Cu-石墨炔/双金属钨酸盐S型异质结协同增强光催化析氢

引用本文: 周正宇, 姚惠琴, 吴有林, 李腾, 椿范立, 靳治良. Cu-石墨炔/双金属钨酸盐S型异质结协同增强光催化析氢[J]. 物理化学学报, 2024, 40(10): 231201. doi: 10.3866/PKU.WHXB202312010 shu

Citation: Zhengyu Zhou, Huiqin Yao, Youlin Wu, Teng Li, Noritatsu Tsubaki, Zhiliang Jin. Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution[J]. Acta Physico-Chimica Sinica, 2024, 40(10): 231201. doi: 10.3866/PKU.WHXB202312010 shu

Cu-石墨炔/双金属钨酸盐S型异质结协同增强光催化析氢

周正宇 ^1, ,
姚惠琴 ^{2,
,} ,
吴有林 ^1, ,
李腾 ^1,3, ,
椿范立 ^{3,
,} ,
靳治良 ^{1,
,}

1.
北方民族大学化学与化学工程学院, 银川 750021;
2.
宁夏医科大学基础医学院化学系, 银川 750004;
3.
Department of Applied Chemistry, Graduate School of Engineering, University of Toyama, Gofuku 3190, Toyama 930-8555, Japan

通讯作者: 姚惠琴,Email:yaohq@nxmu.edu.cn; 椿范立,Email:tsubaki@eng.u-toyama.ac.jp; 靳治良,Email:zl-jin@nun.edu.cn

基金项目:
宁夏回族自治区自然科学基金（2023AAC02046）资助

摘要: 采用有机法和水热法合成了Cu-石墨炔和CoNiWO₄并构建Cu-石墨炔/CoNiWO₄ S型异质结。在保留催化剂强氧化还原能力的同时，通过内建电场和能带弯曲的协同作用促进了光生载流子的高效分离和转移。Cu-石墨炔的引入有效提高了复合催化剂的光吸收能力和导电性，抑制了光生载流子的复合。同时，Cu-石墨炔独特的二维平面网络结构提供了丰富的活性位点，从而促进了光催化反应的进行。密度泛函理论（DFT）计算表明，Cu的表面等离子体共振效应产生的热电子转移到石墨炔上，促进氢气的析出。本研究为Cu-石墨炔和镍钴基催化剂在光催化制氢领域提供了新的参考。

关键词:

English

Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution

Zhengyu Zhou ^1, ,
Huiqin Yao ^{2,
,} ,
Youlin Wu ^1, ,
Teng Li ^1,3, ,
Noritatsu Tsubaki ^{3,
,} ,
Zhiliang Jin ^{1,
,}

1.
School of Chemistry and Chemical Engineering, North Minzu University, Yinchuan 750021, China;
2.
Department of Chemistry, College of Basic Medicine, Ningxia Medical University, Yinchuan 750004, China;
3.
Department of Applied Chemistry, Graduate School of Engineering, University of Toyama, Gofuku 3190, Toyama 930-8555, Japan

Corresponding author: Huiqin Yao, ; Noritatsu Tsubaki, ; Zhiliang Jin,

Received Date: 08 December 2023
Accepted Date: 08 January 2024
Revised Date: 08 January 2024
Available Online: 11 January 2024
Fund Project:
The project was supported by the Ningxia Hui Autonomous Region Natural Science Foundation Project (2023AAC02046).

Abstract: Cu-Graphdiyne and CoNiWO₄ were synthesized by organic and hydrothermal methods, respectively. The establishment of an S-scheme heterojunction between Cu-Graphdiyne and CoNiWO₄ was achieved by interface engineering design. The efficient separation and transfer of photogenerated carriers are facilitated by the synergistic effect of the built-in electric field and band bending, while maintaining the strong redox capacity of the catalysts. The introduction of Cu-Graphdiyne effectively enhances the photo absorption capacity and conductivity of the composite catalyst, and significantly suppresses the recombination of photogenerated carriers. The unique two-dimensional planar network structure of Cu-Graphdiyne provides abundant active sites for photocatalytic processes, thereby facilitating the photocatalytic reaction. Density functional theory (DFT) calculations demonstrate that hot electrons generated by surface plasmon resonance effects of Cu will transfer to Graphdiyne to promote hydrogen evolution reaction. This study offers insights into potential applications of Cu-Graphdiyne and nickel-cobalt based catalysts in photocatalytic hydrogen evolution.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

Cu-石墨炔/双金属钨酸盐S型异质结协同增强光催化析氢

通讯作者: 姚惠琴,Email:yaohq@nxmu.edu.cn; 椿范立,Email:tsubaki@eng.u-toyama.ac.jp; 靳治良,Email:zl-jin@nun.edu.cn

English

Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution

Corresponding author: Huiqin Yao, ; Noritatsu Tsubaki, ; Zhiliang Jin,

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中国化学会秘书处

Cu-石墨炔/双金属钨酸盐S型异质结协同增强光催化析氢

通讯作者: 姚惠琴,Email:yaohq@nxmu.edu.cn; 椿范立,Email:tsubaki@eng.u-toyama.ac.jp; 靳治良,Email:zl-jin@nun.edu.cn

English

Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution

Corresponding author: Huiqin Yao, ; Noritatsu Tsubaki, ; Zhiliang Jin,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

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CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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