Citation: Chunchun Wang, Changjun You, Ke Rong, Chuqi Shen, Fang Yang, Shijie Li. An S-Scheme MIL-101(Fe)-on-BiOCl Heterostructure with Oxygen Vacancies for Boosting Photocatalytic Removal of Cr(VI)[J]. Acta Physico-Chimica Sinica, ;2024, 40(7): 230704. doi: 10.3866/PKU.WHXB202307045 shu

An S-Scheme MIL-101(Fe)-on-BiOCl Heterostructure with Oxygen Vacancies for Boosting Photocatalytic Removal of Cr(VI)

Chunchun Wang ¹ ,
Changjun You ¹ ,
Ke Rong ¹ ,
Chuqi Shen ¹ ,
Fang Yang ² ,
Shijie Li ^1,,

1.
Key Laboratory of Health Risk Factors for Seafood of Zhejiang Province, National Engineering Research Center for Marine Aquaculture, College of Marine Science and Technology, Zhejiang Ocean University, Zhoushan 316022, Zhejiang Province, China;
2.
School of Mechanical and Automotive Engineering, Shanghai University of Engineering Science, Shanghai 201620, China

Corresponding author: Shijie Li, lishijie@zjou.edu.cn
Received Date: 23 July 2023
Revised Date: 25 August 2023
Accepted Date: 25 August 2023

Fund Project: This work has been financially supported by National Natural Science Foundation of China (U1809214, 51708504), the Natural Science Foundation of Zhejiang Province of China (LY20E080014), and the Science and Technology Project of Zhoushan of China (2022C41011).

Hexavalent chromium (Cr(VI)) may be a hazardous and non-biodegradable waste matter which will cause substantial environmental damage. Fabricating powerful photosystems to achieve efficacious elimination of Cr(VI) holds eminent promise in solving environmental issues. Thanks to their outstanding photo/electrical properties, large surface area, and customizable structure, metal-organic framework (MOF) catalysts have attracted widespread attention within the field of pollutant degradation and reduction. Nevertheless, due to the recombination of photo-generated charge carriers, pristine semiconductor MOFs’ photocatalytic performance is inadequate. To overcome this challenge, one of the most typical and effective strategies is to create heterojunctions by combining MOFs with another semiconductor. Among these strategies, the innovative step-scheme (S-scheme) heterojunction has gained increasing prominence. Unlike traditional type II and Z-scheme heterojunctions, the built-in electric field at the S-scheme heterojunction boundary enhances spatial charge separation and boosts redox capacity, thereby improving photocatalytic performance. In this study, a creative MOF-based S-scheme architecture with oxygen vacancies (OV) was built via in situ growth of MIL-101(Fe) crystals on the surface of OV-rich BiOCl microspheres. The optimized MIL-101(Fe)/BiOCl heterojunction exhibited exceptional photocatalytic performance in photo-reducing high concentrations of Cr(VI) and 88.5% of Cr(VI) solution (10 mg·L^-1, 100 mL) can be removed within 60 min, which is about 4.4 and 9.0 times that of BiOCl and MIL-101(Fe). Besides, the MIL-101(Fe)/BiOCl manifests impressive practical implementation prospect due to its high anti-interference property, robustness and reusability. Photoelectron spectroscopy results validated that built-in electric field, bending band, and Coulomb attraction facilitated the transition of photoelectrons from the conduction band (CB) of BiOCl to the valence band (VB) of MIL-101(Fe), where they recombined with the photo-created holes. This suggests an S-scheme interfacial photo-carrier detachment mechanism at the MIL-101(Fe)/BiOCl interface. In addition, BET measurements indicated a notable increase in surface area with the introduction of MIL-101(Fe). The OV-rich S-scheme MIL-101(Fe)/BiOCl heterostructure boasts more reactive sites, enhanced interfacial charge separation, and optimal redox ability of photo-carriers, leading to enhanced photocatalytic properties. Measurements of active radical scavenging and electron spin resonance (ESR) confirm that e^- and ·O₂^- are the primary active species during photocatalysis. These discoveries would open up new avenues for developing defective semiconductor/MOF S-scheme photocatalyst for environmental purification.
- MOF,
- S-scheme heterojunction,
- MIL-101(Fe),
- BiOCl,
- Cr(VI) photoreduction,
- Oxygen vacancy
1. [1]
  (1) Li, X.; He, F.; Wang, Z.; Xing, B. Eco-Environ. Health 2022, 1, 181. doi:10.1016/j.eehl.2022.10.001
2. [2]
  (2) Jeon, I.; Ryberg, E. C.; Alvarez, P. J. J.; Kim, J. H. Nat. Sustain. 2022, 5, 801. doi:10.1038/s41893-022-00915-7
3. [3]
  (3) Deng, H.; Tu, Y.; Wang, H.; Wang, Z.; Li, Y.; Chai, L.; Zhang, W.; Lin, Z. Eco-Environ. Health 2022, 1, 229. doi:10.1016/j.eehl.2022.11.003
4. [4]
  (4) Mallik, A. K.; Moktadir, M. A.; Rahman, M. A.; Shahruzzaman, M.; Rahman, M. M. J. Hazard. Mater. 2022, 423, 127041. doi:10.1016/j.jhazmat.2021.127041
5. [5]
  (5) Cong, Y.; Shen, L.; Wang, B.; Cao, J.; Pan, Z.; Wang, Z.; Wang, K.; Li, Q.; Li, X. Water Res. 2022, 222, 118919. doi:10.1016/j.watres.2022.118919
6. [6]
  (6) Pavithra, K.G.; Jaikumar, V.; Kumar, P. S.; Rajan, P. S. S. J. Clean. Prod. 2019, 228, 580. doi:10.1016/j.jclepro.2019.04.117
7. [7]
  (7) Stern, C. M.; Jegede, T. O.; Hulse, V. A.; Elgrishi, N. Chem. Soc. Rev. 2021, 50, 1642. doi:10.1039/D0CS01165G
8. [8]
  (8) Shannon, M. A.; Bohn, P. W.; Elimelech, M.; Georgiadis, J. G.; Marinas, B. J.; Mayes, A. M. Nature 2008, 452, 301. doi:10.1038/nature06599
9. [9]
  (9) Li, S.; Cai, M.; Wang, C.; Liu, Y. Adv. Fiber Mater. 2023, 5, 994. doi:10.1007/s42765-022-00253-5
10. [10]
  (10) Sun, X.; Li, L.; Jin, S.; Shao, W.; Wang, H.; Zhang, X.; Xie, Y. eScience 2023, 3, 100095. doi:10.1016/j.esci.2023.100095
11. [11]
  (11) Zou, Z.; Zhang, H.; Lan, J.; Luo, J.; Xie, Y.; Li, Y.; Lü, J.; Cao, R. Nano Mater. Sci. 2023, in press. doi:10.1016/j.nanoms.2022.11.001
12. [12]
13. [13]
14. [14]
  (14) Zhou, D.; Luo, H.; Zhang, F.; Wu, J.; Yang, J.; Wang, H. Adv. Fiber Mater. 2022, 4, 1094. doi:10.1007/s42765-022-00149-4
15. [15]
  (15) Wang, C.; Liu, K.; Wang, D.; Wang, G.; Chu, P. K.; Meng, Z.; Wang, X. Adv. Fiber Mater. 2022, 4, 1069. doi:10.1007/s42765-022-00142-x
16. [16]
  (16) Luan, P.; Zhao, X.; Copenhaver, K.; Ozcan, S.; Zhu, H. Adv. Fiber Mater. 2022, 4, 736. doi:10.1007/s42765-022-00151-w
17. [17]
  (17) Sun, J.; Guo, N.; Song, T.; Hao, Y. R.; Sun, J.; Xue, H.; Wang, Q. Adv. Powder Mater. 2022, 1, 100023. doi:10.1016/j.apmate.2021.11.009
18. [18]
  (18) Li, M.; Sun, J.; Chen, G.; Wang, S.; Yao, S. Adv. Powder Mater. 2022, 1, 100032. doi:10.1016/j.apmate.2022.01.005
19. [19]
  (19) Zhang, F.; Li, X.; Dong, X.; Hao, H.; Lang, X.; Chin. J. Catal. 2022, 43, 2395. doi:doi:10.1016/S1872-2067(22)64127-5
20. [20]
  (20) Fu, J.; Li, P.; Lin, Y.; Du, H.; Liu, H.; Zhu, W.; Ren, H. Eco-Environ. Health 2022, 1, 259. doi:10.1016/j.eehl.2022.11.005
21. [21]
  (21) Hou, H.; Shao, G.; Yang, W. J. Mater. Chem. A 2021, 9, 13722. doi:10.1039/D1TA02527A
22. [22]
  (22) Swift, E. Science 2019, 365, 320. doi:10.1126/science.aax8940
23. [23]
  (23) Zhou, P.; Luo, M.; Guo, S. Nat. Rev. Chem. 2022, 6, 823. doi:10.1038/s41570-022-00434-1
24. [24]
  (24) Xu, H.; Shi, J.; Lyu, S.; Lang, X. Chin. J. Catal. 2020, 41, 1468. doi:10.1016/S1872-2067(20)63640-3
25. [25]
  (25) Liang, Z.; Xue, Y.; Wang, X.; Zhang, X.; Tian, J.; Cui, H. Nano Mater. Sci. 2023, 5, 202. doi:10.1016/j.nanoms.2022.03.001
26. [26]
  (26) Chen, Z.; Wei, W.; Chen, H.; Ni, B. Eco-Environ. Health 2022, 1, 86. doi:10.1016/j.eehl.2022.05.001
27. [27]
  (27) Nishioka, S.; Hojo, K.; Xiao, L.; Gao, T.; Miseki, Y.; Yasuda, S.; Yokoi, T.; Sayama, K.; Mallouk, T. E.; Maeda, K. Sci. Adv. 2022, 8, eadc9115. doi:10.1126/sciadv.adc9115
28. [28]
  (28) Shiraishi, Y.; Hashimoto, M.; Chishiro, K.; Moriyama, K.; Tanaka, S.; Hirai, T. J. Am. Chem. Soc. 2020, 142, 7574. doi:10.1021/jacs.0c01683
29. [29]
  (29) Li, M.; Yu, S.; Huang, H.; Li, X.; Feng, Y.; Wang, C.; Wang, Y.; Ma, T.; Guo, L.; Zhang, Y. Angew. Chem. Int. Ed. 2019, 58, 9517. doi:10.1002/ange.201904921
30. [30]
  (30) Yan, X.; Zhao, H.; Li, T.; Zhang, W.; Liu, Q.; Yuan, Y.; Huang, L.; Yao, L.; Yao, J.; Su, H.; et al. Nanoscale 2019, 11, 10203. doi:10.1039/C9NR02304F
31. [31]
  (31) Wu, S.; Sun, W.; Sun, J.; Hood, Z. D.; Yang, S.; Sun, L.; Kent, P. R. C.; Chisholm, M. F. Chem. Mater. 2018, 30, 5128. doi:10.1021/acs.chemmater.8b01629
32. [32]
  (32) Shi, Y.; Li, J.; Mao, C.; Liu, S.; Wang, X.; Liu, X.; Zhao, S.; Liu, X.; Huang, Y.; Zhang, L. Nat. Commun. 2021, 12, 5923. doi:10.1038/s41467-021-26219-6
33. [33]
  (33) Zhang, L.; Zhang, J.; Yu, H.; Yu, J. Adv. Mater. 2022, 34, 2107668. doi:10.1002/adma.202107668
34. [34]
  (34) Li, S.; Yan, R.; Cai, M.; Jiang, W.; Zhang, M.; Li, X. J. Mater. Sci. Technol. 2023, 164, 59. doi:10.1016/j.jmst.2023.05.009
35. [35]
  (35) Li, S.; Cai, M.; Liu, Y.; Wang, C.; Lv, K.; Chen, X. Chin. J. Catal. 2022, 43, 2652. doi:10.1016/S1872-2067(22)64106-8
36. [36]
  (36) Wang, L.; Bie, C.; Yu, J. Trends Chem. 2022, 4, 973. doi:10.1016/j.trechm.2022.08.008
37. [37]
  (37) Wang, Z.; Cheng, B.; Zhang, L.; Yu, J.; Li, Y.; Wageh, S.; Al-Ghamdi, A. A. Chin. J. Catal. 2022, 43, 1657. doi:10.1016/S1872-2067(21)64010-X
38. [38]
  (38) Zhang, J.; Wang, L.; Mousavi, M.; Ghasemi, J. B.; Yu, J. Chin. J. Struct. Chem. 2022, 41, 2206003. doi:10.14102/j.cnki.0254-5861.2022-0150
39. [39]
  (39) Yue, X.; Cheng, L.; Fan, J.; Xiang, Q. Appl. Catal. B 2022, 304, 120979. doi:10.1016/j.apcatb.2021.120979
40. [40]
  (40) Xu, Q.; Zhang, L.; Cheng, B.; Fan, J.; Yu, J. Chem 2020, 6, 1543. doi:10.1016/j.chempr.2020.06.010
41. [41]
  (41) Jabbar, Z. H.; Graimed, B. H.; Okab, A. A.; Alsunbuli, M. M.; Al-husseiny, R. A. J. Photochem. Photobiol. A Chem. 2023, 441, 114734. doi:10.1016/j.jphotochem.2023.114734
42. [42]
  (42) Wang, L.; Zhu, B.; Zhang, J.; Ghasemi, J. B.; Mousavi, M.; Yu, J. Matter 2023, 5, 4187. doi:10.1016/j.matt.2022.09.009
43. [43]
  (43) Xu, Q.; Wageh, S.; Al-Ghamdi, A. A.; Li, X. J. Mater. Sci. Technol. 2022, 124, 171. doi:10.1016/j.jmst.2022.02.016
44. [44]
45. [45]
  (45) Zhao, Z.; Wang, Z.; Zhang, J.; Shao, C.; Dai, K.; Fan, K.; Liang, C. Adv. Funct. Mater. 2023, 2214470. doi:10.1002/adfm.202214470
46. [46]
  (46) Alkanad, K.; Hezam, A.; Drmosh, Q.; Chandrashekar, S. S. G.; AlObaid, A. A.; Warad, I.; Bajiri, M. A.; Krishnappagowda, L. N. Sol. RRL 2021, 5, 2100501. doi:10.1002/solr.202100501
47. [47]
  (47) Wang, Z.; Liu, R.; Zhang, J.; Dai, K. Chin. J. Struct. Chem. 2022, 41, 2206015. doi:10.14102/j.cnki.0254-5861.2022-0108
48. [48]
  (48) Ma, L. J.; Wu, H. Q.; Chen, B. Y.; Wang, G.; Lei, B. X.; Zhang, D.; Kuang, D. B. Adv. Mater. Interfaces 2022, 9, 2102522. doi:10.1002/admi.202102522
49. [49]
  (49) Li, S.; Cai, M.; Wang, C.; Liu, Y.; Li, N.; Zhang, P.; Li, X. J. Mater. Sci. Technol. 2022, 123, 177. doi:10.1016/j.jmst.2022.02.012
50. [50]
  (50) Zhang, Z.; Guo, R.; Tang, J.; Miao, Y.; Gu, J.; Pan, W. J. CO₂ Util. 2021, 45, 101453. doi:10.1016/j.jcou.2021.101453
51. [51]
  (51) Zhou, P.; Shen, Y.; Zhao, S.; Li, G.; Cui, B.; Wei, D.; Shen, Y. Chem. Eng. J. 2022, 407, 126697. doi:10.1016/j.cej.2020.126697
52. [52]
  (52) Jafarzadeh, M. ACS Appl. Mater. Interfaces 2022, 14, 24993. doi:10.1021/acsami.2c03946
53. [53]
  (53) Liu, X.; Zhang, Y.; Guo, X.; Pang, H.; Adv. Fiber Mater. 2022, 4, 1463. doi:10.1007/s42765-022-00214-y
54. [54]
  (54) Peng, S.; Li, R.; Rao, Y.; Huang, Y.; Zhao, Y.; Xiong, M.; Cao, J.; Lee, S. Appl. Catal. B 2022, 316, 121693. doi:10.1016/j.apcatb.2022.121693
55. [55]
  (55) Bao, C.; Zhao, J.; Sun, Y.; Zhao, X.; Zhang, X.; Zhu, Y.; She, X.; Yang, D.; Xing, B. Environ. Sci. Nano 2021, 8, 2347. doi:10.1039/d1en00250c
56. [56]
  (56) Jiang, Z.; Xu, X.; Ma, Y.; Cho, H. S.; Ding, D.; Wang, C.; Wu, J.; Oleynikov, P.; Jia, M.; Cheng, J.; et al. Nature 2020, 586, 549. doi:10.1038/s41586-020-2738-2
57. [57]
  (57) Fakhria, H.; Farzadkia, M.; Boukherroub, R.; Srivastava, V.; Sillanpää, M. Sol. Energy 2020, 208, 990. doi:10.1016/j.solener.2020.08.050
58. [58]
  (58) Stanley, P. M.; Haimerl, J.; Shustova, N. B.; Fischer, R. A.; Warnan, J. Nat. Chem. 2022, 14, 1342. doi:10.1038/s41557-022-01093-x
59. [59]
  (59) Navalón, S.; Dhakshinamoorthy, A.; Álvaro, M.; Ferrer, B.; García, H. Chem. Rev. 2023, 123, 445. doi:10.1021/acs.chemrev.2c00460
60. [60]
  (60) Daliran, S.; Oveisi, A. R.; Peng, Y.; López-Magano, A.; Khajeh, M.; Mas-Ballesté, R. N.; Alemán, J.; Luque, R.; Garcia, H. Chem. Soc. Rev. 2022, 51, 7810. doi:10.1039/d1cs00976a
61. [61]
  (61) Liao, X.; Wang, F.; Wang, F.; Cai, Y.; Yao, Y.; Teng, B. T.; Hao, Q.; Lu, S. Appl. Catal. B 2019, 259, 118064. doi:10.1016/j.apcatb.2019.118064
62. [62]
  (62) Wang, Y.; Zhong, Z.; Muhammad, Y.; He, H.; Zhao, Z.; Nie, S.; Zhao, Z. Chem. Eng. J. 2020, 398, 125684. doi:10.1016/j.cej.2020.125684
63. [63]
  (63) Li, B.; Zhao, J.; Lin, X.; Tu, D.; Meng, Y.; Li, Y.; Huang, P.; Zhang, H. J. Clean. Prod. 2022, 355, 131812. doi:10.1016/j.jclepro.2022.131812
64. [64]
  (64) Liang, R.; He, Z.; Lu, Y.; Yan, G.; Wu, L. Sep. Purif. Technol. 2021, 277, 119442. doi:10.1016/j.seppur.2021.119442
65. [65]
  (65) Doan, V. D.; Huynh, B. A.; Pham, H. A. L.; Vasseghian, Y.; Le, V. T. Environ. Res. 2021, 201, 111593. doi:10.1016/j.envres.2021.111593
66. [66]
  (66) Li, S.; Wang, C.; Dong, K.; Zhang, P.; Chen, X.; Li, X. Chin. J. Catal. 2023, 51, 101. doi:10.1016/S1872-2067(23)64479-1
67. [67]
  (67) Zuo, S.; Ding, Y.; Wu, L.; Yang, F.; Guan, Z.; Ding, S.; Xia, D.; Li, X.; Li, D. Water Res. 2023, 231, 119631. doi:10.1016/j.watres.2023.119631
68. [68]
  (68) Jia, Z.; Li, T.; Zheng, Z.; Zhang, J.; Liu, J.; Li, R.; Wang, Y.; Zhang, X.; Wang, Y.; Fan, C. Chem. Eng. J. 2020, 380, 122422. doi:10.1016/j.cej.2019.122422
69. [69]
  (69) Hajiali, M.; Farhadian, M.; Tangestaninejad, S. Appl. Surf. Sci. 2022, 602, 154389. doi:10.1016/j.apsusc.2022.154389
70. [70]
  (70) Lu, C.; Yang, D.; Wang, L.; Wen, S.; Cao, D.; Tu, C.; Gao, L.; Li, Y.; Zhou, Y.; Huang, W. J. Alloy. Compd. 2022, 904, 164046. doi:10.1016/j.jallcom.2022.164046
71. [71]
  (71) Liu, L.; Wang, Z.; Zhang, J.; Ruzimuradov, O.; Dai, K.; Low, J. Adv. Mater. 2023, 35, 2300643. doi:10.1002/adma.202300643
72. [72]
  (72) Wang, W.; Li, X.; Deng, F.; Liu, J.; Gao, X.; Huang, J.; Xu, J.; Feng, Z.; Chen, Z.; Han, L. Chin. Chem. Lett. 2022, 33, 5200. doi:10.1016/j.cclet.2022.01.058
73. [73]
  (73) Huang, B.; Fu, X.; Wang, K.; Wang, L.; Zhang, H.; Liu, Z.; Liu, B.; Li, J. Adv. Powder Mater. 2024, 100140. doi:10.1016/j.apmate.2023.100140
74. [74]
  (74) Ning, R.; Pang, H.; Yan, Z.; Lu, Z.; Wang, Q.; Wu, Z.; Dai, W.; Liu, L.; Li, Z.; Fan, G.; et al. J. Hazard. Mater. 2022, 435, 129061. doi:10.1016/j.jhazmat.2022.129061
75. [75]
  (75) Wang, W.; Wang, Z.; Hu, Y.; Liu, Y.; Chen, S. eScience 2022, 2, 438. doi:10.1016/j.esci.2022.04.004
76. [76]
  (76) He, H.; Wang, Z.; Dai, K.; Li, S.; Zhang, J. Chin. J. Catal. 2023, 48, 267. doi:10.1016/S1872-2067(23)64420-1
77. [77]
  (77) Hua, J.; Wang, Z.; Zhan, J.; Dai, K.; Shao, C.; Fan, K. J. Mater. Sci. Technol. 2023, 156, 64. doi:10.1016/j.jmst.2023.03.003
78. [78]
  (78) Li, S.; Liang, J.; Wei, P.; Liu, Q.; Xie, L.; Luo, Y.; Sun, X. eScience 2022, 2, 382. doi:10.1016/j.esci.2022.04.008
79. [79]
  (79) Liu, Y.; Yu, F.; Wang, F.; Bai, S.; He, G. Chin. J. Struct. Chem. 2022, 41, 2201034. doi:10.14102/j.cnki.0254-5861.2021-0046
80. [80]
  (80) Gómez-Avilés, A.; Solís, R. R.; García-Frutos, E. M.; Bedia, J.; Belver, C. Chem. Eng. J. 2023, 461, 141889. doi:10.1016/j.cej.2023.141889
81. [81]
  (81) Li, X.; Hu, Y.; Dong, F.; Huang, J.; Han, L.; Deng, F.; Luo, Y.; Xie, Y.; He, C.; Feng, Z.; et al. Appl. Catal. B 2023, 325, 122341. doi:10.1016/j.apcatb.2022.122341
82. [82]
  (82) Ghoreishian, S. M.; Ranjith, K. S.; Park, B.; Hwang, S. K.; Hosseini, R.; Behjatmanesh-Ardakani, R.; Pourmortazavi, S. M.; Lee, H. U.; Son, B.; Mirsadeghi, S.; et al. Chem. Eng. J. 2021, 419, 129530. doi:10.1016/j.cej.2021.129530
83. [83]
  (83) Li, X.; Liu, T.; Zhang, Y.; Cai, J.; He, M.; Li, M.; Chen, Z.; Zhang, L. Adv. Fiber Mater. 2022, 4, 1620. doi:10.1007/s42765-022-00189-w
84. [84]
  (84) Feng, X.; Sun, L.; Wang, W.; Zhao, Y.; Shi, J. Sep. Purif. Technol. 2023, 324, 124520. doi:10.1016/j.seppur.2023.124520
85. [85]
  (85) Sun, G.; Xiao, B.; Zheng, H.; Shi, J. W.; Mao, S.; He, C.; Li, Z.; Cheng, Y. J. Mater. Chem. A 2021, 9, 9735. doi:10.1039/D1TA01089A
86. [86]
  (86) Xiong, X.; Yang, H.; Zhang, J.; Lin, J.; Yang, S.; Chen, C.; Xi, J.; Kong, Z.; Song, L.; Zeng, J. J. Alloy. Compd. 2023, 933, 167784. doi:10.1016/j.jallcom.2022.167784
87. [87]
88. [88]
  (88) Li, S.; Shao, L.; Yang, Z.; Cheng, S.; Yang, C.; Liu, Y.; Xia, X. Green Energy Environ. 2022, 7, 246. doi:10.1016/j.gee.2020.09.005
89. [89]
  (89) Xu, F.; Meng, K.; Cheng, B.; Wang, S.; Xu, J.; Yu, J. Nat. Commun. 2020, 11, 4613. doi:10.1038/s41467-020-18350-7
90. [90]
  (90) Bhosale, A. H.; Narra, S.; Bhosale, S. S.; Diau, E. W. -G. J. Phys. Chem. Lett. 2022, 13, 7987. doi:10.1021/acs.jpclett.2c02153
91. [91]
  (91) Cheng, C.; He, B.; Fan, J.; Cheng, B.; Cao, S.; Yu, J. Adv. Mater. 2021, 33, 2100317. doi:10.1002/adma.202100317
1. [1]
  Yuejiao An , Wenxuan Liu , Yanfeng Zhang , Jianjun Zhang , Zhansheng Lu . Revealing Photoinduced Charge Transfer Mechanism of SnO₂/BiOBr S-Scheme Heterostructure for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2407021-. doi: 10.3866/PKU.WHXB202407021
2. [2]
  Jianyu Qin , Yuejiao An , Yanfeng Zhang . In Situ Assembled ZnWO₄/g-C₃N₄ S-Scheme Heterojunction with Nitrogen Defect for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408002-. doi: 10.3866/PKU.WHXB202408002
3. [3]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031
4. [4]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
5. [5]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005
6. [6]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020
7. [7]
  Jiaxing Cai , Wendi Xu , Haoqiang Chi , Qian Liu , Wa Gao , Li Shi , Jingxiang Low , Zhigang Zou , Yong Zhou . 具有0D/2D界面的InOOH/ZnIn₂S₄空心球S型异质结用于增强光催化CO₂转化性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407002-. doi: 10.3866/PKU.WHXB202407002
8. [8]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
9. [9]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . 引入内建电场强化BiOBr/C₃N₅ S型异质结中光载流子分离以实现高效催化降解微污染物. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-. doi: 10.3866/PKU.WHXB202407014
10. [10]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
11. [11]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
12. [12]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
13. [13]
  Yang Xia , Kangyan Zhang , Heng Yang , Lijuan Shi , Qun Yi . 构建双通道路径增强iCOF/Bi₂O₃ S型异质结在纯水体系中光催化合成H₂O₂性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407012-. doi: 10.3866/PKU.WHXB202407012
14. [14]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
15. [15]
  Yujia LI , Tianyu WANG , Fuxue WANG , Chongchen WANG . Direct Z-scheme MIL-100(Fe)/BiOBr heterojunctions: Construction and photo-Fenton degradation for sulfamethoxazole. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 481-495. doi: 10.11862/CJIC.20230314
16. [16]
  Fei Jin , Bolin Yang , Xuanpu Wang , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Facilitating efficient photocatalytic hydrogen evolution via enhanced carrier migration at MOF-on-MOF S-scheme heterojunction interfaces through a graphdiyne (CnH2n-2) electron transport layer. Chinese Journal of Structural Chemistry, 2023, 42(12): 100198-100198. doi: 10.1016/j.cjsc.2023.100198
17. [17]
  Huihui LIU , Baichuan ZHAO , Chuanhui WANG , Zhi WANG , Congyun ZHANG . Green synthesis of MIL-101/Au composite particles and their sensitivity to Raman detection of thiram. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2021-2030. doi: 10.11862/CJIC.20240059
18. [18]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
19. [19]
  Maosen Xu , Pengfei Zhu , Qinghong Cai , Meichun Bu , Chenghua Zhang , Hong Wu , Youzhou He , Min Fu , Siqi Li , Xingyan Liu . In-situ fabrication of TiO₂/NH₂−MIL-125(Ti) via MOF-driven strategy to promote efficient interfacial effects for enhancing photocatalytic NO removal activity. Chinese Chemical Letters, 2024, 35(10): 109524-. doi: 10.1016/j.cclet.2024.109524
20. [20]
  Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-. doi: 10.3866/PKU.WHXB202312010

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(92)
HTML views(1)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142