Citation: Shuang Cao, Bo Zhong, Chuanbiao Bie, Bei Cheng, Feiyan Xu. WO₃/Zn_0.5Cd_0.5S S型异质结光催化产氢耦合有机物转化机理研究[J]. Acta Physico-Chimica Sinica, ;2024, 40(5): 230701. doi: 10.3866/PKU.WHXB202307016 shu

WO₃/Zn_0.5Cd_0.5S S型异质结光催化产氢耦合有机物转化机理研究

1.
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China;
2.
Laboratory of Solar Fuel, Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan 430078, China

Received Date: 11 July 2023
Revised Date: 25 July 2023
Accepted Date: 25 July 2023

Fund Project: This work was supported by the National Key Research and Development Program of China (2022YFB3803600, 2022YFE0115900), National Natural Science Foundation of China (52003213, 22238009, 22261142666, 52073223, 22278324, 51932007), and the Natural Science Foundation of Hubei Province of China (2022CFA001).

开发新型纳米材料实现光催化产氢耦合有机物转化、提高太阳能到化学能的转换效率，在解决能源和环境危机方面具有巨大潜力。三元金属硫化物具有可调控的带隙和优异的可见光响应，在光催化分解水产氢方面引起了广泛关注。其中，Zn_0.5Cd_0.5S是一种带隙较窄、导带位置较高、耐光腐蚀的还原型光催化剂；然而，单一Zn_0.5Cd_0.5S中光生电子和空穴的复合率较高，只有少部分光生载流子参与光催化反应，导致量子效率较低而无法达到实际需求。WO₃是一种典型的氧化型光催化剂，具有较低的价带位置和较强的氧化能力，是与Zn_0.5Cd_0.5S耦合构建S型异质结的理想半导体。基于此，本文通过静电纺丝和水热方法将Zn_0.5Cd_0.5S纳米片垂直生长在WO₃纳米纤维上，制备了具有核壳结构的WO₃/Zn_0.5Cd_0.5S异质结。功函数的差异驱动Zn_0.5Cd_0.5S的电子转移到WO₃上，在界面处形成内建电场并使能带弯曲。通过原位光照X射线光电子能谱、电子顺磁共振和时间分辨荧光光谱分析，发现在内建电场、弯曲能带和库仑吸引力的作用下，WO₃导带上的光生电子迁移到Zn_0.5Cd_0.5S价带上并与其光生空穴复合，表明WO₃和Zn_0.5Cd_0.5S之间形成了S型异质结，实现了具有强氧化还原能力的载流子的高效分离。得益于独特的S型光催化机制以及反应物在催化剂表面的有效吸附与活化，没有贵金属助催化剂的情况下，WO₃/Zn_0.5Cd_0.5S异质结在产氢(715 μmol·g^-1·h^-1)和乳酸转化为丙酮酸方面表现出增强的光催化活性，实现了光生电子和空穴的高效利用。原位漫反射傅里叶变换红外光谱和密度泛函理论计算揭示了光催化产氢和有机物转化的反应机理。本工作为设计和研究新型S型异质结光催化剂、实现高效产氢耦合有机物转化提供了新的见解。
- Tungsten oxide,
- S-scheme heterojunction,
- Hydrogen production,
- Organic transformation,
- Chemisorption and activation
1. [1]
  (1) Domaschke, M.; Zhou, X.; Wergen, L.; Romeis, S.; Miehlich, M. E.; Meyer, K.; Peukert, W.; Schmuki, P. ACS Catal. 2019, 9, 3627. doi: 10.1021/acscatal.9b00578
2. [2]
  (2) Liu, Q.; Shen, J.; Yu, X.; Yang, X.; Liu, W.; Yang, J.; Tang, H.; Xu, H.; Li, H.; Li, Y.; et al. Appl. Catal. B 2019, 248, 84. doi: 10.1016/j.apcatb.2019.02.020
3. [3]
  (3) Tuna Genç, M.; Sarilmaz, A.; Dogan, S.; Aksoy Çekceoğlu, İ.; Ozen, A.; Aslan, E.; Saner Okan, B.; Jaafar, J.; Ozel, F.; Ersoz, M.; et al. Int. J. Hydrog. Energy 2023, 38, 253. doi: 10.1016/j.ijhydene.2023.04.185
4. [4]
  (4) Lin, K.; Wang, Z.; Hu, Z.; Luo, P.; Yang, X.; Zhang, X.; Rafiq, M.; Huang, F.; Cao, Y. J. Mater. Chem. A 2019, 7, 19087. doi: 10.1039/c9ta06219j
5. [5]
  (5) Wang, L.; Fei, X.; Zhang, L.; Yu, J.; Cheng, B.; Ma, Y. J. Mater. Sci. Technol. 2022, 112, 1. doi: 10.1016/j.jmst.2021.10.016
6. [6]
  (6) Gao, R.; Cheng, B.; Fan, J.; Yu, J.; Ho, W. Chin. J. Catal. 2021, 42, 15. doi: 10.1016/s1872-2067(20)63614-2
7. [7]
  (7) Lei, Y.; Zhang, Y.; Li, Z.; Xu, S.; Huang, J.; Hoong Ng, K.; Lai, Y. Chem. Eng. J. 2021, 425, 131478. doi: 10.1016/j.cej.2021.131478
8. [8]
  (8) Liu, Y.; Sun, Z.; Hu, Y. H. Chem. Eng. J. 2021, 409, 128250. doi: 10.1016/j.cej.2020.128250
9. [9]
  (9) Wageh, S.; Al-Ghamdi, A. A.; Al-Hartomy, O. A.; Alotaibi, M. F.; Wang, L. Chin. J. Catal. 2022, 43, 586. doi: 10.1016/s1872-2067(21)63925-6
10. [10]
11. [11]
  (11) Wang, L.; Yang, T.; Peng, L.; Zhang, Q.; She, X.; Tang, H.; Liu, Q. Chin. J. Catal. 2022, 43, 2720. doi: 10.1016/S1872-2067(22)64133-0
12. [12]
  (12) Lin, S.; Zhang, N.; Wang, F.; Lei, J.; Zhou, L.; Liu, Y.; Zhang, J. ACS Sustain. Chem. Eng. 2020, 9, 481. doi: 10.1021/acssuschemeng.0c07753
13. [13]
  (13) Qin, D.; Xia, Y.; Li, Q.; Yang, C.; Qin, Y.; Lv, K. J. Mater. Sci. Technol. 2020, 56, 206. doi: 10.1016/j.jmst.2020.03.034
14. [14]
  (14) Zhen, W.; Ning, X.; Yang, B.; Wu, Y.; Li, Z.; Lu, G. Appl. Catal. B 2018, 221, 243. doi: 10.1016/j.apcatb.2017.09.024
15. [15]
  (15) Gao, D.; Xu, J.; Wang, L.; Zhu, B.; Yu, H.; Yu, J. Adv. Mater. 2022, 34, 2108475. doi: 10.1002/adma.202108475
16. [16]
  (16) Cao, S.; Yu, J.; Wageh, S.; Al-Ghamdi, A. A.; Mousavi, M.; Ghasemi, J. B.; Xu, F. J. Mater. Chem. A 2022, 10, 17174. doi: 10.1039/d2ta05181h
17. [17]
  (17) Cheng, C.; He, B.; Fan, J.; Cheng, B.; Cao, S.; Yu, J. Adv. Mater. 2021, 33, 2100317. doi: 10.1002/adma.202100317
18. [18]
  (18) Gao, D.; Deng, P.; Zhang, J.; Zhang, L.; Wang, X.; Yu, H.; Yu, J. Angew. Chem. Int. Ed. 2023, 62, e202304559. doi: 10.1002/anie.202304559
19. [19]
20. [20]
21. [21]
  (21) Liu, K.; Peng, L.; Zhen, P.; Chen, L.; Song, S.; Garcia, H.; Sun, C. J. Phys. Chem. C 2021, 125, 14656. doi: 10.1021/acs.jpcc.1c03535
22. [22]
  (22) Wang, K.; Li, S.; Wang, G.; Li, Y.; Li, Y.; Jin, Z. Int. J. Energy Res. 2022, 46, 19508. doi: 10.1002/er.8522
23. [23]
  (23) Zou, Y.; Guo, C.; Cao, X.; Chen, T.; Kou, Y.; Zhang, L.; Wang, T.; Akram, N.; Wang, J. Int. J. Hydrog. Energy 2022, 47, 25289. doi: 10.1016/j.ijhydene.2022.05.251
24. [24]
  (24) Cheng, C.; Zhang, J.; Zhu, B.; Liang, G.; Zhang, L.; Yu, J. Angew. Chem. Int. Ed. 2023, 62, e202218688. doi: 10.1002/anie.202218688
25. [25]
  (25) Xia, Y.; Zhu, B.; Li, L.; Ho, W.; Wu, J.; Chen, H.; Yu, J. Small 2023, 19, 2301928. doi: 10.1002/smll.202301928
26. [26]
  (26) Zhang, J.; Le, Y.; Zhang, Y. J. Mater. Sci. Technol. 2023, 142, 121. doi: 10.1016/j.jmst.2022.11.001
27. [27]
  (27) Cao, B.; Wan, S.; Wang, Y.; Guo, H.; Ou, M.; Zhong, Q. J. Colloid Interface Sci. 2022, 605, 311. doi: 10.1016/j.jcis.2021.07.113
28. [28]
  (28) He, F.; Meng, A.; Cheng, B.; Ho, W.; Yu, J. Chin. J. Catal. 2020, 41, 9. doi: 10.1016/s1872-2067(19)63382-6
29. [29]
  (29) Huang, D.; Wen, M.; Zhou, C.; Li, Z.; Cheng, M.; Chen, S.; Xue, W.; Lei, L.; Yang, Y.; Xiong, W.; Wang, W. Appl. Catal. B 2020, 267, 118651. doi: 10.1016/j.apcatb.2020.118651
30. [30]
  (30) Li, H.; Hao, X.; Liu, Y.; Li, Y.; Jin, Z. J. Colloid Interface Sci. 2020, 572, 62. doi: 10.1016/j.jcis.2020.03.052
31. [31]
  (31) Ye, H.-F.; Shi, R.; Yang, X.; Fu, W.-F.; Chen, Y. Appl. Catal. B 2018, 233, 70. doi: 10.1016/j.apcatb.2018.03.060
32. [32]
  (32) Cai, M.; Liu, Y.; Dong, K.; Wang, C.; Li, S. J. Colloid Interface Sci. 2023, 629, 276. doi: 10.1016/j.jcis.2022.08.136
33. [33]
  (33) Li, S.; Yan, R.; Cai, M.; Jiang, W.; Zhang, M.; Li, X. J. Mater. Sci. Technol. 2023, 164, 59. doi: 10.1016/j.jmst.2023.05.009
34. [34]
  (34) Cai, M.; Wang, C.; Liu, Y.; Yan, R.; Li, S. Sep. Purif. Technol. 2022, 300, 121892. doi: 10.1016/j.seppur.2022.121892
35. [35]
  (35) Dai, D.; Xu, H.; Ge, L.; Han, C.; Gao, Y.; Li, S.; Lu, Y. Appl. Catal. B 2017, 217, 429. doi: 10.1016/j.apcatb.2017.06.014
36. [36]
  (36) Shao, Z.; He, Y.; Zeng, T.; Yang, Y.; Pu, X.; Ge, B.; Dou, J. J. Alloy. Compd. 2018, 769, 889. doi: 10.1016/j.jallcom.2018.08.064
37. [37]
  (37) Wang, P.; Zhan, S.; Wang, H.; Xia, Y.; Hou, Q.; Zhou, Q.; Li, Y.; Kumar, R. R. Appl. Catal. B 2018, 230, 210. doi: 10.1016/j.apcatb.2018.02.043
38. [38]
  (38) Zhang, L.; Zhang, F.; Xue, H.; Gao, J.; Peng, Y.; Song, W.; Ge, L. Chin. J. Catal. 2021, 42, 1677. doi: 10.1016/S1872-2067(21)63791-9
39. [39]
  (39) Bai, J.; Chen, W.; Hao, L.; Shen, R.; Zhang, P.; Li, N.; Li, X. Chem. Eng. J. 2022, 447, 137488. doi: 10.1016/j.cej.2022.137488
40. [40]
  (40) Bai, J.; Shen, R.; Chen, W.; Xie, J.; Zhang, P.; Jiang, Z.; Li, X. Chem. Eng. J. 2022, 429, 132587. doi: 10.1016/j.cej.2021.132587
41. [41]
  (41) Wang, Y.; Ying, M.; Zhang, M.; Ren, X.; Kim, I. S. Macromol. Mater. Eng. 2021, 306, 2100587. doi: 10.1002/mame.202100587
42. [42]
  (42) Zhang, L.; Zhang, J.; Yu, H.; Yu, J. Adv. Mater. 2022, 34, 2107668. doi: 10.1002/adma.202107668
43. [43]
  (43) Zhu, B.; Tan, H.; Fan, J.; Cheng, B.; Yu, J.; Ho, W. J. Materiomics 2021, 7, 988. doi: 10.1016/j.jmat.2021.02.015
44. [44]
  (44) Dai, Z.; Zhen, Y.; Sun, Y.; Li, L.; Ding, D. Chem. Eng. J. 2021, 415, 129002. doi: 10.1016/j.cej.2021.129002
45. [45]
  (45) Xu, Q.; Wageh, S.; Al-Ghamdi, A. A.; Li, X. J. Mater. Sci. Technol. 2022, 124, 171. doi: 10.1016/j.jmst.2022.02.016
46. [46]
  (46) Li, H.; Tao, S.; Wan, S.; Qiu, G.; Long, Q.; Yu, J.; Cao, S. Chin. J. Catal. 2023, 46, 167. doi: 10.1016/S1872-2067(22)64201-3
47. [47]
  (47) Dai, M.; He, Z.; Zhang, P.; Li, X.; Wang, S. J. Mater. Sci. Technol. 2022, 122, 231. doi: 10.1016/j.jmst.2022.02.014
48. [48]
  (48) Kumar, A.; Khosla, A.; Kumar Sharma, S.; Dhiman, P.; Sharma, G.; Gnanasekaran, L.; Naushad, M.; Stadler, F. J. Fuel 2023, 333, 126267. doi: 10.1016/j.fuel.2022.126267
49. [49]
  (49) Wang, L.; Bie, C.; Yu, J. Trends in Chem. 2022, 4, 973. doi: 10.1016/j.trechm.2022.08.008
50. [50]
  (50) Xi, Y.; Chen, W.; Dong, W.; Fan, Z.; Wang, K.; Shen, Y.; Tu, G.; Zhong, S.; Bai, S. ACS Appl. Mater. Interfaces 2021, 13, 39491. doi: 10.1021/acsami.1c11233
51. [51]
  (51) Zhang, B.; Hu, X.; Liu, E.; Fan, J. Chin. J. Catal. 2021, 42, 1519. doi: 10.1016/S1872-2067(20)63765-2
52. [52]
  (52) Wang, X.; Sayed, M.; Ruzimuradov, O.; Zhang, J.; Fan, Y.; Li, X.; Bai, X.; Low, J. Appl. Mater. Today 2022, 29, 101609. doi: 10.1016/j.apmt.2022.101609
53. [53]
  (53) Li, S.; Cai, M.; Liu, Y.; Wang, C.; Lv, K.; Chen, X. Chin. J. Catal. 2022, 43, 2652. doi: 10.1016/s1872-2067(22)64106-8
54. [54]
  (54) Dutta, V.; Sharma, S.; Raizada, P.; Thakur, V. K.; Khan, A. A. P.; Saini, V.; Asiri, A. M.; Singh, P. J. Environ. Chem. Eng. 2021, 9, 105018. doi: 10.1016/j.jece.2020.105018
55. [55]
  (55) Xiang, X.; Zhu, B.; Zhang, J.; Jiang, C.; Chen, T.; Yu, H.; Yu, J.; Wang, L. Appl. Catal. B 2023, 324, 122301. doi: 10.1016/j.apcatb.2022.122301
56. [56]
  (56) Yang, Y.; Wu, J.; Cheng, B.; Zhang, L.; Al-Ghamdi, A. A.; Wageh, S.; Li, Y. Chin. J. Struct. Chem. 2022, 41, 2206006. doi: 10.14102/j.cnki.0254-5861.2022-0124
57. [57]
  (57) Jiang, J.; Wang, G.; Shao, Y.; Wang, J.; Zhou, S.; Su, Y. Chin. J. Catal. 2022, 43, 329. doi: 10.1016/S1872-2067(21)63889-5
58. [58]
  (58) Wei, Y.; Zhang, Q.; Zhou, Y.; Ma, X.; Wang, L.; Wang, Y.; Sa, R.; Long, J.; Fu, X.; Yuan, R. Chin. J. Catal. 2022, 43, 2665. doi: 10.1016/S1872-2067(22)64124-X
59. [59]
  (59) Zhang, J.; Zhang, L.; Wang, W.; Yu, J. J. Phys. Chem. Lett. 2022, 13, 8462. doi: 10.1021/acs.jpclett.2c02125
60. [60]
  (60) He, B.; Wang, Z.; Xiao, P.; Chen, T.; Yu, J.; Zhang, L. Adv. Mater. 2022, 34, 2203225. doi: 10.1002/adma.202203225
61. [61]
1. [1]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
2. [2]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020
3. [3]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
4. [4]
  Jiaxing Cai , Wendi Xu , Haoqiang Chi , Qian Liu , Wa Gao , Li Shi , Jingxiang Low , Zhigang Zou , Yong Zhou . 具有0D/2D界面的InOOH/ZnIn₂S₄空心球S型异质结用于增强光催化CO₂转化性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407002-. doi: 10.3866/PKU.WHXB202407002
5. [5]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . 引入内建电场强化BiOBr/C₃N₅ S型异质结中光载流子分离以实现高效催化降解微污染物. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-. doi: 10.3866/PKU.WHXB202407014
6. [6]
  Jingzhao Cheng , Shiyu Gao , Bei Cheng , Kai Yang , Wang Wang , Shaowen Cao . 4-氨基-1H-咪唑-5-甲腈修饰供体-受体型氮化碳光催化剂的构建及其高效光催化产氢研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-. doi: 10.3866/PKU.WHXB202406026
7. [7]
  Yuejiao An , Wenxuan Liu , Yanfeng Zhang , Jianjun Zhang , Zhansheng Lu . Revealing Photoinduced Charge Transfer Mechanism of SnO₂/BiOBr S-Scheme Heterostructure for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2407021-. doi: 10.3866/PKU.WHXB202407021
8. [8]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031
9. [9]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005
10. [10]
  Jianyu Qin , Yuejiao An , Yanfeng Zhang . In Situ Assembled ZnWO₄/g-C₃N₄ S-Scheme Heterojunction with Nitrogen Defect for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408002-. doi: 10.3866/PKU.WHXB202408002
11. [11]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
12. [12]
  Yang Xia , Kangyan Zhang , Heng Yang , Lijuan Shi , Qun Yi . 构建双通道路径增强iCOF/Bi₂O₃ S型异质结在纯水体系中光催化合成H₂O₂性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407012-. doi: 10.3866/PKU.WHXB202407012
13. [13]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
14. [14]
  Peipei Sun , Jinyuan Zhang , Yanhua Song , Zhao Mo , Zhigang Chen , Hui Xu . 引入内建电场增强光载流子分离以促进H₂的生产. Acta Physico-Chimica Sinica, 2024, 40(11): 2311001-. doi: 10.3866/PKU.WHXB202311001
15. [15]
  Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-. doi: 10.3866/PKU.WHXB202312010
16. [16]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
17. [17]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030
18. [18]
  Qianqian Liu , Xing Du , Wanfei Li , Wei-Lin Dai , Bo Liu . Synergistic Effects of Internal Electric and Dipole Fields in SnNb₂O₆/Nitrogen-Enriched C₃N₅ S-Scheme Heterojunction for Boosting Photocatalytic Performance. Acta Physico-Chimica Sinica, 2024, 40(10): 2311016-. doi: 10.3866/PKU.WHXB202311016
19. [19]
  Aidang Lu , Yunting Liu , Yanjun Jiang . Comprehensive Organic Chemistry Experiment: Synthesis and Characterization of Triazolopyrimidine Compounds. University Chemistry, 2024, 39(8): 241-246. doi: 10.3866/PKU.DXHX202401029
20. [20]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(93)
HTML views(1)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

WO3/Zn0.5Cd0.5S S型异质结光催化产氢耦合有机物转化机理研究

Metrics

通讯作者: 陈斌, bchen63@163.com

WO₃/Zn_0.5Cd_0.5S S型异质结光催化产氢耦合有机物转化机理研究