Citation: Zehao Zhang, Zheng Wang, Haibo Li. V₂CF_x MXene衍生2D V₂O₃@介孔碳纳米片的制备及其电容脱盐特性[J]. Acta Physico-Chimica Sinica, ;2024, 40(8): 230802. doi: 10.3866/PKU.WHXB202308020 shu

V₂CF_x MXene衍生2D V₂O₃@介孔碳纳米片的制备及其电容脱盐特性

Zehao Zhang ^1,2 ,
Zheng Wang ^1,, ,
Haibo Li ^2,,

1.
State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, College of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, China;
2.
Ningxia Key Laboratory of Photovoltaic Materials, School of Materials and New Energy, Ningxia University, Yinchuan 750021, China

Corresponding author: Zheng Wang, Haibo Li,
Received Date: 15 August 2023
Revised Date: 10 September 2023
Accepted Date: 12 September 2023

Fund Project: The project was supported by the National Natural Science Foundation of China (22272085, 22169015).

采用同源金属V₂CF_x MXene作为前驱体制备了三氧化二钒@多孔碳(V₂O₃@porous carbon，V₂O₃@PC)纳米片作为电容去离子(CDI)阳极，研究其脱盐特性。实验探究了在不同在碳化温度下V₂O₃@PC的结构、结晶度、润湿性、石墨化程度和电化学特性。研究表明，所制备的V₂O₃@PC呈现出典型的2D纳米片结构，高结晶度的V₂O₃纳米颗粒被高石墨化度的PC牢牢束缚。这种结构具有良好的界面润湿性和高导电性，因而可以促进电解质的渗透，加速界面电荷的转移以并促进盐离子的传输和扩散。此外，PC也能较好的抑制V₂O₃在多次循环后的体积膨胀。电化学结果表明，V的可逆电化学转化在一定程度上提高了Na⁺的储存。当电压为1.2 V时，NaCl电导率为1000 μS·cm⁻¹时，优化后的V₂O₃@PC电极具有高达2.20 mmol∙g⁻¹的脱盐容量，0.13 mmol∙g⁻¹∙min⁻¹的脱盐速率，62%的水回收率以及24.0 Wh∙m⁻³的低能耗。
- Capacitive deionization,
- V₂O₃,
- Metal organic frameworks,
- MXene,
- Electrochemistry
1. [1]
  (1) Jin, Z.; Zhang, M.; Mei, H.; Liu, H.; Pan, L.; Yan, Y.; Cheng, L.; Zhang, L. Carbon 2023, 202, 159. doi: 10.1016/j.carbon.2022.11.035
2. [2]
  (2) Qiu, X.; Kong, H.; Li, Y.; Wang, Q.; Wang, Y. ACS Appl. Mater. Interfaces 2022, 14 (49), 54855. doi: 10.1021/acsami.2c15997
3. [3]
  (3) Lu, Z.; Wei, Y.; Deng, J.; Ding, L.; Li, Z.-K.; Wang, H. ACS Nano 2019, 13 (9), 10535. doi: 10.1021/acsnano.9b04612
4. [4]
  (4) Lei, J.; Xiong, Y.; Yu, F.; Ma, J. Chem. Eng. J. 2022, 437, 135381. doi: 10.1016/j.cej.2022.135381
5. [5]
  (5) Wang, K.; Liu, Y.; Xu, X.; Jiao, Y.; Pan, L. Chem. Eng. J. 2023, 463, 142394. doi: 10.1016/j.cej.2023.142394
6. [6]
  (6) Tu, X.; Liu, Y.; Wang, K.; Ding, Z.; Xu, X.; Lu, T.; Pan, L. J. Colloid Interface Sci. 2023, 642, 680. doi: 10.1016/j.jcis.2023.04.007
7. [7]
8. [8]
  (8) Jiang, Z. Y.; Yang, M.; Wang, Q.; Qu, Z. G.; Zhang, J. F. Desalination 2023, 548, 116274. doi: 10.1016/j.desal.2022.116274
9. [9]
  (9) Sivasubramanian, P.; Kumar, M.; Kirankumar, V. S.; Samuel, M. S.; Dong, C.-D.; Chang, J.-H. Desalination 2023, 559, 116652. doi: 10.1016/j.desal.2023.116652
10. [10]
  (10) Sui, Z.; Liu, W.; Xu, X.; Liu, Y.; Tian, Q. Diamond Relat. Mater. 2020, 104, 107758. doi: 10.1016/j.diamond.2020.107758
11. [11]
  (11) Liu, Y.; Gao, X.; Wang, K.; Dou, X.; Zhu, H.; Yuan, X.; Pan, L. J. Mater. Chem. A 2020, 8 (17), 8476. doi: 10.1039/C9TA14112J
12. [12]
  (12) Li, Q.; Xu, X.; Guo, J.; Hill, J. P.; Xu, H.; Xiang, L.; Li, C.; Yamauchi, Y.; Mai, Y. Angew. Chem. Int. Ed. 2021, 60 (51), 26528. doi: 10.1002/anie.202111823
13. [13]
  (13) Wang, G.; Yan, T.; Zhang, J.; Shi, L.; Zhang, D. Environ. Sci. Technol. 2020, 54 (13), 8411. doi: 10.1021/acs.est.0c01518
14. [14]
  (14) Xu, H.; Li, M.; Gong, S.; Zhao, F.; Zhao, Y.; Li, C.; Qi, J.; Wang, Z.; Wang, H.; Fan, X.; et al. J. Colloid Interface Sci. 2022, 624, 233. doi: 10.1016/j.jcis.2022.05.131
15. [15]
  (15) Geng, X.; Kuai, J.; Ren, X.; Guo, W. Water Sci. Technol. 2022, 86 (11), 3014. doi: 10.2166/wst.2022.383
16. [16]
  (16) He, D.; Wong, C. E.; Tang, W.; Kovalsky, P.; Waite, T. D. Environ. Sci. Technol. Lett. 2016, 3 (5), 222. doi: 10.1021/acs.estlett.6b00124
17. [17]
  (17) Liu, Q.; Hu, Z.; Li, W.; Zou, C.; Jin, H.; Wang, S.; Chou, S.; Dou, S.-X. Energy Environ. Sci. 2021, 14 (1), 15. doi: 10.1039/D0EE02997A
18. [18]
  (18) Ahn, C.; Cavalleri, A.; Georges, A.; Ismail-Beigi, S.; Millis, A. J.; Triscone, J.-M. Nat. Mater. 2021, 20 (11), 1462. doi: 10.1038/s41563-021-00989-2
19. [19]
  (19) Cao, D.; Zheng, L.; Li, Q.; Zhang, J.; Dong, Y.; Yue, J.; Wang, X.; Bai, Y.; Tan, G.; Wu, C. Nano Lett. 2021, 21 (12), 5225. doi: 10.1021/acs.nanolett.1c01276
20. [20]
  (20) Hu, M.; Yang, W.; Tan, H.; Jin, L.; Zhang, L.; Kerns, P.; Dang, Y.; Dissanayake, S.; Schaefer, S.; Liu, B.; et al. Matter 2020, 2 (5), 1244. doi: 10.1016/j.matt.2020.02.002
21. [21]
  (21) Li, B.; Wang, Y.; Jiang, N.; An, L.; Song, J.; Zuo, Y.; Ning, F.; Shang, H.; Xia, D. Nano Energy 2020, 72, 104727. doi: 10.1016/j.nanoen.2020.104727
22. [22]
  (22) Ding, Y.; Peng, Y.; Chen, S.; Zhang, X.; Li, Z.; Zhu, L.; Mo, L.-E.; Hu, L. ACS Appl. Mater. Interfaces 2019, 11 (47), 44109. doi: 10.1021/acsami.9b13729
23. [23]
  (23) Zhu, K.; Wei, S.; Shou, H.; Shen, F.; Chen, S.; Zhang, P.; Wang, C.; Cao, Y.; Guo, X.; Luo, M.; et al. Nat. Commun. 2021, 12 (1), 6878. doi: 10.1038/s41467-021-27203-w
24. [24]
  (24) Ren, X.; Ai, D.; Zhan, C.; Lv, R.; Kang, F.; Huang, Z.-H. Electrochim. Acta 2019, 318, 730. doi: 10.1016/j.electacta.2019.06.138
25. [25]
  (25) Fonseca, J.; Gong, T.; Jiao, L.; Jiang, H.-L. J. Mater. Chem. A 2021, 9 (17), 10562. doi: 10.1039/D1TA01043C
26. [26]
  (26) Gu, Y.; Wu, Y.-n.; Li, L.; Chen, W.; Li, F.; Kitagawa, S. Angew. Chem. Int. Ed. 2017, 56 (49), 15658. doi: 10.1002/anie.201709738
27. [27]
  (27) Guo, Y.; Wang, W.; Lei, H.; Wang, M.; Jiao, S. Adv. Mater. 2022, 34 (13), 2110109. doi: 10.1002/adma.202110109
28. [28]
29. [29]
30. [30]
  (30) Wang, Y.; Guo, T.; Alhajji, E.; Tian, Z.; Shi, Z.; Zhang, Y.-Z.; Alshareef, H. N. Adv. Energy Mater. 2023, 13 (4), 2202860. doi: 10.1002/aenm.202202860
31. [31]
  (31) An, Y.; Tian, Y.; Feng, J.; Qian, Y. Mater. Today 2022, 57, 146. doi: 10.1016/j.mattod.2022.06.006
32. [32]
  (32) Wang, W.; Li, H. J. Liaocheng Univ. 2023, 36 (3), 82. doi: 10.19728/j.issn1672-6634.2023010004
33. [33]
  (33) Xi, W.; Li, H. J. Inorg. Mater. 2021, 36 (3), 283. doi: 10.15541/jim20200243
34. [34]
  (34) Li, X.; Li, M.; Yang, Q.; Li, H.; Xu, H.; Chai, Z.; Chen, K.; Liu, Z.; Tang, Z.; Ma, L.; et al. ACS Nano 2020, 14 (1), 541. doi: 10.1021/acsnano.9b06866
35. [35]
  (35) Chen, L.; Sun, Y.; Wei, X.; Song, L.; Tao, G.; Cao, X.; Wang, D.; Zhou, G.; Song, Y. Adv. Mater. 2023, 35 (26), 2300771. doi: 10.1002/adma.202300771
36. [36]
  (36) Li, X.; Li, M.; Yang, Q.; Liang, G.; Huang, Z.; Ma, L.; Wang, D.; Mo, F.; Dong, B.; Huang, Q.; et al. Adv. Energy Mater. 2020, 10 (36), 2001791. doi: 10.1002/aenm.202001791
37. [37]
  (37) Jin, T.; Li, H.; Li, Y.; Jiao, L.; Chen, J. Nano Energy 2018, 50, 462. doi: 10.1016/j.nanoen.2018.05.056
38. [38]
  (38) Kim, J.-H.; Kim, Y.-S.; Moon, S.-H.; Park, D.-H.; Kim, M.-C.; Choi, J.-H.; Shin, J.-H.; Park, K.-W. Electrochim. Acta 2021, 389, 138685. doi: 10.1016/j.electacta.2021.138685
39. [39]
  (39) Zhang, Z.; Li, H. Chem. Eng. J. 2022, 447, 137438. doi: 10.1016/j.cej.2022.137438
40. [40]
  (40) Zhang, Z.; Li, H. Appl. Surf. Sci. 2020, 514, 145920. doi: 10.1016/j.apsusc.2020.145920
41. [41]
  (41) Zhang, N.; Feng, X.; Rao, D.; Deng, X.; Cai, L.; Qiu, B.; Long, R.; Xiong, Y.; Lu, Y.; Chai, Y. Nat. Commun. 2020, 11 (1), 4066. doi: 10.1038/s41467-020-17934-7
42. [42]
  (42) Lu, C.; Yang, L.; Yan, B.; Sun, L.; Zhang, P.; Zhang, W.; Sun, Z. Adv. Funct. Mater. 2020, 30 (47), 2000852. doi: 10.1002/adfm.202000852
43. [43]
  (43) Chen, Z.; Xu, X.; Wang, K.; Meng, F.; Lu, T.; Pan, L. Desalination 2023, 564, 116733. doi: 10.1016/j.desal.2023.116733
44. [44]
  (44) Liu, Y.; Du, X.; Wang, Z.; Zhang, L.; Chen, Q.; Wang, L.; Liu, Z.; Dou, X.; Zhu, H.; Yuan, X. Desalination 2021, 520, 115376. doi: 10.1016/j.desal.2021.115376
45. [45]
  (45) Han, J.; Yan, T.; Shen, J.; Shi, L.; Zhang, J.; Zhang, D. Environ. Sci. Technol. 2019, 53 (21), 12668. doi: 10.1021/acs.est.9b04274
46. [46]
  (46) Liu, Y.; Gao, X.; Zhang, L.; Shen, X.; Du, X.; Dou, X.; Yuan, X. Desalination 2020, 494, 114665. doi: 10.1016/j.desal.2020.114665
47. [47]
  (47) El-Deen, A. G.; Choi, J.-H.; Kim, C. S.; Khalil, K. A.; Almajid, A. A.; Barakat, N. A. M. Desalination 2015, 361, 53. doi: 10.1016/j.desal.2015.01.033
48. [48]
  (48) Wang, W.; Liu, Z.; Zhang, Z.; Li, H. Glob. Chall. 2022, 6 (2), 2100095. doi: 10.1002/gch2.202100095
49. [49]
  (49) Guo, L.; Mo, R.; Shi, W.; Huang, Y.; Leong, Z. Y.; Ding, M.; Chen, F.; Yang, H. Y. Nanoscale 2017, 9 (35), 13305. doi: 10.1039/C7NR03579A
50. [50]
  (50) Kim, S.; Lee, J.; Kim, C.; Yoon, J. Electrochim. Acta 2016, 203, 265. doi: 10.1016/j.electacta.2016.04.056
51. [51]
  (51) Lee, J.; Kim, S.; Kim, C.; Yoon, J. Energy Environ. Sci. 2014, 7 (11), 3683. doi: 10.1039/C4EE02378A
52. [52]
  (52) Xi, W.; Li, H. Environ. Sci.: Nano 2020, 7 (3), 764. doi: 10.1039/C9EN01238A
53. [53]
  (53) Han, J.; Shi, L.; Yan, T.; Zhang, J.; Zhang, D. Environ. Sci.: Nano 2018, 5 (10), 2337. doi: 10.1039/C8EN00652K
54. [54]
  (54) Li, Y.; Yin, Y.; Xie, F.; Zhao, G.; Han, L.; Zhang, L.; Lu, T.; Amin, M. A.; Yamauchi, Y.; Xu, X.; et al. Environ. Res. 2022, 212, 113331. doi: 10.1016/j.envres.2022.113331
55. [55]
  (55) Halabaso, E. R.; Salvacion, J. W. L.; Kuncoro, E. P.; Doong, R.-A. Environ. Sci.: Nano 2021, 8 (10), 2844. doi: 10.1039/D1EN00514F
56. [56]
  (56) Liu, B.; Yu, L.; Yu, F.; Ma, J. Desalination 2021, 500, 114897. doi: 10.1016/j.desal.2020.114897
57. [57]
  (57) Min, X.-B.; Liu, F.-S.; Wang, Y.-Y.; Yan, Y.-Q.; Wang, H.-Y. J. Cent. South Univ. 2022, 29 (2), 359. doi: 10.1007/s11771-022-4893-0
58. [58]
  (58) Cai, Y.; Wang, Y.; Fang, R.; Wang, J. Sep. Purif. Technol. 2022, 280, 119828. doi: 10.1016/j.seppur.2021.119828
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V2CFx MXene衍生2D V2O3@介孔碳纳米片的制备及其电容脱盐特性

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V₂CF_x MXene衍生2D V₂O₃@介孔碳纳米片的制备及其电容脱盐特性