内建电场与偶极场协同增强SnNb2O6/富氮C3N5 S型异质结光催化性能

引用本文: 刘倩倩, 杜兴, 李宛飞, 戴维林, 刘波. 内建电场与偶极场协同增强SnNb₂O₆/富氮C₃N₅ S型异质结光催化性能[J]. 物理化学学报, 2024, 40(10): 231101. doi: 10.3866/PKU.WHXB202311016 shu

Citation: Qianqian Liu, Xing Du, Wanfei Li, Wei-Lin Dai, Bo Liu. Synergistic Effects of Internal Electric and Dipole Fields in SnNb₂O₆/Nitrogen-Enriched C₃N₅ S-Scheme Heterojunction for Boosting Photocatalytic Performance[J]. Acta Physico-Chimica Sinica, 2024, 40(10): 231101. doi: 10.3866/PKU.WHXB202311016 shu

内建电场与偶极场协同增强SnNb₂O₆/富氮C₃N₅ S型异质结光催化性能

刘倩倩 ^{1,,
,} ,
杜兴 ^1, ,
李宛飞 ^1,2, ,
戴维林 ^{3,
,} ,
刘波 ^{1,
,}

1.
苏州科技大学, 材料科学与工程学院, 苏州市微纳光电材料与传感器重点实验室, 江苏苏州 215009;
2.
姑苏实验室, 江苏苏州 215123;
3.
复旦大学, 化学系, 上海市分子催化与创新材料重点实验室, 上海 200433

通讯作者: 刘倩倩,Email:liuqianqian@usts.edu.cn; 戴维林,Email:wldai@fudan.edu.cn; 刘波,Email:liubo@mail.usts.edu.cn

基金项目:
国家自然科学基金项目（22002102，61904118，62205231），江苏省研究生科研与实践创新项目（SJCX22_1555），江苏省环境功能材料重点实验室资助

摘要: 定向电荷转移是调控光生载流子分离动力学的一种极具吸引力的策略。本文通过在SnNb₂O₆纳米片上原位生长C₃N₅纳米棒，设计一种具有强内建电场（IEF）和偶极场（DF）的新型2D/1D SnNb₂O₆/富氮C₃N₅ S型异质结。通过构筑S型异质结，在界面处产生IEF，促进电荷从SnNb₂O₆向C₃N₅的定向迁移。与此同时，C₃N₅中的DF提供一种驱动力，将光生电子定向转移至活性位点。通过IEF和DF的协同效应，SnNb₂O₆/C₃N₅异质结实现了快速的定向电子转移，从而显著提高了电荷分离效率。研究结果表明，SnNb₂O₆/C₃N₅异质结的最佳产氢速率高达1090.0 μmol·g^-1·h^-1 （反应过程中持续释放H₂气泡），分别是SnNb₂O₆和C₃N₅的38.8和10.7倍。此外，SnNb₂O₆/C₃N₅异质结在去除罗丹明B、四环素和Cr（Ⅵ）方面也表现出优异的光催化性能。通过电子顺磁共振（EPR）、时间分辨光致发光光谱（TPRL）和密度泛函理论（DFT）计算，本文系统探讨了SnNb₂O₆/C₃N₅异质结的定向电荷转移机制。这项研究为开发高效异质结光催化剂提供了一种可行的方法。

关键词:

English

Synergistic Effects of Internal Electric and Dipole Fields in SnNb₂O₆/Nitrogen-Enriched C₃N₅ S-Scheme Heterojunction for Boosting Photocatalytic Performance

Qianqian Liu ^{1,,
,} ,
Xing Du ^1, ,
Wanfei Li ^1,2, ,
Wei-Lin Dai ^{3,
,} ,
Bo Liu ^{1,
,}

1.
Suzhou Key Laboratory for Nanophotonic and Nanoelectronic Materials and Its Devices, School of Materials Science and Engineering, Suzhou University of Science and Technology, Suzhou 215009, Jiangsu Province, China;
2.
Gusu Lab Mat, Suzhou 215123, Jiangsu Province, China;
3.
Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, China

Corresponding author: Qianqian Liu, ; Wei-Lin Dai, ; Bo Liu,

Received Date: 10 November 2023
Accepted Date: 18 December 2023
Revised Date: 15 December 2023
Available Online: 02 January 2024
Fund Project:
This work is supported by National Natural Science Foundation of China (22002102, 61904118, 62205231), Postgraduate Research & Practice Innovation Program of Jiangsu Province (SJCX22_1555) and Jiangsu Key Laboratory for Environment Functional Materials.

Abstract: Directional electron transfer is an appealing strategy for harnessing photogenerated charge separation kinetics. Herein, a novel 2D/1D SnNb₂O₆/nitrogen-enriched C₃N₅ S-scheme heterojunction with strong internal electric field (IEF) and dipole field (DF) is designed through in situ growth of C₃N₅ nanorods on SnNb₂O₆ nanosheets. The IEF generated at the interface via the formation of the S-scheme heterojunction induces directional charge transfer from SnNb₂O₆ to C₃N₅. Simultaneously, the DF within C₃N₅ provides the impetus to guide photo-excited electrons to the active sites. Consequently, the synergistic effects of IEF and DF facilitate swift directional electron transfer. The optimized SnNb₂O₆/C₃N₅ heterojunction demonstrates a remarkable H₂ production rate of 1090.0 μmol·g^-1·h^-1 with continuous release of H₂ bubbles. This performance surpasses that of SnNb₂O₆ and C₃N₅ by 38.8 and 10.7 times, respectively. Additionally, the SnNb₂O₆/C₃N₅ heterojunction exhibits superior activity in the removal of Rhodamine B, tetracycline, and Cr(VI). Based on electron paramagnetic resonance (EPR), time-resolved photoluminescence (TPRL) and density functional theory (DFT) calculations, etc., the directional charge transfer mechanism was systematically explored. The research furnishes a plausible approach to construct effective heterojunction photocatalysts for applications in energy and environmental domains.

Key words:

1. [1]
  (1) Liu, Q.; Du, X.; Gu, H.; Cheng, M.; Hu, J.; Wei, T.; Li, W.; Liu, B.; Dai, W.-L. J. Phys. D: Appl. Phys. 2022,55, 484002. doi: 10.1088/1361-6463/ac962e(1) Liu, Q.; Du, X.; Gu, H.; Cheng, M.; Hu, J.; Wei, T.; Li, W.; Liu, B.; Dai, W.-L. J. Phys. D: Appl. Phys. 2022,55, 484002. doi: 10.1088/1361-6463/ac962e
2. [2]
  (2) Zhang, H.; Wang, Z.; Zhang, J.; Dai, K. Chin. J. Catal. 2023, 49, 42. doi: 10.1016/S1872-2067(23)64444-4(2) Zhang, H.; Wang, Z.; Zhang, J.; Dai, K. Chin. J. Catal. 2023, 49, 42. doi: 10.1016/S1872-2067(23)64444-4
3. [3]
  (3) Zhao, Z.; Wang, Z.; Zhang, J.; Shao, C.; Dai, K.; Fan, K.; Liang, C. Adv. Funct. Mater. 2023, 33, 2214470. doi: 10.1002/adfm.202214470(3) Zhao, Z.; Wang, Z.; Zhang, J.; Shao, C.; Dai, K.; Fan, K.; Liang, C. Adv. Funct. Mater. 2023, 33, 2214470. doi: 10.1002/adfm.202214470
4. [4]
  (4) Liu, L.; Wang, Z.; Zhang, J.; Ruzimuradov, O.; Dai, K.; Low, J. Adv. Mater. 2023, 35, 2300643. doi: 10.1002/adma.202300643(4) Liu, L.; Wang, Z.; Zhang, J.; Ruzimuradov, O.; Dai, K.; Low, J. Adv. Mater. 2023, 35, 2300643. doi: 10.1002/adma.202300643
5. [5]
  (5) Shi, W.-L.; Xu, Z.; Shi, Y.-X.; Li, L.-L.; Lu, J.-L.; Sun, X.-H.; Du, X.; Guo, F.; Lu, C.-Y. Rare Met. 2023,43, 198. doi: 10.1007/s12598-023-02403-z(5) Shi, W.-L.; Xu, Z.; Shi, Y.-X.; Li, L.-L.; Lu, J.-L.; Sun, X.-H.; Du, X.; Guo, F.; Lu, C.-Y. Rare Met. 2023,43, 198. doi: 10.1007/s12598-023-02403-z
6. [6]
  (6) Yang, F.; Zhang, Q.; Zhang, J.; Zhang, L.; Cao, M.; Dai, W.-L. Appl. Catal. B-Environ. 2020, 278, 119290. doi: 10.1016/j.apcatb.2020.119290(6) Yang, F.; Zhang, Q.; Zhang, J.; Zhang, L.; Cao, M.; Dai, W.-L. Appl. Catal. B-Environ. 2020, 278, 119290. doi: 10.1016/j.apcatb.2020.119290
7. [7]
  (7) Li, S.; Dong, K.; Cai, M.; Li, X.; Chen, X. eScience 2023, 100208. doi: 10.1016/j.esci.2023.100208(7) Li, S.; Dong, K.; Cai, M.; Li, X.; Chen, X. eScience 2023, 100208. doi: 10.1016/j.esci.2023.100208
8. [8]
  (8) Gu, H.; Zhang, H.; Wang, X.; Li, Q.; Chang, S.; Huang, Y.; Gao, L.; Cui, Y.; Liu, R.; Dai, W.-L. Appl. Catal. B-Environ. 2023, 328, 122537. doi: 10.1016/j.apcatb.2023.122537(8) Gu, H.; Zhang, H.; Wang, X.; Li, Q.; Chang, S.; Huang, Y.; Gao, L.; Cui, Y.; Liu, R.; Dai, W.-L. Appl. Catal. B-Environ. 2023, 328, 122537. doi: 10.1016/j.apcatb.2023.122537
9. [9]
  (9) Lei, Z.; Ma, X.; Hu, X.; Fan, J.; Liu, E. Acta Phys. -Chim. Sin. 2022, 38, 2110049. [雷卓楠, 马心怡, 胡晓云, 樊君, 刘恩周. 物理化学学报, 2022, 38, 2110049.] doi: 10.3866/PKU.WHXB202110049
10. [10]
  (10) Luo, C.; Long, Q.; Cheng, B.; Zhu, B.; Wang, L. Acta Phys. -Chim. Sin. 2023, 39, 2212026. [罗铖, 龙庆, 程蓓, 朱必成, 王临曦. 物理化学学报, 2023, 39, 2212026.] doi: 10.3866/PKU.WHXB202212026
11. [11]
  (11) Li, L.; Zhang, Q.; Wang, X.; Zhang, J.; Gu, H.; Dai, W.-L. J. Phys. Chem. C 2021, 125, 10964. doi: 10.1021/acs.jpcc.1c02269(11) Li, L.; Zhang, Q.; Wang, X.; Zhang, J.; Gu, H.; Dai, W.-L. J. Phys. Chem. C 2021, 125, 10964. doi: 10.1021/acs.jpcc.1c02269
12. [12]
  (12) Yin, F.; Qin, P.; Xu, J.; Cao, S. Acta Phys. -Chim. Sin. 2023, 39, 2212062. [殷方鑫, 秦品权, 许景三, 曹少文. 物理化学学报, 2023, 39, 2212062.] doi: 10.3866/PKU.WHXB202212062
13. [13]
  (13) Chellapandi, T.; Madhumitha, G.; Roopan, S. M.; Manjupriya, R.; Arunachalapandi, M.; Pouthika, K.; Elamathi, M. Sep. Purif. Technol. 2023, 307, 122865. doi: 10.1016/j.seppur.2022.122865(13) Chellapandi, T.; Madhumitha, G.; Roopan, S. M.; Manjupriya, R.; Arunachalapandi, M.; Pouthika, K.; Elamathi, M. Sep. Purif. Technol. 2023, 307, 122865. doi: 10.1016/j.seppur.2022.122865
14. [14]
  (14) Xiong, Z.; Liang, Y.; Yang, J.; Yang, G.; Jia, J.; Sa, K.; Zhang, X.; Zeng, Z. Sep. Purif. Technol. 2023, 306, 122522. doi: 10.1016/j.seppur.2022.122522(14) Xiong, Z.; Liang, Y.; Yang, J.; Yang, G.; Jia, J.; Sa, K.; Zhang, X.; Zeng, Z. Sep. Purif. Technol. 2023, 306, 122522. doi: 10.1016/j.seppur.2022.122522
15. [15]
  (15) Li, Z.; Zhou, Y.; Zhou, Y.; Wang, K.; Yun, Y.; Chen, S.; Jiao, W.; Chen, L.; Zou, B.; Zhu, M. Nat. Commun. 2023, 14, 5742. doi: 10.1038/s41467-023-41522-0(15) Li, Z.; Zhou, Y.; Zhou, Y.; Wang, K.; Yun, Y.; Chen, S.; Jiao, W.; Chen, L.; Zou, B.; Zhu, M. Nat. Commun. 2023, 14, 5742. doi: 10.1038/s41467-023-41522-0
16. [16]
  (16) Liu, Z.; Zhang, C.; Liu, L.; Zhang, T.; Wang, J.; Wang, R.; Du, T.; Yang, C.; Zhang, L.; Xie, L.; et al.. Adv. Mater. 2021, 33, 2104099. doi: 10.1002/adma.202104099(16) Liu, Z.; Zhang, C.; Liu, L.; Zhang, T.; Wang, J.; Wang, R.; Du, T.; Yang, C.; Zhang, L.; Xie, L.; et al.. Adv. Mater. 2021, 33, 2104099. doi: 10.1002/adma.202104099
17. [17]
  (17) Zhang, J.; Gu, H.; Wang, X.; Zhang, H.; Chang, S.; Li, Q.; Dai, W.-L. J. Colloid Interface Sci. 2022,625, 785. doi: 10.1016/j.jcis.2022.06.074(17) Zhang, J.; Gu, H.; Wang, X.; Zhang, H.; Chang, S.; Li, Q.; Dai, W.-L. J. Colloid Interface Sci. 2022,625, 785. doi: 10.1016/j.jcis.2022.06.074
18. [18]
  (18) Zhu, B.; Liu, J.; Sun, J.; Xie, F.; Tan, H.; Cheng, B.; Zhang, J. J. Mater. Sci. Technol. 2023,162, 90. doi: 10.1016/j.jmst.2023.03.054(18) Zhu, B.; Liu, J.; Sun, J.; Xie, F.; Tan, H.; Cheng, B.; Zhang, J. J. Mater. Sci. Technol. 2023,162, 90. doi: 10.1016/j.jmst.2023.03.054
19. [19]
  (19) Xu, Q.; Zhang, L.; Cheng, B.; Fan, J.; Yu, J. Chem 2020, 6, 1543. doi: 10.1016/j.chempr.2020.06.010(19) Xu, Q.; Zhang, L.; Cheng, B.; Fan, J.; Yu, J. Chem 2020, 6, 1543. doi: 10.1016/j.chempr.2020.06.010
20. [20]
  (20) Wang, Z.; Wang, J.; Zhang, J.; Dai, K. Acta Phys. -Chim. Sin. 2023, 39, 2209037. [王中辽, 汪静, 张金锋, 代凯. 物理化学学报, 2023, 39, 2209037.] doi: 10.3866/PKU.WHXB202209037
21. [21]
  (21) Wang, J.; Zhang, Q.; Deng, F.; Luo, X.; Dionysiou, D. D. Chem. Eng. J. 2020, 379, 122264. doi: 10.1016/j.cej.2019.122264(21) Wang, J.; Zhang, Q.; Deng, F.; Luo, X.; Dionysiou, D. D. Chem. Eng. J. 2020, 379, 122264. doi: 10.1016/j.cej.2019.122264
22. [22]
  (22) Li, S.; Yan, R.; Cai, M.; Jiang, W.; Zhang, M.; Li, X. J. Mater. Sci. Technol. 2023, 164, 59. doi: 10.1016/j.jmst.2023.05.009(22) Li, S.; Yan, R.; Cai, M.; Jiang, W.; Zhang, M.; Li, X. J. Mater. Sci. Technol. 2023, 164, 59. doi: 10.1016/j.jmst.2023.05.009
23. [23]
  (23) He, B.; Xiao, P.; Wan, S.; Zhang, J.; Chen, T.; Zhang, L.; Yu, J. Angew. Chem. Int. Ed. 2023, e202313172. doi: 10.1002/anie.202313172(23) He, B.; Xiao, P.; Wan, S.; Zhang, J.; Chen, T.; Zhang, L.; Yu, J. Angew. Chem. Int. Ed. 2023, e202313172. doi: 10.1002/anie.202313172
24. [24]
  (24) Sun, T.; Li, C.; Bao, Y.; Fan, J.; Liu, E. Acta Phys. -Chim. Sin. 2023, 39, 2212009. [孙涛, 李晨曦, 鲍钰鹏, 樊君, 刘恩周. 物理化学学报, 2023, 39, 2212009.] doi: 10.3866/PKU.WHXB202212009
25. [25]
  (25) Cheng, C.; He, B.; Fan, J.; Cheng, B.; Cao, S.; Yu, J. Adv. Mater. 2021, 33, 2100317. doi: 10.1002/adma.202100317(25) Cheng, C.; He, B.; Fan, J.; Cheng, B.; Cao, S.; Yu, J. Adv. Mater. 2021, 33, 2100317. doi: 10.1002/adma.202100317
26. [26]
  (26) Liu, Q.; Zhang, Q.; Liu, B.; Dai, W.-L. Nanotechnology 2021, 32, 065705. doi: 10.1088/1361-6528/abc3e3(26) Liu, Q.; Zhang, Q.; Liu, B.; Dai, W.-L. Nanotechnology 2021, 32, 065705. doi: 10.1088/1361-6528/abc3e3
27. [27]
  (27) Wang, Z.; Wang, H.; Shi, Y.; Liu, C.; Wu, L. Chem. Eng. J. 2022, 429, 132018. doi: 10.1016/j.cej.2021.132018(27) Wang, Z.; Wang, H.; Shi, Y.; Liu, C.; Wu, L. Chem. Eng. J. 2022, 429, 132018. doi: 10.1016/j.cej.2021.132018
28. [28]
  (28) Cao, J.-T.; Ma, Y.; Lv, J.-L.; Ren, S.-W.; Liu, Y.-M. Chem. Commun. 2020, 56, 1513. doi: 10.1039/C9CC09102E(28) Cao, J.-T.; Ma, Y.; Lv, J.-L.; Ren, S.-W.; Liu, Y.-M. Chem. Commun. 2020, 56, 1513. doi: 10.1039/C9CC09102E
29. [29]
  (29) Wang, H.; Li, M.; Lu, Q.; Cen, Y.; Zhang, Y.; Yao, S. ACS Sustain. Chem. Eng. 2019, 7, 625. doi: 10.1021/acssuschemeng.8b04182(29) Wang, H.; Li, M.; Lu, Q.; Cen, Y.; Zhang, Y.; Yao, S. ACS Sustain. Chem. Eng. 2019, 7, 625. doi: 10.1021/acssuschemeng.8b04182
30. [30]
  (30) Liang, S.; Liang, R.; Wen, L.; Yuan, R.; Wu, L.; Fu, X. Appl. Catal. B-Environ. 2012, 125, 103. doi: 10.1016/j.apcatb.2012.05.017(30) Liang, S.; Liang, R.; Wen, L.; Yuan, R.; Wu, L.; Fu, X. Appl. Catal. B-Environ. 2012, 125, 103. doi: 10.1016/j.apcatb.2012.05.017
31. [31]
  (31) Yuan, L.; Yang, M.-Q.; Xu, Y.-J.Nanoscale 2014, 6, 6335. doi: 10.1039/C4NR00116H(31) Yuan, L.; Yang, M.-Q.; Xu, Y.-J.Nanoscale 2014, 6, 6335. doi: 10.1039/C4NR00116H
32. [32]
  (32) Vadivel, S.; Hariganesh, S.; Paul, B.; Rajendran, S.; Habibi-Yangjeh, A.; Maruthamani, D.; Kumaravel, M. Chem. Phys. Lett. 2020, 738, 136862. doi: 10.1016/j.cplett.2019.136862(32) Vadivel, S.; Hariganesh, S.; Paul, B.; Rajendran, S.; Habibi-Yangjeh, A.; Maruthamani, D.; Kumaravel, M. Chem. Phys. Lett. 2020, 738, 136862. doi: 10.1016/j.cplett.2019.136862
33. [33]
  (33) Pagacz-Kostrzewa, M.; Bronisz, R.; Wierzejewska, M. Chem. Phys. Lett. 2009, 473, 238. doi: 10.1016/j.cplett.2009.03.079(33) Pagacz-Kostrzewa, M.; Bronisz, R.; Wierzejewska, M. Chem. Phys. Lett. 2009, 473, 238. doi: 10.1016/j.cplett.2009.03.079
34. [34]
  (34) Xu, Q.; Zhu, B.; Jiang, C.; Cheng, B.; Yu, J. Sol. RRL2018, 2, 1800006. doi: 10.1002/solr.201800006(34) Xu, Q.; Zhu, B.; Jiang, C.; Cheng, B.; Yu, J. Sol. RRL2018, 2, 1800006. doi: 10.1002/solr.201800006
35. [35]
  (35) Katritzky, A. R. Chem. Heterocycl. Compd. 1972, 8, 917. doi: 10.1007/BF00476314(35) Katritzky, A. R. Chem. Heterocycl. Compd. 1972, 8, 917. doi: 10.1007/BF00476314
36. [36]
  (36) Yu, H.; Shi, R.; Zhao, Y.; Bian, T.; Zhao, Y.; Zhou, C.; Waterhouse, G. I. N.; Wu, L.-Z.; Tung, C.-H.; Zhang, T.Adv. Mater. 2017, 29, 1605148. doi: 10.1002/adma.201605148(36) Yu, H.; Shi, R.; Zhao, Y.; Bian, T.; Zhao, Y.; Zhou, C.; Waterhouse, G. I. N.; Wu, L.-Z.; Tung, C.-H.; Zhang, T.Adv. Mater. 2017, 29, 1605148. doi: 10.1002/adma.201605148
37. [37]
  (37) Hu, T.; Dai, K.; Zhang, J.; Chen, S. Appl. Catal. B-Environ. 2020, 269, 118844. doi: 10.1016/j.apcatb.2020.118844(37) Hu, T.; Dai, K.; Zhang, J.; Chen, S. Appl. Catal. B-Environ. 2020, 269, 118844. doi: 10.1016/j.apcatb.2020.118844
38. [38]
  (38) Wang, Z.; Liu, R.; Zhang, J.; Dai, K. Chin. J. Struc. Chem. 2022, 41, 2206015. doi: 10.14102/j.cnki.0254-5861.2022-0108(38) Wang, Z.; Liu, R.; Zhang, J.; Dai, K. Chin. J. Struc. Chem. 2022, 41, 2206015. doi: 10.14102/j.cnki.0254-5861.2022-0108
39. [39]
  (39) Wang, L.; Chen, R.; Zhang, Z.; Chen, X.; Ding, J.; Zhang, J.; Wan, H.; Guan, G. J. Environ. Chem. Eng. 2023,11, 109345. doi: 10.1016/j.jece.2023.109345(39) Wang, L.; Chen, R.; Zhang, Z.; Chen, X.; Ding, J.; Zhang, J.; Wan, H.; Guan, G. J. Environ. Chem. Eng. 2023,11, 109345. doi: 10.1016/j.jece.2023.109345
40. [40]
  (40) Cui, Y.; Zhang, G.; Lin, Z.; Wang, X. Appl. Catal. B-Environ. 2016, 181, 413. doi: 10.1016/j.apcatb.2015.08.018(40) Cui, Y.; Zhang, G.; Lin, Z.; Wang, X. Appl. Catal. B-Environ. 2016, 181, 413. doi: 10.1016/j.apcatb.2015.08.018
41. [41]
  (41) Cai, M.; Liu, Y.; Dong, K.; Chen, X.; Li, S. Chin. J. Catal. 2023, 52, 239. doi: 10.1016/S1872-2067(23)64496-1(41) Cai, M.; Liu, Y.; Dong, K.; Chen, X.; Li, S. Chin. J. Catal. 2023, 52, 239. doi: 10.1016/S1872-2067(23)64496-1
42. [42]
  (42) Li, Q.; Kako, T.; Ye, J. Int. J. Hydrog. Energy 2011, 36, 4716. doi: 10.1016/j.ijhydene.2011.01.082(42) Li, Q.; Kako, T.; Ye, J. Int. J. Hydrog. Energy 2011, 36, 4716. doi: 10.1016/j.ijhydene.2011.01.082
43. [43]
  (43) Atuchin, V. V.; Kalabin, I. E.; Kesler, V. G.; Pervukhina, N. V. J. Electron Spectrosc. 2005,142, 129. doi: 10.1016/j.elspec.2004.10.003(43) Atuchin, V. V.; Kalabin, I. E.; Kesler, V. G.; Pervukhina, N. V. J. Electron Spectrosc. 2005,142, 129. doi: 10.1016/j.elspec.2004.10.003
44. [44]
  (44) Ding, J.; Wang, L.; Liu, Q.; Chai, Y.; Liu, X.; Dai, W.-L. Appl. Catal. B-Environ. 2015, 176–177, 91. doi: 10.1016/j.apcatb.2015.03.028(44) Ding, J.; Wang, L.; Liu, Q.; Chai, Y.; Liu, X.; Dai, W.-L. Appl. Catal. B-Environ. 2015, 176–177, 91. doi: 10.1016/j.apcatb.2015.03.028
45. [45]
  (45) Wang, H.; Yu, J.; Zhan, X.; Chen, L.; Sun, Y.; Shi, H. Appl. Surf. Sci. 2020, 528, 146938. doi: 10.1016/j.apsusc.2020.146938(45) Wang, H.; Yu, J.; Zhan, X.; Chen, L.; Sun, Y.; Shi, H. Appl. Surf. Sci. 2020, 528, 146938. doi: 10.1016/j.apsusc.2020.146938
46. [46]
  (46) Li, H.; Li, F.; Yu, J.; Cao, S. Acta Phys. -Chim. Sin. 2021, 37, 2010073. [李瀚, 李芳, 余家国, 曹少文. 物理化学学报, 2021, 37, 2010073.] doi: 10.3866/PKU.WHXB202010073
47. [47]
  (47) Jiang, D.; Wen, B.; Zhang, Y.; Jin, Y.; Li, D.; Chen, M. J. Colloid Interface Sci. 2019, 536, 1. doi: 10.1016/j.jcis.2018.10.027(47) Jiang, D.; Wen, B.; Zhang, Y.; Jin, Y.; Li, D.; Chen, M. J. Colloid Interface Sci. 2019, 536, 1. doi: 10.1016/j.jcis.2018.10.027
48. [48]
  (48) Luo, B.; Hong, Y.; Li, D.; Fang, Z.; Jian, Y.; Shi, W. ACS Sustain. Chem. Eng. 2018, 6, 14332. doi: 10.1021/acssuschemeng.8b03006(48) Luo, B.; Hong, Y.; Li, D.; Fang, Z.; Jian, Y.; Shi, W. ACS Sustain. Chem. Eng. 2018, 6, 14332. doi: 10.1021/acssuschemeng.8b03006
49. [49]
  (49) Jin, Y.; Jiang, D.; Li, D.; Xiao, P.; Ma, X.; Chen, M. ACS Sustain. Chem. Eng. 2017, 5, 9749. doi: 10.1021/acssuschemeng.7b01548(49) Jin, Y.; Jiang, D.; Li, D.; Xiao, P.; Ma, X.; Chen, M. ACS Sustain. Chem. Eng. 2017, 5, 9749. doi: 10.1021/acssuschemeng.7b01548
50. [50]
  (50) Wang, H.; Chen, L.; Sun, Y.; Yu, J.; Zhao, Y.; Zhan, X.; Shi, H. Sep. Purif. Technol. 2021, 265, 118516. doi: 10.1016/j.seppur.2021.118516(50) Wang, H.; Chen, L.; Sun, Y.; Yu, J.; Zhao, Y.; Zhan, X.; Shi, H. Sep. Purif. Technol. 2021, 265, 118516. doi: 10.1016/j.seppur.2021.118516
51. [51]
  (51) Butler, M. A. J. Appl. Phys.1977, 48, 1914. doi: 10.1063/1.323948(51) Butler, M. A. J. Appl. Phys.1977, 48, 1914. doi: 10.1063/1.323948
52. [52]
  (52) Wu, L.; Yang, X.; Chen, T.; Li, Y.; Meng, Q.; Zhu, L.; Zhu, W.; He, R.; Duan, T. Chem. Eng. J. 2022,427, 131773. doi: 10.1016/j.cej.2021.131773(52) Wu, L.; Yang, X.; Chen, T.; Li, Y.; Meng, Q.; Zhu, L.; Zhu, W.; He, R.; Duan, T. Chem. Eng. J. 2022,427, 131773. doi: 10.1016/j.cej.2021.131773
53. [53]
  (53) Zhang, Z.; Jiang, D.; Li, D.; He, M.; Chen, M. Appl. Catal. B-Environ. 2016, 183, 113. doi: 10.1016/j.apcatb.2015.10.022(53) Zhang, Z.; Jiang, D.; Li, D.; He, M.; Chen, M. Appl. Catal. B-Environ. 2016, 183, 113. doi: 10.1016/j.apcatb.2015.10.022
54. [54]
  (54) Fang, C.; Hu, X.; Du, X.; Mao, G.; Wang, X.; Wang, L.; Liu, Q.; Ding, J. Appl. Catal. A 2023, 652, 119032. doi: 10.1016/j.apcata.2023.119032(54) Fang, C.; Hu, X.; Du, X.; Mao, G.; Wang, X.; Wang, L.; Liu, Q.; Ding, J. Appl. Catal. A 2023, 652, 119032. doi: 10.1016/j.apcata.2023.119032
55. [55]
  (55) Wan, C.; Zhou, L.; Sun, L.; Xu, L.; Cheng, D.-G.; Chen, F.; Zhan, X.; Yang, Y. Chem. Eng. J. 2020,396, 125229. doi: 10.1016/j.cej.2020.125229(55) Wan, C.; Zhou, L.; Sun, L.; Xu, L.; Cheng, D.-G.; Chen, F.; Zhan, X.; Yang, Y. Chem. Eng. J. 2020,396, 125229. doi: 10.1016/j.cej.2020.125229
56. [56]
  (56) Xu, Q.; Cheng, B.; Yu, J.; Liu, G. Carbon 2017, 118, 241. doi: 10.1016/j.carbon.2017.03.052(56) Xu, Q.; Cheng, B.; Yu, J.; Liu, G. Carbon 2017, 118, 241. doi: 10.1016/j.carbon.2017.03.052
57. [57]
  (57) Yu, W.; Zhang, S.; Chen, J.; Xia, P.; Richter, M. H.; Chen, L.; Xu, W.; Jin, J.; Chen, S.; Peng, T. J. Mater. Chem. A 2018, 6, 15668. doi: 10.1039/C8TA02922A(57) Yu, W.; Zhang, S.; Chen, J.; Xia, P.; Richter, M. H.; Chen, L.; Xu, W.; Jin, J.; Chen, S.; Peng, T. J. Mater. Chem. A 2018, 6, 15668. doi: 10.1039/C8TA02922A
58. [58]
  (58) Wang, C.; You, C.; Rong, K.; Shen, C.; Yang, F.; Li, S. Acta Phys. -Chim. Sin. 2024, 40, 2307045. [王春春, 游常俊, 戎珂, 申楚琦, 杨方, 李世杰. 物理化学学报, 2024, 40, 2307045.] doi: 10.3866/PKU.WHXB202307045
59. [59]
  (59) Li, S.; Chen, X.; Yuan, Y. Acta Phys. -Chim. Sin. 2023, 39, 2303032. [李世杰, 陈晓波, 袁玉鹏. 物理化学学报, 2023, 39, 2303032.] doi: 10.3866/PKU.WHXB202303032
60. [60]
  (60) Yin, S.; Sun, L.; Zhou, Y.; Li, X.; Li, J.; Song, X.; Huo, P.; Wang, H.; Yan, Y. Chem. Eng. J. 2021,406, 126776. doi: 10.1016/j.cej.2020.126776(60) Yin, S.; Sun, L.; Zhou, Y.; Li, X.; Li, J.; Song, X.; Huo, P.; Wang, H.; Yan, Y. Chem. Eng. J. 2021,406, 126776. doi: 10.1016/j.cej.2020.126776
61. [61]
  (61) Jiang, Z.; Wan, W.; Li, H.; Yuan, S.; Zhao, H.; Wong, P. K. Adv. Mater. 2018, 30, 1706108. doi: 10.1002/adma.201706108(61) Jiang, Z.; Wan, W.; Li, H.; Yuan, S.; Zhao, H.; Wong, P. K. Adv. Mater. 2018, 30, 1706108. doi: 10.1002/adma.201706108
62. [62]
  (62) Thenuwara, A. C.; Cerkez, E. B.; Shumlas, S. L.; Attanayake, N. H.; Mckendry, I. G.; Frazer, L.; Borguet, E.; Kang, Q.; Remsing, R. C.; Klein, M. L.; et al. Angew. Chem. Int. Ed.2016, 55, 10381. doi: 10.1002/anie.201601935(62) Thenuwara, A. C.; Cerkez, E. B.; Shumlas, S. L.; Attanayake, N. H.; Mckendry, I. G.; Frazer, L.; Borguet, E.; Kang, Q.; Remsing, R. C.; Klein, M. L.; et al. Angew. Chem. Int. Ed.2016, 55, 10381. doi: 10.1002/anie.201601935
63. [63]
  (63) Zeng, Z.; Su, Y.; Quan, X.; Choi, W.; Zhang, G.; Liu, N.; Kim, B.; Chen, S.; Yu, H.; Zhang, S. Nano Energy 2020, 69, 104409. doi: 10.1016/j.nanoen.2019.104409(63) Zeng, Z.; Su, Y.; Quan, X.; Choi, W.; Zhang, G.; Liu, N.; Kim, B.; Chen, S.; Yu, H.; Zhang, S. Nano Energy 2020, 69, 104409. doi: 10.1016/j.nanoen.2019.104409
64. [64]
  (64) Hua, J.; W, Z.; Zhang, J.; Dai, K.; Shao, C.; Fan, K. J. Mater. Sci. Technol. 2023, 156, 64. doi: 10.1016/j.jmst.2023.03.003(64) Hua, J.; W, Z.; Zhang, J.; Dai, K.; Shao, C.; Fan, K. J. Mater. Sci. Technol. 2023, 156, 64. doi: 10.1016/j.jmst.2023.03.003
65. [65]
  (65) Li, S.; Cai, M.; Liu, Y.; Wang, C.; Lv, K.; Chen, X. Chin. J. Catal. 2022, 43, 2652. doi: 10.1016/S1872-2067(22)64106-8(65) Li, S.; Cai, M.; Liu, Y.; Wang, C.; Lv, K.; Chen, X. Chin. J. Catal. 2022, 43, 2652. doi: 10.1016/S1872-2067(22)64106-8
66. [66]
  (66) Li, S.; Wang, C.; Dong, K.; Zhang, P.; Chen, X.; Li, X. Chin. J. Catal. 2023, 51, 101. doi: 10.1016/S1872-2067(23)64479-1(66) Li, S.; Wang, C.; Dong, K.; Zhang, P.; Chen, X.; Li, X. Chin. J. Catal. 2023, 51, 101. doi: 10.1016/S1872-2067(23)64479-1
67. [67]
  (67) He, H.; Wang, Z.; Dai, K.; Li, S.; Zhang, J. Chin. J. Catal. 2023, 48, 267. doi: 10.1016/S1872-2067(23)64420-1(67) He, H.; Wang, Z.; Dai, K.; Li, S.; Zhang, J. Chin. J. Catal. 2023, 48, 267. doi: 10.1016/S1872-2067(23)64420-1

扫一扫看文章

计量

PDF下载量: 1
文章访问数: 122
HTML全文浏览量: 8

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

内建电场与偶极场协同增强SnNb₂O₆/富氮C₃N₅ S型异质结光催化性能

通讯作者: 刘倩倩,Email:liuqianqian@usts.edu.cn; 戴维林,Email:wldai@fudan.edu.cn; 刘波,Email:liubo@mail.usts.edu.cn

English

Synergistic Effects of Internal Electric and Dipole Fields in SnNb₂O₆/Nitrogen-Enriched C₃N₅ S-Scheme Heterojunction for Boosting Photocatalytic Performance

Corresponding author: Qianqian Liu, ; Wei-Lin Dai, ; Bo Liu,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处