非晶高熵FeCoCrMnBS氢氧化物构筑及其增强氧析出催化性能研究

引用本文: 韩鑫, 程志豪, 张金凤, 刘杰, 钟澄, 胡文彬. 非晶高熵FeCoCrMnBS氢氧化物构筑及其增强氧析出催化性能研究[J]. 物理化学学报, 2025, 41(4): 240402. doi: 10.3866/PKU.WHXB202404023 shu

Citation: Xin Han, Zhihao Cheng, Jinfeng Zhang, Jie Liu, Cheng Zhong, Wenbin Hu. Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction[J]. Acta Physico-Chimica Sinica, 2025, 41(4): 240402. doi: 10.3866/PKU.WHXB202404023 shu

非晶高熵FeCoCrMnBS氢氧化物构筑及其增强氧析出催化性能研究

韩鑫 ^1, ,
程志豪 ^1, ,
张金凤 ^1, ,
刘杰 ^{1,
,} ,
钟澄 ^{1, 2,} ,
胡文彬 ^{1, 2,}

1.
天津大学材料科学与工程学院先进陶瓷与加工技术重点实验室(教育部)以及天津复合与功能材料重点实验室, 天津 300072
2.
天津大学-新加坡国立大学福州联合学院, 福州 350207

通讯作者: 刘杰, jieliu0109@tju.edu.cn

基金项目:
国家自然科学基金项目 52271224

国家自然科学基金项目 51801134

天津市自然科学基金项目 20JCQNJC01130

摘要: 析氧反应(OER)是电解水的关键反应之一。因此，高效的析氧反应电催化剂对水的分解至关重要。本研究工作基于泡沫镍(NF)基底，成功构筑了新型FeCoCrMnBS高熵氢氧化物(HEH)催化剂。FeCoCrMnBS HEH具有由大量非晶结构的超薄纳米片构成的多孔形态。获得的FeCoCrMnBS/NF电极在碱性介质中表现出优异的OER电催化活性，在100 mA∙cm⁻²下只需要290 mV的过电位。此外，该催化剂在10 mA∙cm⁻²下显示出超过120 h的耐久性。增强的催化性能受益于独特的非晶结构以及B与S之间的正协同作用。该协同作用能够促进了硫酸盐的形成，从而削弱了OER中间体在催化剂表面的吸附。本研究为设计高效的OER电催化剂提供了一种新的设计策略。

关键词:

English

Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction

1.
Key Laboratory of Advanced Ceramics and Machining Technology (Ministry of Education), and Tianjin Key Laboratory of Composite and Functional Materials, School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China
2.
Joint School of National University of Singapore and Tianjin University, International Campus of Tianjin University, Binhai New City, Fuzhou 350207, China

Corresponding author: Jie Liu, Email: jieliu0109@tju.edu.cn

Received Date: 15 April 2024
Accepted Date: 01 July 2024
Revised Date: 30 June 2024
Available Online: 15 April 2025
Fund Project:
the National Natural Science Foundation of China

the National Natural Science Foundation of China

Tianjin Natural Science Foundation

Abstract: The efficient electrocatalysts towards the oxygen evolution reaction (OER) are vital for water splitting. Herein, a novel FeCoCrMnBS high-entropy (Oxy) hydroxide (HEH) is synthesized on a nickel foam (NF) surface via a facile approach. The FeCoCrMnBS HEH possesses a porous morphology composed of plentiful ultra-thin nanosheets with the amorphous structure. The obtained FeCoCrMnBS/NF electrode exhibits exceptional electrocatalytic OER activity in alkaline solution, requiring only 290 mV overpotential for 100 mA∙cm⁻². Moreover, this catalyst displays a long-term durability of over 120 h at 10 mA∙cm⁻². The enhanced catalytic performance benefits from the unique amorphous structure and the positive synergy effect between B and S, promoting the formation of SO₄²⁻ and thus weakening the adsorption of intermediates in OER on the catalyst surface. This work provides a new strategy for the design of desirable OER electrocatalysts.

Key words:

1. [1]
  Jia, Z.; Nomoto, K.; Wang, Q.; Kong, C.; Sun, L.; Zhang, L. -C.; Liang, S. -X.; Lu, J.; Kruzic, J. J. Adv. Funct. Mater. 2021, 31, 2101586. doi: 10.1002/adfm.202101586
2. [2]
  Chen, Z.; Huang, K.; Zhang, T.; Xia, J.; Wu, J.; Zhang, Z.; Zhang, B. Processes 2023, 11, 245. doi: 10.3390/pr11010245
3. [3]
  Lu, Y.; Huang, K.; Cao, X.; Zhang, L.; Wang, T.; Peng, D.; Zhang, B.; Liu, Z.; Wu, J.; Zhang, Y.; et al. Adv. Funct. Mater. 2022, 32, 2110645. doi: 10.1002/adfm.202110645
4. [4]
  Wang, Q.; Li, Y.; Yang, Y.; Zhang, X.; Guo, Y.; Jia, Z.; Shen, B. APL Mater. 2022, 10, 100701. doi: 10.1063/5.0117046
5. [5]
  Fu, X.; Zhang, J.; Zhan, S.; Xia, F.; Wang, C.; Ma, D.; Yue, Q.; Wu, J.; Kang, Y. ACS Catal. 2022, 12, 11955. doi: 10.1021/acscatal.2c02778
6. [6]
  Jiang, S.; Tian, K.; Li, X.; Duan, C.; Wang, D.; Wang, Z.; Sun, H.; Zheng, R.; Liu, Y. J. Colloid Interface Sci. 2022, 606, 635. doi: 10.1016/j.jcis.2021.08.060
7. [7]
  Mei, Y.; Feng, Y.; Zhang, C.; Zhang, Y.; Qi, Q.; Hu, J. ACS Catal. 2022, 12, 10808. doi: 10.1021/acscatal.2c02604
8. [8]
  Ma, P.; Zhang, S.; Zhang, M.; Gu, J.; Zhang, L.; Sun, Y.; Ji, W.; Fu, Z. Sci. China-Mater. 2020, 63, 2613. doi: 10.1007/s40843-020-1461-2
9. [9]
  Wang, S.; Huo, W.; Fang, F.; Xie, Z.; Shang, J. K.; Jiang, J. Chem. Eng. J. 2022, 429, 132410. doi: 10.1016/j.cej.2021.132410
10. [10]
  Sharma, L.; Katiyar, N. K.; Parui, A.; Das, R.; Kumar, R.; Tiwary, C. S.; Singh, A. K.; Halder, A.; Biswas, K. Nano Res. 2022, 15, 4799. doi: 10.1007/s12274-021-3802-4
11. [11]
  Zhou, P.; Liu, D.; Chen, Y.; Chen, M.; Liu, Y.; Chen, S.; Kwok, C. T.; Tang, Y.; Wang, S.; Pan, H. J. Mater. Sci. Technol. 2022, 109, 267. doi: 10.1016/j.jmst.2021.09.003
12. [12]
  Li, S. -Y.; Nguyen, T. X.; Su, Y. -H.; Lin, C. -C.; Huang, Y. -J.; Shen, Y. -H.; Liu, C. -P.; Ruan, J. -J.; Chang, K. -S.; Ting, J. -M. Small 2022, 18, 2106127. doi: 10.1002/smll.202106127
13. [13]
  Tang, J.; Xu, J. L.; Ye, Z. G.; Ma, Y. C.; Li, X. B.; Luo, J. M.; Huang, Y. Z. J. Alloy. Compd. 2021, 885, 160995. doi: 10.1016/j.jallcom.2021.160995
14. [14]
  Zhang, L.; Cai, W.; Bao, N. Adv. Mater. 2021, 33, 2100745. doi: 10.1002/adma.202100745
15. [15]
  Yang, P.; Shi, Y.; Xia, T.; Jiang, Z.; Ren, X.; Liang, L.; Shao, Q.; Zhu, K. J. Alloy. Compd. 2023, 938, 168582. doi: 10.1016/j.jallcom.2022.168582
16. [16]
  Cui, M.; Yang, C.; Li, B.; Dong, Q.; Wu, M.; Hwang, S.; Xie, H.; Wang, X.; Wang, G.; Hu, L. Adv. Energy Mater. 2021, 11, 2002887. doi: 10.1002/aenm.202002887
17. [17]
  Yu, T.; Zhang, Y.; Hu, Y.; Hu, K.; Lin, X.; Xie, G.; Liu, X.; Reddy, K. M.; Ito, Y.; Qiu, H. -J. ACS Mater. Lett. 2022, 4, 181. doi: 10.1021/acsmaterialslett.1c00762
18. [18]
  Feng, D.; Dong, Y.; Nie, P.; Zhang, L.; Qiao, Z. -A. Chem. Eng. J. 2022, 430, 132883. doi: 10.1016/j.cej.2021.132883
19. [19]
  Wu, L.; Shen, X.; Ji, Z.; Yuan, J.; Yang, S.; Zhu, G.; Chen, L.; Kong, L.; Zhou, H. Adv. Funct. Mater. 2023, 33, 2208170. doi: 10.1002/adfm.202208170
20. [20]
  Wang, G.; Chen, J.; Wen, Z.; Li, J. Sci. China-Mater. 2024, 67, 1791. doi: 10.1007/s40843-024-2967-2
21. [21]
  Ren, J. -T.; Chen, L.; Wang, H. -Y.; Yuan, Z. -Y. Inorg. Chem. Front. 2024, 11, 2029. doi: 10.1039/D4QI00103F
22. [22]
  Ren, J. -T.; Chen, L.; Wang, H. -Y.; Yuan, Z. -Y. Chem. Soc. Rev. 2023, 52, 8319. doi: 10.1039/D3CS00557G
23. [23]
  Chen, L.; Wang, L.; Ren, J. -T.; Wang, H. -Y.; Tian, W. -W.; Sun, M. -L.; Yuan, Z. -Y. Small Methods. 2024, 2400108. doi: 10.1002/smtd.202400108
24. [24]
  Huang, K.; Peng, D.; Yao, Z.; Xia, J.; Zhang, B.; Liu, H.; Chen, Z.; Wu, F.; Wu, J.; Huang, Y. Chem. Eng. J. 2021, 425, 131533. doi: 10.1016/j.cej.2021.131533
25. [25]
  Duan, C.; Li, X.; Wang, D.; Wang, Z.; Sun, H.; Zheng, R.; Liu, Y. Sustain. Energ. Fuels 2022, 6, 1479. doi: 10.1039/d1se02038b
26. [26]
  Wang, Y.; Gong, N.; Liu, H.; Ma, W.; Hippalgaonkar, K.; Liu, Z.; Huang, Y. Adv. Mater. 2023, 35, 2302067. doi: 10.1002/adma.202302067
27. [27]
  Mao, Q.; Mu, X.; Deng, K.; Yu, H.; Wang, Z.; Xu, Y.; Li, X.; Wang, L.; Wang, H. Adv. Funct. Mater. 2023, 33, 2304963. doi: 10.1002/adfm.202304963
28. [28]
  Chen, Z. -J.; Zhang, T.; Gao, X. -Y.; Huang, Y. -J.; Qin, X. -H.; Wang, Y. -F.; Zhao, K.; Peng, X.; Zhang, C.; Liu, L.; et al. Adv. Mater. 2021, 33, 2101845. doi: 10.1002/adma.202101845
29. [29]
  Bai, Y.; Wu, Y.; Zhou, X.; Ye, Y.; Nie, K.; Wang, J.; Xie, M.; Zhang, Z.; Liu, Z.; Cheng, T.; et al. Nat. Commun. 2022, 13, 6094. doi: 10.1038/s41467-022-33846-0
30. [30]
  Hu, Y.; Zheng, Y.; Jin, J.; Wang, Y.; Peng, Y.; Yin, J.; Shen, W.; Hou, Y.; Zhu, L.; An, L.; et al. Nat. Commun. 2023, 14, 1949. doi: 10.1038/s41467-023-37751-y
31. [31]
  Zhao, K.; Li, X.; Su, D. Acta Phys. -Chim. Sin. 2021, 37, 2009077. doi: 10.3866/PKU.WHXB202009077
32. [32]
  Zhang, X.; Qiu, Y.; Li, Q.; Ji, X.; Liu, J. J. Power Sources 2022, 522, 231004. doi: 10.1016/j.jpowsour.2022.231004
33. [33]
  Nemani, S. K.; Zhang, B.; Wyatt, B. C.; Hood, Z. D.; Manna, S.; Khaledialidusti, R.; Hong, W.; Sternberg, M. G.; Sankaranarayanan, S. K. R. S.; Anasori, B. ACS Nano 2021, 15, 12815. doi: 10.1021/acsnano.1c02775
34. [34]
  Glasscott, M. W.; Pendergast, A. D.; Goines, S.; Bishop, A. R.; Hoang, A. T.; Renault, C.; Dick, J. E. Nat. Commun. 2019, 10, 2650. doi: 10.1038/s41467-019-10303-z
35. [35]
  Yao, Y.; Huang, Z.; Xie, P.; Lacey, S. D.; Jacob, R. J.; Xie, H.; Chen, F.; Nie, A.; Pu, T.; Rehwoldt, M.; et al. Science 2018, 359, 1489. doi: 10.1126/science.aan5412
36. [36]
  Baek, J.; Hossain, M. D.; Mukherjee, P.; Lee, J.; Winther, K. T.; Leem, J.; Jiang, Y.; Chueh, W. C.; Bajdich, M.; Zheng, X. Nat. Commun. 2023, 14, 5936. doi: 10.1038/s41467-023-41359-7
37. [37]
  Zhou, P.; Wong, P. K.; Niu, P.; Chen, M.; Kwok, C. T.; Tang, Y.; Li, R.; Wang, S.; Pan, H. Sci. China-Mater. 2023, 66, 1033. doi: 10.1007/s40843-022-2234-5
38. [38]
  Yao, Y.; Li, Z.; Dou, Y.; Jiang, T.; Zou, J.; Lim, S. Y.; Norby, P.; Stamate, E.; Jensen, J. O.; Zhang, W. Dalton Trans. 2023, 52, 4142. doi: 10.1039/d2dt03637a
39. [39]
  Antink, W. H.; Lee, S.; Lee, H. S.; Shin, H.; Yoo, T. Y.; Ko, W.; Shim, J.; Na, G.; Sung, Y. -E.; Hyeon, T. Adv. Funct. Mater. 2023, 34, 2309438. doi: 10.1002/adfm.202309438
40. [40]
  Lin, L.; Ding, Z.; Karkera, G.; Diemant, T.; Kante, M. V. V.; Agrawal, D.; Hahn, H.; Aghassi-Hagmann, J.; Fichtner, M.; Breitung, B.; et al. Small Struct. 2023, 4, 2300012. doi: 10.1002/sstr.202300012
41. [41]
  Qiu, H. -J.; Fang, G.; Gao, J.; Wen, Y.; Lv, J.; Li, H.; Xie, G.; Liu, X.; Sun, S. ACS Mater. Lett. 2019, 1, 526. doi: 10.1021/acsmaterialslett.9b00414
42. [42]
  Zhu, H.; Zhu, Z.; Hao, J.; Sun, S.; Lu, S.; Wang, C.; Ma, P.; Dong, W.; Du, M. Chem. Eng. J. 2022, 431, 133251. doi: 10.1016/j.cej.2021.133251
43. [43]
  Lu, Y.; Xu, S.; Zhang, L.; Hu, Q.; Song, J.; Zhang, F.; Zhang, B. Sustain. Mater. Technol. 2022, 33, e00455. doi: 10.1016/j.susmat.2022.e00455
44. [44]
  Liu, L. -H.; Li, N.; Han, M.; Han, J. -R.; Liang, H. -Y. Rare Metals 2022, 41, 125. doi: 10.1007/s12598-021-01760-x
45. [45]
  Zhang, Y.; Dai, W.; Zhang, P.; Lu, T.; Pan, Y. J. Alloy. Compd. 2021, 868, 159064. doi: 10.1016/j.jallcom.2021.159064
46. [46]
  Xue, Y.; Fang, J.; Wang, X.; Xu, Z.; Zhang, Y.; Lv, Q.; Liu, M.; Zhu, W.; Zhuang, Z. Adv. Funct. Mater. 2021, 31, 2101405. doi: 10.1002/adfm.202101405
47. [47]
  Chen, M.; Kitiphatpiboon, N.; Feng, C.; Zhao, Q.; Abudula, A.; Ma, Y.; Yan, K.; Guan, G. Appl. Catal. B-Environ. 2023, 330, 122577. doi: 10.1016/j.apcatb.2023.122577
48. [48]
  Wei, R.; Zhang, K.; Zhao, P.; An, Y.; Tang, C.; Chen, C.; Li, X.; Ma, X.; Ma, Y.; Hao, X. Appl. Surf. Sci. 2021, 549, 149327. doi: 10.1016/j.apsusc.2021.149327
49. [49]
  Wang, H.; Wei, R.; Li, X.; Ma, X.; Hao, X.; Guan, G. J. Mater. Sci. Technol. 2021, 68, 191. doi: 10.1016/j.jmst.2020.06.045
50. [50]
  Nguyen, T. X.; Su, Y. -H.; Lin, C. -C.; Ting, J. -M. Adv. Funct. Mater. 2021, 31, 2106229. doi: 10.1002/adfm.202106229
51. [51]
  Hu, R.; Wei, L. Y.; Xian, J. L.; Fang, G. Y.; Wu, Z.; Fan, M.; Guo, J. Y.; Li, Q. X.; Liu, K. S.; Jiang, H. Y.; et al. Acta Phys. Chim. Sin. 2023, 39, 2212025. doi: 10.3866/pku.Whxb202212025
52. [52]
  Wang, Y.; Jia, D.; Zhang, W.; Jia, G.; Xie, H.; Ye, W.; Zhu, G.; Gao, P. Chem. Commun. 2022, 58, 6132. doi: 10.1039/d2cc00696k
53. [53]
  Shi, Y.; Du, W.; Zhou, W.; Wang, C.; Lu, S.; Lu, S.; Zhang, B. Angew. Chem. -Int. Edit. 2020, 59, 22470. doi: 10.1002/anie.202011097
54. [54]
  Anantharaj, S.; Noda, S. Small 2020, 16, 1905779. doi: 10.1002/smll.201905779

扫一扫看文章

计量

PDF下载量: 0
文章访问数: 666
HTML全文浏览量: 60

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

非晶高熵FeCoCrMnBS氢氧化物构筑及其增强氧析出催化性能研究

通讯作者: 刘杰, jieliu0109@tju.edu.cn

English

Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction

Corresponding author: Jie Liu, Email: jieliu0109@tju.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

非晶高熵FeCoCrMnBS氢氧化物构筑及其增强氧析出催化性能研究

通讯作者: 刘杰, jieliu0109@tju.edu.cn

English

Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction

Corresponding author: Jie Liu, Email: jieliu0109@tju.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs