi: 10.1007/s40843-023-2755-2 doi: 10.1007/s40843-023-2755-2
6. [6]
  Qian, Y.; Zhang, F.; Kang, D. J.; Pang, H. Energy Environ. Mater. 2023, 6, e12414. doi: 10.1002/eem2.12414 doi: 10.1002/eem2.12414
7. [7]
  Wang, P.; Yang, M.; Tang, S. P.; Li, Y. J.; Lin, X.; Zhang, H. Y.; Zhu, Z.; Chen, F. T. J. Alloy. Compd. 2022, 918, 165607. doi: 10.1016/j.jallcom.2022.165607 doi: 10.1016/j.jallcom.2022.165607
8. [8]
  Wang, X. P., Li, Y. J., Li, T.; Jin, Z. L. Adv. Sustain. Syst. 2023, 7, 2200139. doi: 10.1002/adsu.202200139 doi: 10.1002/adsu.202200139
9. [9]
  Fan, K.; Sun, Y.; Xu, P.; Guo, J.; Li, Z.; Shao, M. Chem. Res. Chin. Univ. 2022, 38, 1185. doi: 10.1007/s40242-022-2254-z doi: 10.1007/s40242-022-2254-z
10. [10]
  Cai, M.; Wei, Y.; Li, Y.; Li, X.; Wang, S.; Shao, G.; Zhang, P. EcoEnergy 2023, 1, 248. doi: 10.1002/ece2.16 doi: 10.1002/ece2.16
11. [11]
  Shen, R.; Liang, G.; Hao, L.; Zhang, P.; Li, X. Adv. Mater. 2023, 35, 2303649. doi: 10.1002/adma.202303649 doi: 10.1002/adma.202303649
12. [12]
  Zheng, C. Y., Jiang, G. P., Li, Y. J.; Jin, Z. L. J. Alloy. Compd. 2022, 904, 164041. doi: 10.1016/j.jallcom.2022.164041. doi: 10.1016/j.jallcom.2022.164041
13. [13]
  Wang, J.; Wang, Z.; Dai, K.; Zhang, J. J. Mater. Sci. Technol. 2023, 165, 187. doi: 10.1016/j.jmst.2023.03.067 doi: 10.1016/j.jmst.2023.03.067
14. [14]
  Xu, Q.; Zhang, L.; Cheng, B.; Fan, J.; Yu, J. Chem 2020, 6, 1543. doi: 10.1016/j.chempr.2020.06.010 doi: 10.1016/j.chempr.2020.06.010
15. [15]
  Wu, X.; Chen, G.; Wang, J.; Li, J.; Wang, G. Acta Phys. -Chim. Sin. 2023, 39, 2212016. doi: 10.3866/pku.Whxb202212016 doi: 10.3866/pku.Whxb202212016
16. [16]
  Cheng, C.; Zhang, J.; Zhu, B.; Liang, G.; Zhang, L.; Yu, J. Angew. Chem. Int. Ed. 2023, 62, e202218688. doi: 10.1002/anie.202218688 doi: 10.1002/anie.202218688
17. [17]
  Cai, J.; Liu, B.; Zhang, S.; Wang, L.; Wu, Z.; Zhang, J.; Cheng, B. J. Mater. Sci. Technol. 2024, 197, 183. doi: 10.1016/j.jmst.2024.02.012 doi: 10.1016/j.jmst.2024.02.012
18. [18]
  Fan, Z. B.; Guo, X.; Liu, F. J.; Li, Y. J.; Zhang, L. J.; Jin, Z. L. Appl. Mater. Today 2022, 29, 101637. doi: 10.1016/j.apmt.2022.101637. doi: 10.1016/j.apmt.2022.101637
19. [19]
  Hua, J.; Wang, Z.; Zhang, J.; Dai, K.; Shao, C.; Fan, K. J. Mater. Sci. Technol. 2023, 156, 64. doi: 10.1016/j.jmst.2023.03.003 doi: 10.1016/j.jmst.2023.03.003
20. [20]
  He, H.; Wang, Z.; Dai, K.; Li, S.; Zhang, J. Chin. J. Catal. 2023, 48, 267. doi: 10.1016/S1872-2067(23)64420-1 doi: 10.1016/S1872-2067(23)64420-1
21. [21]
  Zhu, Z.; Zhang, H. Y.; Teng, Y.; Lin, X.; Li, M.; Li, Y. J. Surf. Interfaces 2023, 41, 103160. doi: 10.1016/j.surfin.2023.103160 doi: 10.1016/j.surfin.2023.103160
22. [22]
  Dong, Y.; Ji, P.; Xu, X.; Li, R.; Wang, Y.; Homewood, K. P.; Xia, X.; Gao, Y.; Chen, X. Energy Environ. Mater. 2024, 7, e12643. doi: 10.1002/eem2.12643 doi: 10.1002/eem2.12643
23. [23]
  Liu, M.; Huang, Q.; Wang, S.; Li, Z.; Li, B.; Jin, S.; Tan, B. Angew. Chem. Int. Ed. 2018, 57, 11968. doi: 10.1002/anie.201806664 doi: 10.1002/anie.201806664
24. [24]
  He, J.; Wang, X. D.; Jin, S. B.; Liu, Z. Q.; Zhu, M. S. Chin. J. Catal. 2022, 43, 1306. doi: 10.1016/s1872-2067(21)63936-0. doi: 10.1016/s1872-2067(21)63936-0
25. [25]
  Zhang, G.; Li, X.; Chen, D.; Li, N.; Xu, Q.; Li, H.; Lu, J. Adv. Funct. Mater. 2023, 33, 2308553. doi: 10.1002/adfm.202308553. doi: 10.1002/adfm.202308553
26. [26]
  Ding, H.; Shen, R.; Huang, K.; Huang, C.; Liang, G.; Zhang, P.; Li, X. Adv. Funct. Mater. 2024, 34, 2400065. doi: 10.1002/adfm.202400065. doi: 10.1002/adfm.202400065
27. [27]
  Gao, Z.; Jian, Y.; Yang, S.; Xie, Q. J.; McFadzean, C. J. R.; Wei, B. S.; Tang, J. T.; Yuan, J. Y.; Pan, C. Y.; Yu, G. P. Angew. Chem. Int. Ed. 2023, 135, e202304173. doi: 10.1002/anie.202304173. doi: 10.1002/anie.202304173
28. [28]
  Liu, R.; Zhao, L.; Liu, B.; Yu, J.; Wang, Y.; Yu, W.; Xin, D.; Fang, C.; Jiang, X.; Hu, R.; et al. Chin. J. Struc. Chem. 2024, 43, 100332. doi: 10.1016/j.cjsc.2024.100332 doi: 10.1016/j.cjsc.2024.100332
29. [29]
  Zhang, Z. Q.; Wang, H. B.; Li, Y. X.; Xie, M. G.; Li, C. G.; Lu, H. Y.; Peng, Y.; Shi, Z. Chem. Res. Chin. Univ. 2022, 38, 750. doi: 10.1007/s40242-022-1504-4 doi: 10.1007/s40242-022-1504-4
30. [30]
  Huang, K.; Feng, B.; Wen, X.; Hao, L.; Xu, D.; Liang, G.; Shen, R.; Li, X. Chin. J. Struc. Chem. 2023, 42, 100204. doi: 10.1016/j.cjsc.2023.100204 doi: 10.1016/j.cjsc.2023.100204
31. [31]
  Wan, L.; Zhou, Q.; Wang, X.; Wood, T. E.; Wang, L.; Duchesne, P. N.; Guo, J.; Yan, X.; Xia, M.; Li, Y. F.; et al. Nat. Catal. 2019, 2, 889. doi: 10.1038/s41929-019-0338-z doi: 10.1038/s41929-019-0338-z
32. [32]
  Han, X.; He, X.; Sun, L.; Han, X.; Zhan, W.; Xu, J.; Wang, X.; Chen, J. ACS Catal. 2018, 8, 3348. doi: 10.1021/acscatal.7b04219 doi: 10.1021/acscatal.7b04219
33. [33]
  Liu, L.; Yang, W.; Li, Q.; Gao, S.; Shang, J. K. ACS Appl. Mater. Inter. 2014, 6, 5629. doi: 10.1021/am500131b doi: 10.1021/am500131b
34. [34]
  Wang, K.; Yang, L.; Wang, X.; Guo, L.; Cheng, G.; Zhang, C.; Jin, S.; Tan, B.; Cooper, A. Angew. Chem. Int. Ed. 2017, 56, 14149. doi: 10.1002/anie.201708548 doi: 10.1002/anie.201708548
35. [35]
  Hao, L.; Ning, J.; Luo, B.; Wang, B.; Zhang, Y.; Tang, Z.; Yang, J.; Thomas, A.; Zhi, L. J. Am. Chem. Soc. 2015, 137, 219. doi: 10.1021/ja508693y doi: 10.1021/ja508693y
36. [36]
  Wang, J.; Wang, Z.; Zhang, J.; Dai, K. Chin. J. Struc. Chem. 2023, 42, 100202. doi: 10.1016/j.cjsc.2023.100202 doi: 10.1016/j.cjsc.2023.100202
37. [37]
  Shen, R.; Li, N.; Qin, C.; Li, X.; Zhang, P.; Li, X.; Tang, J. Adv. Funct. Mater. 2023, 33, 2301463. doi: 10.1002/adfm.202301463 doi: 10.1002/adfm.202301463
38. [38]
  Zhang, M.; Chen, Z.; Wang, Y.; Zhang, J.; Zheng, X.; Rao, D.; Han, X.; Zhong, C.; Hu, W.; Deng, Y. Appl. Catal. B-Environ. 2019, 246, 202. doi: 10.1016/j.apcatb.2019.01.042 doi: 10.1016/j.apcatb.2019.01.042
39. [39]
  Hao, L.; Shen, R.; Huang, C.; Liang, Z.; Li, N.; Zhang, P.; Li, X.; Qin, C.; Li, X. Appl. Catal. B-Environ. 2023, 330, 122581. doi: 10.1016/j.apcatb.2023.122581 doi: 10.1016/j.apcatb.2023.122581
40. [40]
  Waqas, M. Chem. Res. Chin. Univ. 2024, 40, 529. doi: 10.1007/s40242-024-4055-z doi: 10.1007/s40242-024-4055-z
41. [41]
  Shen, R.; He, K.; Zhang, A.; Li, N.; Ng, Y. H.; Zhang, P.; Hu, J.; Li, X. Appl. Catal. B-Environ. 2021, 291, 120104. doi: 10.1016/j.apcatb.2021.120104 doi: 10.1016/j.apcatb.2021.120104
42. [42]
  Guo, L.; Gao, J.; Li, M.; Xie, Y.; Chen, H.; Wang, S.; Li, Z.; Wang, X.; Zhou, W. EcoEnergy 2023, 1, 437. doi: 10.1002/ece2.20 doi: 10.1002/ece2.20
43. [43]
  Xu, N.; Liu, Y.; Yang, W.; Tang, J.; Cai, B.; Li, Q.; Sun, J.; Wang, K.; Xu, B.; Zhang, Q. ACS Appl. Energy Mater. 2020, 3, 11939. doi: 10.1021/acsaem.0c02102 doi: 10.1021/acsaem.0c02102
44. [44]
  Sun, T.; Liang, Y.; Xu, Y. Angew. Chem. Int. Ed. 2022, 61, e202116875. doi: 10.1002/anie.202116875 doi: 10.1002/anie.202116875
45. [45]
  Gao, S.; Zhang, P.; Huang, G.; Chen, Q.; Bi, J.; Wu, L. ChemSusChem 2021, 14, 3850. doi: 10.1002/cssc.202101308 doi: 10.1002/cssc.202101308
46. [46]
  Xu, Z.; Cui, Y.; Guo, B.; Li, H. -Y.; Li, H. -X. ChemCatChem 2021, 13, 958. doi: 10.1002/cctc.202001631 doi: 10.1002/cctc.202001631
47. [47]
  Feng, T.; Wang, J.; Gao, S.; Feng, C.; Shang, N.; Wang, C.; Li, X. Appl. Surf. Sci. 2019, 469, 431. doi: 10.1016/j.apsusc.2018.11.036 doi: 10.1016/j.apsusc.2018.11.036
48. [48]
  Yu, J.; Sun, X.; Xu, X.; Zhang, C.; He, X. Appl. Catal. B-Environ. 2019, 257, 117935. doi: 10.1016/j.apcatb.2019.117935 doi: 10.1016/j.apcatb.2019.117935
49. [49]
  Guo, L.; Niu, Y.; Xu, H.; Li, Q.; Razzaque, S.; Huang, Q.; Jin, S.; Tan, B. J. Mater. Chem. A 2018, 6, 19775. doi: 10.1039/C8TA07391K doi: 10.1039/C8TA07391K
50. [50]
  Chen, C.; Xiong, Y.; Zhong, X.; Lan, P.; Wei, Z.; Pan, H.; Su, P.; Song, Y.; Chen, Y. F.; Nafady, A.; et al. Angew. Chem. Int. Ed. 2022, 61, e202114071. doi: 10.1002/anie.202114071 doi: 10.1002/anie.202114071
51. [51]
  Kuecken, S.; Acharjya, A.; Zhi, L.; Schwarze, M.; Schomäcker, R.; Thomas, A. Chem. Commun. 2017, 53, 5854. doi: 10.1039/C7CC01827D doi: 10.1039/C7CC01827D
52. [52]
  Liu, C.; Wang, Y. C.; Yang, Q.; Li, X. Y.; Yi, F.; Liu, K. W.; Cao, H. M.; Wang, C. J.; Yan, H. J. Chem. -A Eur. J. 2021, 27, 13059. doi: 10.1002/chem.202101956 doi: 10.1002/chem.202101956
53. [53]
  Lan, Z.; Chi, X.; Wu, M.; Zhang, X.; Chen, X.; Zhang, G.; Wang, X. Small 2022, 18, 2200129. doi: 10.1002/smll.202200129 doi: 10.1002/smll.202200129
54. [54]
  Huang, W.; He, Q.; Hu, Y.; Li, Y. Angew. Chem. Int. Ed. 2019, 131, 8768. doi: 10.1002/ange.201900046 doi: 10.1002/ange.201900046
55. [55]
  Jiang, Q.; Sun, L.; Bi, J.; Liang, S.; Li, L.; Yu, Y.; Wu, L. ChemSusChem 2018, 11, 1108. doi: 10.1002/cssc.201702220 doi: 10.1002/cssc.201702220
56. [56]
  Xu, N.; Cai, B.; Li, Q.; Liu, Y.; Tang, J.; Wang, K.; Xu, B.; Fan, Y. J. Alloy. Compd. 2021, 871, 159565. doi: 10.1016/j.jallcom.2021.159565 doi: 10.1016/j.jallcom.2021.159565
57. [57]
  Liu, M.; Yang, K.; Li, Z.; Fan, E.; Fu, H.; Zhang, L.; Zhang, Y.; Zheng, Z. Chem. Commun. 2022, 58, 92. doi: 10.1039/d1cc05619k doi: 10.1039/d1cc05619k
58. [58]
  Liu, M.; Wang, X.; Liu, J.; Wang, K.; Jin, S.; Tan, B. ACS Appl. Mater. Inter. 2020, 12, 12774. doi: 10.1021/acsami.9b21903 doi: 10.1021/acsami.9b21903
59. [59]
  Zhang, S.; Cheng, G.; Guo, L.; Wang, N.; Tan, B.; Jin, S. Angew. Chem. Int. Edit. 2020, 59, 6007. doi: 10.1002/anie.201914424 doi: 10.1002/anie.201914424
60. [60]
  Meier, C. B.; Clowes, R.; Berardo, E.; Jelfs, K. E.; Zwijnenburg, M. A.; Sprick, R. S.; Cooper, A. I. Chem. Mater. 2019, 31, 8830. doi: 10.1021/acs.chemmater.9b02825 doi: 10.1021/acs.chemmater.9b02825
61. [61]
  Li, Y.; Tang, Y.; Li, J.; Chang, Y.; Huang, H.; Zhong, C. J. Mater. Sci. 2021, 56, 5772. doi: 10.1007/s10853-020-05637-9 doi: 10.1007/s10853-020-05637-9
62. [62]
  Zheng, L.; Wang, D.; Wu, S.; Jiang, X.; Zhang, J.; Xing, Q.; Zou, J.; Luo, S. J. Mater. Chem. A 2020, 8, 25425. doi: 10.1039/D0TA10165F doi: 10.1039/D0TA10165F
63. [63]
  Chen, Y.; Huang, G.; Gao, Y.; Chen, Q.; Bi, J. Int. J. Hydrog. Energy 2022, 47, 8739. doi: 10.1016/j.ijhydene.2021.12.220 doi: 10.1016/j.ijhydene.2021.12.220
64. [64]
  Liu, J.; Li, X.; Han, C.; Liu, M.; Li, X.; Sun, J.; Shao, C. Energy Environ. Mater. 2023, 6, e12404. doi: 10.1002/eem2.12404 doi: 10.1002/eem2.12404
65. [65]
  Fu, C.; Li, D.; Zhang, J.; Guo, W.; Yang, H.; Zhao, B.; Chen, Z.; Fu, X.; Liang, Z.; Jiang, L. Chem. Res. Chin. Univ. 2023, 39, 891. doi: 10.1007/s40242-023-3182-2 doi: 10.1007/s40242-023-3182-2
66. [66]
  Zhang, Z.; Xiang, K.; Wang, H.; Li, X.; Zou, J.; Liang, G.; Jiang, J. SusMat 2024, e229. doi: 10.1002/sus2.229 doi: 10.1002/sus2.229
67. [67]
  Li, Y.; Li, Y.; Yang, C.; Gan, L. J. Phys. Chem. C 2023, 127, 17732. doi: 10.1021/acs.jpcc.3c04031 doi: 10.1021/acs.jpcc.3c04031
68. [68]
  Wu, Y.; Lv, H.; Wu, X. Chin. J. Struc. Chem. 2024, 100375. doi: 10.1016/j.cjsc.2024.100375 doi: 10.1016/j.cjsc.2024.100375
69. [69]
  Yu, K.; He, P.; He, N.; Li, X.; Dong, C.; Jiang, B.; Zou, Y.; Pei, X.; Li, Y.; Ma, L. Sci. China. Mater. 2023, 66, 4680. doi: 10.1007/s40843-023-2599-9 doi: 10.1007/s40843-023-2599-9
70. [70]
  Xu, X.; Shao, C.; Zhang, J.; Wang, Z.; Dai, K. Acta Phys. -Chim. Sin. 2024, 40, 2309031. doi: 10.3866/PKU.WHXB202309031 doi: 10.3866/PKU.WHXB202309031
71. [71]
  He, H.; Wang, Z.; Zhang, J.; Shao, C.; Dai, K.; Fan, K. Adv. Funct. Mater. 2024, 34, 2315426. doi: 10.1002/adfm.202315426 doi: 10.1002/adfm.202315426
72. [72]
  Zhang, H.; Wang, Z.; Zhang, J.; Dai, K. Chin. J. Catal. 2023, 49, 42. doi: 10.1016/S1872-2067(23)64444-4 doi: 10.1016/S1872-2067(23)64444-4
73. [73]
  Yang, T.; Wang, J.; Wang, Z.; Zhang, J.; Dai, K. Chin. J. Catal. 2024, 58, 157. doi: 10.1016/S1872-2067(23)64607-8 doi: 10.1016/S1872-2067(23)64607-8
74. [74]
  Zhang, H.; Shao, C.; Wang, Z.; Zhang, J.; Dai, K. J. Mater. Sci. Technol. 2024, 195, 146. doi: 10.1016/j.jmst.2023.11.081 doi: 10.1016/j.jmst.2023.11.081
75. [75]
  Xu, Z.; Wu, Y.; Tao, R.; Jin, Z.; Fang, X. Chem. Res. Chin. Univ. 2023, 39, 928. doi: 10.1007/s40242-022-2274-8 doi: 10.1007/s40242-022-2274-8
76. [76]
  Song, P.; Du, J.; Ma, X.; Shi, Y.; Fang, X.; Liu, D.; Wei, S.; Liu, Z.; Cao, Y.; Lin, B.; et al. EcoEnergy 2023, 1, 197. doi: 10.1002/ece2.8 doi: 10.1002/ece2.8
77. [77]
  Zhan, H.; Zhou, R.; Liu, K.; Ma, Z.; Wang, P.; Zhan, S.; Zhou, Q. Sci. China. Mater. 2024, 67, 1740. doi: 10.1007/s40843-024-2900-5 doi: 10.1007/s40843-024-2900-5
78. [78]
  Zhang, P.; Li, Y.; Zhang, Y.; Hou, R.; Zhang, X.; Xue, C.; Wang, S.; Zhu, B.; Li, N.; Shao, G. Small Methods 2020, 4, 2000214. doi: 10.1002/smtd.202000214 doi: 10.1002/smtd.202000214
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  Chenye An , Sikandaier Abiduweili , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . Hierarchical S-scheme Heterojunction of Red Phosphorus Nanoparticles Embedded Flower-like CeO₂ Triggering Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-0. doi: 10.3866/PKU.WHXB202405019
6. [6]
  Jinwang Wu , Qijing Xie , Chengliang Zhang , Haifeng Shi . Rationally Designed ZnFe_1.2Co_0.8O₄/BiVO₄ S-Scheme Heterojunction with Spin-Polarization for the Elimination of Antibiotic. Acta Physico-Chimica Sinica, 2025, 41(5): 100050-0. doi: 10.1016/j.actphy.2025.100050
7. [7]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-0. doi: 10.3866/PKU.WHXB202309031
8. [8]
  Jianyu Qin , Yuejiao An , Yanfeng Zhang . In Situ Assembled ZnWO₄/g-C₃N₄ S-Scheme Heterojunction with Nitrogen Defect for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408002-0. doi: 10.3866/PKU.WHXB202408002
9. [9]
  Kaihui Huang , Boning Feng , Xinghua Wen , Lei Hao , Difa Xu , Guijie Liang , Rongchen Shen , Xin Li . Effective photocatalytic hydrogen evolution by Ti3C2-modified CdS synergized with N-doped C-coated Cu2O in S-scheme heterojunctions. Chinese Journal of Structural Chemistry, 2023, 42(12): 100204-100204. doi: 10.1016/j.cjsc.2023.100204
10. [10]
  Jiaxing Cai , Wendi Xu , Haoqiang Chi , Qian Liu , Wa Gao , Li Shi , Jingxiang Low , Zhigang Zou , Yong Zhou . Highly Efficient InOOH/ZnIn₂S₄ Hollow Sphere S-Scheme Heterojunction with 0D/2D Interface for Enhancing Photocatalytic CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(11): 2407002-0. doi: 10.3866/PKU.WHXB202407002
11. [11]
  Peng Li , Yuanying Cui , Zhongliao Wang , Graham Dawson , Chunfeng Shao , Kai Dai . Efficient interfacial charge transfer of CeO₂/Bi₁₉Br₃S₂₇ S-scheme heterojunction for boosted photocatalytic CO₂ reduction. Acta Physico-Chimica Sinica, 2025, 41(6): 100065-0. doi: 10.1016/j.actphy.2025.100065
12. [12]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . Efficient Photocatalytic Production of H₂O₂ over ZnO/D-A Conjugated Polymer S-scheme Heterojunction and Charge Transfer Dynamics Investigation. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-0. doi: 10.3866/PKU.WHXB202406027
13. [13]
  Tieping CAO , Yuejun LI , Dawei SUN . Surface plasmon resonance effect enhanced photocatalytic CO₂ reduction performance of S-scheme Bi₂S₃/TiO₂ heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 903-912. doi: 10.11862/CJIC.20240366
14. [14]
  Yang Xia , Kangyan Zhang , Heng Yang , Lijuan Shi , Qun Yi . Improving Photocatalytic H₂O₂ Production over iCOF/Bi₂O₃ S-Scheme Heterojunction in Pure Water via Dual Channel Pathways. Acta Physico-Chimica Sinica, 2024, 40(11): 2407012-0. doi: 10.3866/PKU.WHXB202407012
15. [15]
  Xinyu Miao , Hao Yang , Jie He , Jing Wang , Zhiliang Jin . Adjusting the electronic structure of Keggin-type polyoxometalates to construct S-scheme heterojunction for photocatalytic hydrogen evolution. Acta Physico-Chimica Sinica, 2025, 41(6): 100051-0. doi: 10.1016/j.actphy.2025.100051
16. [16]
  Yi Yang , Xin Zhou , Miaoli Gu , Bei Cheng , Zhen Wu , Jianjun Zhang . Femtosecond transient absorption spectroscopy investigation on ultrafast electron transfer in S-scheme ZnO/CdIn₂S₄ photocatalyst for H₂O₂ production and benzylamine oxidation. Acta Physico-Chimica Sinica, 2025, 41(6): 100064-0. doi: 10.1016/j.actphy.2025.100064
17. [17]
  Shuang Cao , Bo Zhong , Chuanbiao Bie , Bei Cheng , Feiyan Xu . Insights into Photocatalytic Mechanism of H₂ Production Integrated with Organic Transformation over WO₃/Zn_0.5Cd_0.5S S-Scheme Heterojunction. Acta Physico-Chimica Sinica, 2024, 40(5): 2307016-0. doi: 10.3866/PKU.WHXB202307016
18. [18]
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19. [19]
  Jiajie Cai , Chang Cheng , Bowen Liu , Jianjun Zhang , Chuanjia Jiang , Bei Cheng . CdS/DBTSO-BDTO S-scheme photocatalyst for H₂ production and its charge transfer dynamics. Acta Physico-Chimica Sinica, 2025, 41(8): 100084-0. doi: 10.1016/j.actphy.2025.100084
20. [20]
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu2O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production

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通讯作者: 陈斌, bchen63@163.com

Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production