Citation: Dong Xiang, Kunzhen Li, Kanghua Miao, Ran Long, Yujie Xiong, Xiongwu Kang. 胺功能化的铜催化剂：氢键介导的电化学CO₂还原为C₂产物以及优越的可充电Zn-CO₂电池性能[J]. Acta Physico-Chimica Sinica, ;2024, 40(8): 230802. doi: 10.3866/PKU.WHXB202308027 shu

胺功能化的铜催化剂：氢键介导的电化学CO₂还原为C₂产物以及优越的可充电Zn-CO₂电池性能

Dong Xiang ¹ ,
Kunzhen Li ¹ ,
Kanghua Miao ¹ ,
Ran Long ² ,
Yujie Xiong ^2,, ,
Xiongwu Kang ^1,,

1.
New Energy Research Institute, School of Environment and Energy, South China University of Technology, Guangzhou 510006, China;
2.
Hefei National Laboratory for Physical Sciences at the Microscale, School of Chemistry and Materials Science, University of Science and Technology of China, Hefei 230026, China

Corresponding author: Yujie Xiong, Xiongwu Kang,
Received Date: 15 August 2023
Revised Date: 20 September 2023
Accepted Date: 28 September 2023

Fund Project: The project was supported by the National Natural Science Foundation of China (U2032151, 21725102, 91961106).

有机分子功能化是一种有前景的策略，用于调控电化学CO₂还原反应(eCO₂RR)的C₂₊产物选择性和活性。然而，我们对于电化学CO₂还原调控机制的分子水平理解仍然不够清晰。在本文中，我们成功制备了铜纳米颗粒，并使用一系列胺类衍生物(如十六胺(HAD)、N-甲基十六胺(N-MHDA)、十六烷基二甲胺(HDDMA)和十六酰胺(PMM))对其进行功能化，以系统地研究胺表面活性剂分子结构对eCO₂RR选择性和活性的影响。结果表明，HDA的功能化可以将C₂产物和C₂H₄的法拉第效率(FE)提高至73.5%和46.4%，并且在−0.9 V vs. RHE (可逆氢电极)电位下，C₂产物的分电流密度为131.4 mA·cm⁻²。理论研究发现，HDA通过与CO₂和eCO₂RR中间体之间的氢键相互作用，富集了*CO₂、*CO和其他反应中间体，降低了CO―CHO耦合反应的动力学能垒，从而促进了eCO₂RR向C₂产物的转化。当胺基的H原子被甲基取代后，氢键相互作用减弱，竞争的析氢反应加剧。PMM通过Cu―O键与Cu表面发生键合，而不是通过Cu―N键，导致Cu-PMM更倾向于产乙醇。原位拉曼光谱显示，在Cu-HDA表面，CO主要吸附在Cu的顶位吸附位点上，与在Cu表面上的桥式吸附不同，这可能是因为前者表面对CO的富集引发了CO的吸附构型变化。HDA功能化还提高了Cu催化剂的表面pH。基于Cu-HDA组装的可充电Zn-CO₂电池在放电电流密度为16 mA∙cm^–2时，最大功率密度为6.48 mW∙cm^–2，并具有长达60 h的良好充放电稳定性。本研究的重点在于通过在分子水平上调节Cu基材料的CO₂RR活性和选择性，促进CO₂-C₂的转化，这可能为提高C₂产物的产率提供新的见解。
- CO₂ reduction,
- CO―CHO coupling,
- Organic functionalization,
- In situ Raman,
- C₂ product,
- Zn-CO₂ battery
1. [1]
  (1) Hepburn, C.; Adlen, E.; Beddington, J.; Carter, E. A.; Fuss, S.; Mac Dowell, N.; Minx, J. C.; Smith, P.; Williams, C. K. Nature 2019, 575, 87. doi: 10.1038/s41586-019-1681-6
2. [2]
  (2) McGinnis, R. Joule 2020, 4, 509. doi: 10.1016/j.joule.2020.01.002
3. [3]
  (3) Wang, J.; Zou, J.; Hu, X.; Ning, S.; Wang, X.; Kang, X.; Chen, S. J. Mater. Chem. A 2019, 7, 27514. doi: 10.1039/c9ta11140a
4. [4]
  (4) Chen, K.; Cao, M.; Ni, G.; Chen, S.; Liao, H.; Zhu, L.; Li, H.; Fu, J.; Hu, J.; Cortés, E.; et al. Appl. Catal. B 2022, 306, 121093. doi: 10.1016/j.apcatb.2022.121093
5. [5]
  (5) Chen, K.; Cao, M.; Lin, Y.; Fu, J.; Liao, H.; Zhou, Y.; Li, H.; Qiu, X.; Hu, J.; Zheng, X.; et al. Adv. Funct. Mater. 2021, 32, 2111322. doi: 10.1002/adfm.202111322
6. [6]
  (6) Peng, C.; Yang, S.; Luo, G.; Yan, S.; Shakouri, M.; Zhang, J.; Chen, Y.; Li, W.; Wang, Z.; Sham, T K.; et al. Adv. Mater. 2022, 34, e2204476. Doi: 10.1002/adma.202204476
7. [7]
  (7) Xiang, D.; Li, K.; Li, M.; Long, R.; Xiong, Y.; Yakhvarov, D.; Kang, X. Mater. Today Phys. 2023, 33, 101045. doi: 10.1016/j.mtphys.2023.101045
8. [8]
  (8) Wang, H. Nano Res. 2021, 15, 2834. doi: 10.1007/s12274-021-3984-9
9. [9]
  (9) Zang, D.; Gao, X. J.; Li, L.; Wei, Y.; Wang, H. Nano Res. 2022, 15, 8872. doi: 10.1007/s12274-022-4698-3
10. [10]
  (10) Wang, Q.; Liu, K.; Hu, K.; Cai, C.; Li, H.; Li, H.; Herran, M.; Lu, Y.-R.; Chan, T.-S.; Ma, C.; et al. Nat. Commun. 2022, 13, 6082. doi: 10.1038/s41467-022-33692-0
11. [11]
  (11) Chen, S.; Li, X.; Kao, C. W.; Luo, T.; Chen, K.; Fu, J.; Ma, C.; Li, H.; Li, M.; Chan, T. S.; et al. Angew. Chem. Int. Ed. 2022, 61, e202206233. doi: 10.1002/anie.202206233
12. [12]
  (12) Wang, J.; Ning, S.; Luo, M.; Xiang, D.; Chen, W.; Kang, X.; Jiang, Z.; Chen, S. Appl. Catal. B 2021, 288, 119979. doi: 10.1016/j.apcatb.2021.119979
13. [13]
  (13) Han, L.; Tian, B.; Gao, X.; Zhong, Y.; Wang, S.; Song, S.; Wang, Z.; Zhang, Y.; Kuang, Y.; Sun, X. SmartMat 2022, 3, 142. doi: 10.1002/smm2.1082
14. [14]
  (14) Wang, Q.; Liu, K.; Fu, J.; Cai, C.; Li, H.; Long, Y.; Chen, S.; Liu, B.; Li, H.; Li, W.; et al. Angew. Chem. Int. Ed. 2021, 60, 25241. doi: 10.1002/anie.202109329
15. [15]
  (15) Wang, Y.; Liu, J.; Zheng, G. Adv. Mater. 2021, 33, e2005798. doi: 10.1002/adma.202005798
16. [16]
  (16) Yang, D.; Wang, X. SmartMat 2022, 3, 54. doi: 10.1002/smm2.1102
17. [17]
  (17) Zhou, Y.; Che, F.; Liu, M.; Zou, C.; Liang, Z.; De Luna, P.; Yuan, H.; Li, J.; Wang, Z.; Xie, H.; et al. Nat. Chem. 2018, 10, 974. doi: 10.1038/s41557-018-0092-x
18. [18]
  (18) Li, Y. C.; Wang, Z.; Yuan, T.; Nam, D. H.; Luo, M.; Wicks, J.; Chen, B.; Li, J.; Li, F.; de Arquer, F. P. G.; et al. J. Am. Chem. Soc. 2019, 141, 8584. doi: 10.1021/jacs.9b02945
19. [19]
  (19) He, C.; Duan, D.; Low, J.; Bai, Y.; Jiang, Y.; Wang, X.; Chen, S.; Long, R.; Song, L.; Xiong, Y. Nano Res. 2023, 16, 4494. doi: 10.1007/s12274-021-3532-7
20. [20]
  (20) Wang, Y.; Han, P.; Lv, X.; Zhang, L.; Zheng, G. Joule 2018, 2, 2551. doi: 10.1016/j.joule.2018.09.021
21. [21]
  (21) Hahn, C.; Hatsukade, T.; Kim, Y. G.; Vailionis, A.; Baricuatro, J. H.; Higgins, D. C.; Nitopi, S. A.; Soriaga, M. P.; Jaramillo, T. F. Proc. Natl. Acad. Sci. 2017, 114, 5918. doi: 10.1073/pnas.1618935114
22. [22]
  (22) Zhu, C.; Zhang, Z.; Zhong, L.; Zhao, S.; Shi, G.; Wu, B.; Gu, H.; Wu, J.; Gao, X.; Liu, K.; et al. J. Energy Chem. 2022, 70, 382. doi: 10.1016/j.jechem.2022.02.027
23. [23]
  (23) Zhou, Y.; Liang, Y.; Fu, J.; Liu, K.; Chen, Q.; Wang, X.; Li, H.; Zhu, L.; Hu, J.; Pan, H.; et al. Nano Lett. 2022, 22, 1963. doi: 10.1021/acs.nanolett.1c04653
24. [24]
  (24) Yang, B.; Liu, K.; Li, H.; Liu, C.; Fu, J.; Li, H.; Huang, J. E.; Ou, P.; Alkayyali, T.; Cai, C.; et al. J. Am. Chem. Soc. 2022, 144, 3039. doi: 10.1021/jacs.1c11253
25. [25]
  (25) Li, F.; Thevenon, A.; Rosas-Hernandez, A.; Wang, Z.; Li, Y.; Gabardo, C. M.; Ozden, A.; Dinh, C. T.; Li, J.; Wang, Y.; et al. Nature 2020, 577, 509. doi: 10.1038/s41586-019-1782-2
26. [26]
  (26) Chen, X.; Chen, J.; Alghoraibi, N. M.; Henckel, D. A.; Zhang, R.; Nwabara, U. O.; Madsen, K. E.; Kenis, P. J. A.; Zimmerman, S. C.; Gewirth, A. A. Nat. Catal. 2020, 4, 20. doi: 10.1038/s41929-020-00547-0
27. [27]
  (27) Lin, J.; Zhou, Y.; Wen, J.; Si, W.; Gao, H.; Wang, G.; Kang, X. J. Energy Chem. 2022, 75, 164. doi: 10.1016/j.jechem.2022.08.014
28. [28]
  (28) Li, F.; Li, Y. C.; Wang, Z.; Li, J.; Nam, D.-H.; Lum, Y.; Luo, M.; Wang, X.; Ozden, A.; Hung, S.-F.; et al. Nat. Catal. 2019, 3, 75. doi: 10.1038/s41929-019-0383-7
29. [29]
  (29) Checco, A.; Hofmann, T.; DiMasi, E.; Black, C. T.; Ocko, B. M. Nano Lett. 2010, 10, 1354. doi: 10.1021/nl9042246
30. [30]
  (30) Wakerley, D.; Lamaison, S.; Ozanam, F.; Menguy, N.; Mercier, D.; Marcus, P.; Fontecave, M.; Mougel, V. Nat. Mater. 2019, 18, 1222. doi: 10.1038/s41563-019-0445-x
31. [31]
  (31) Xie, M. S.; Xia, B. Y.; Li, Y.; Yan, Y.; Yang, Y.; Sun, Q.; Chan, S. H.; Fisher, A.; Wang, X. Energy Environ. Sci. 2016, 9, 1687. doi: 10.1039/c5ee03694a
32. [32]
33. [33]
  (33) Zhao, Y.; Wang, C.; Liu, Y.; MacFarlane, D. R.; Wallace, G. G. Adv. Energy Mater. 2018, 8, 1801400. doi: 10.1002/aenm.201801400
34. [34]
  (34) Wei, X.; Yin, Z.; Lyu, K.; Li, Z.; Gong, J.; Wang, G.; Xiao, L.; Lu, J.; Zhuang, L. ACS Catal. 2020, 10, 4103. doi: 10.1021/acscatal.0c00049
35. [35]
  (35) Lyu, Z.; Zhu, S.; Xie, M.; Zhang, Y.; Chen, Z.; Chen, R.; Tian, M.; Chi, M.; Shao, M.; Xia, Y. Angew. Chem. Int. Ed. 2021, 60, 1909. doi: 10.1002/anie.202011956
36. [36]
  (36) Xie, Y.; Chen, Y. J. Mater. Sci. 2021, 56, 10135. doi: 10.1007/s10853-021-05920-3
37. [37]
  (37) Nitopi, S.; Bertheussen, E.; Scott, S. B.; Liu, X.; Engstfeld, A. K.; Horch, S.; Seger, B.; Stephens, I. E. L.; Chan, K.; Hahn, C.; et al. Chem. Rev. 2019, 119, 7610. doi: 10.1021/acs.chemrev.8b00705
38. [38]
  (38) Kim, J.-Y.; Hong, D.; Lee, J.-C.; Kim, H. G.; Lee, S.; Shin, S.; Kim, B.; Lee, H.; Kim, M.; Oh, J.; et al. Nat. Commun. 2021, 12, 3765. doi: 10.1038/s41467-021-24105-9
39. [39]
  (39) Todorova, T. K.; Schreiber, M. W.; Fontecave, M. ACS Catal. 2019, 10, 1754. doi: 10.1021/acscatal.9b04746
40. [40]
  (40) Li, H.; Li, Y.; Koper, M. T. M.; Calle-Vallejo, F. J. Am. Chem. Soc. 2014, 136, 15694. doi: 10.1021/ja508649p
41. [41]
  (41) Kong, X.; Zhao, J.; Ke, J.; Wang, C.; Li, S.; Si, R.; Liu, B.; Zeng, J.; Geng, Z. Nano Lett. 2022, 22, 3801. doi: 10.1021/acs.nanolett.2c00945
42. [42]
  (42) Gao, J.; Zhang, H.; Guo, X.; Luo, J.; Zakeeruddin, S. M.; Ren, D.; Gratzel, M. J. Am. Chem. Soc. 2019, 141, 18704. doi: 10.1021/jacs.9b07415
43. [43]
  (43) Pan, Z.; Wang, K.; Ye, K.; Wang, Y.; Su, H.-Y.; Hu, B.; Xiao, J.; Yu, T.; Wang, Y.; Song, S. ACS Catal. 2020, 10, 3871. doi: 10.1021/acscatal.9b05115
44. [44]
  (44) Moradzaman, M.; Mul, G. ChemElectroChem 2021, 8, 1478. doi: 10.1002/celc.202001598
45. [45]
  (45) Zhang, G.; Zhao, Z. J.; Cheng, D.; Li, H.; Yu, J.; Wang, Q.; Gao, H.; Guo, J.; Wang, H.; Ozin, G. A.; et al. Nat. Commun. 2021, 12, 5745. doi: 10.1038/s41467-021-26053-w
46. [46]
  (46) Zhang, Z.; Melo, L.; Jansonius, R. P.; Habibzadeh, F.; Grant, E. R.; Berlinguette, C. P. ACS Energy Lett. 2020, 5, 3101. doi: 10.1021/acsenergylett.0c01606
47. [47]
  (47) Zhu, S.; Jiang, B.; Cai, W. B.; Shao, M. J. Am. Chem. Soc. 2017, 139, 15664. doi: 10.1021/jacs.7b10462
48. [48]
  (48) Jiang, S.; Klingan, K.; Pasquini, C.; Dau, H. J. Chem. Phys. 2019, 150, 041718. doi: 10.1063/1.5054109
49. [49]
  (49) Kaur, S.; Kumar, M.; Gupta, D.; Mohanty, P. P.; Das, T.; Chakraborty, S.; Ahuja, R.; Nagaiah, T. C. Nano Energy 2023, 109, 108242. doi: 10.1016/j.nanoen.2023.108242
50. [50]
  (50) Gong, S.; Wang, W.; Zhang, C.; Zhu, M.; Lu, R.; Ye, J.; Yang, H.; Wu, C.; Liu, J.; Rao, D.; et al. Adv. Funct. Mater. 2022, 32, 2110649. doi: 10.1002/adfm.202110649
51. [51]
  (51) Ni, W.; Liu, Z.; Zhang, Y.; Ma, C.; Deng, H.; Zhang, S.; Wang, S. Adv. Mater. 2021, 33, e2003238. doi: 10.1002/adma.202003238
52. [52]
  (52) Wang, F.; Wang, G.; Deng, P.; Chen, Y.; Li, J.; Wu, D.; Wang, Z.; Wang, C.; Hua, Y.; Tian, X. Small 2023, 19, e2301128. doi: 10.1002/smll.202301128
53. [53]
  (53) Zeng, Z.; Gan, L. Y.; Bin Yang, H.; Su, X.; Gao, J.; Liu, W.; Matsumoto, H.; Gong, J.; Zhang, J.; Cai, W.; et al. Nat. Commun. 2021, 12, 4088. doi: 10.1038/s41467-021-24052-5
54. [54]
  (54) Zheng, W.; Wang, Y.; Shuai, L.; Wang, X.; He, F.; Lei, C.; Li, Z.; Yang, B.; Lei, L.; Yuan, C.; et al. Adv. Funct. Mater. 2021, 31, 2008146. doi: 10.1002/adfm.202008146
55. [55]
  (55) Li, J.; Chen, L.-W.; Hao, Y.-C.; Yuan, M.; Lv, J.; Dong, A.; Li, S.; Gu, H.; Yin, A.-X.; Chen, W.; et al. Chem. Eng. J. 2023, 461, 141865. doi: 10.1016/j.cej.2023.141865
56. [56]
  (56) Xu, A.; Chen, X.; Wei, D.; Chu, B.; Yu, M.; Yin, X.; Xu, J. Small 2023, 19, 2302253. doi: 10.1002/smll.202302253
57. [57]
  (57) Gao, S.; Jin, M.; Sun, J.; Liu, X.; Zhang, S.; Li, H.; Luo, J.; Sun, X. J. Mater. Chem. A 2021, 9, 21024. doi: 10.1039/D1TA04360A
1. [1]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
2. [2]
  Jiajun Wang , Guolin Yi , Shengling Guo , Jianing Wang , Shujuan Li , Ke Xu , Weiyi Wang , Shulai Lei . Computational design of bimetallic TM₂@g-C₉N₄ electrocatalysts for enhanced CO reduction toward C₂ products. Chinese Chemical Letters, 2024, 35(7): 109050-. doi: 10.1016/j.cclet.2023.109050
3. [3]
  Jianyu Qin , Yuejiao An , Yanfeng Zhang . In Situ Assembled ZnWO₄/g-C₃N₄ S-Scheme Heterojunction with Nitrogen Defect for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408002-. doi: 10.3866/PKU.WHXB202408002
4. [4]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
5. [5]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
6. [6]
  Shicheng Yan . Experimental Teaching Design for the Integration of Scientific Research and Teaching: A Case Study on Organic Electrooxidation. University Chemistry, 2024, 39(11): 350-358. doi: 10.12461/PKU.DXHX202408036
7. [7]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
8. [8]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
9. [9]
  Yangrui Xu , Yewei Ren , Xinlin Liu , Hongping Li , Ziyang Lu . 具有高传质和亲和表面的NH₂-UIO-66基疏水多孔液体用于增强CO₂光还原. Acta Physico-Chimica Sinica, 2024, 40(11): 2403032-. doi: 10.3866/PKU.WHXB202403032
10. [10]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
11. [11]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
12. [12]
  Yongheng Ren , Yang Chen , Hongwei Chen , Lu Zhang , Jiangfeng Yang , Qi Shi , Lin-Bing Sun , Jinping Li , Libo Li . Electrostatically driven kinetic Inverse CO2/C2H2 separation in LTA-type zeolites. Chinese Journal of Structural Chemistry, 2024, 43(10): 100394-100394. doi: 10.1016/j.cjsc.2024.100394
13. [13]
  Qin Cheng , Ming Huang , Qingqing Ye , Bangwei Deng , Fan Dong . Indium-based electrocatalysts for CO₂ reduction to C1 products. Chinese Chemical Letters, 2024, 35(6): 109112-. doi: 10.1016/j.cclet.2023.109112
14. [14]
  Liang Ma , Zhou Li , Zhiqiang Jiang , Xiaofeng Wu , Shixin Chang , Sónia A. C. Carabineiro , Kangle Lv . Effect of precursors on the structure and photocatalytic performance of g-C3N4 for NO oxidation and CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(11): 100416-100416. doi: 10.1016/j.cjsc.2023.100416
15. [15]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
16. [16]
  Yi Liu , Zhe-Hao Wang , Guan-Hua Xue , Lin Chen , Li-Hua Yuan , Yi-Wen Li , Da-Gang Yu , Jian-Heng Ye . Photocatalytic dicarboxylation of strained C–C bonds with CO₂ via consecutive visible-light-induced electron transfer. Chinese Chemical Letters, 2024, 35(6): 109138-. doi: 10.1016/j.cclet.2023.109138
17. [17]
  Yuejiao An , Wenxuan Liu , Yanfeng Zhang , Jianjun Zhang , Zhansheng Lu . Revealing Photoinduced Charge Transfer Mechanism of SnO₂/BiOBr S-Scheme Heterostructure for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2407021-. doi: 10.3866/PKU.WHXB202407021
18. [18]
  Fan Wu , Wenchang Tian , Jin Liu , Qiuting Zhang , YanHui Zhong , Zian Lin . Core-Shell Structured Covalent Organic Framework-Coated Silica Microspheres as Mixed-Mode Stationary Phase for High Performance Liquid Chromatography. University Chemistry, 2024, 39(11): 319-326. doi: 10.12461/PKU.DXHX202403031
19. [19]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031
20. [20]
  Mianying Huang , Zhiguang Xu , Xiaoming Lin . Mechanistic analysis of Co2VO4/X (X = Ni, C) heterostructures as anode materials of lithium-ion batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100309-100309. doi: 10.1016/j.cjsc.2023.100309

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(97)
HTML views(8)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

胺功能化的铜催化剂：氢键介导的电化学CO2还原为C2产物以及优越的可充电Zn-CO2电池性能

Metrics

通讯作者: 陈斌, bchen63@163.com

胺功能化的铜催化剂：氢键介导的电化学CO₂还原为C₂产物以及优越的可充电Zn-CO₂电池性能