Citation: Xue Xiao, Jiachun Li, Xiangtong Meng, Jieshan Qiu. 硫掺杂碳包覆Fe_0.95S_1.05纳米球复合材料的储钠性能[J]. Acta Physico-Chimica Sinica, ;2024, 40(6): 230700. doi: 10.3866/PKU.WHXB202307006 shu

硫掺杂碳包覆Fe_0.95S_1.05纳米球复合材料的储钠性能

State Key Laboratory of Organic-Inorganic Composites, State Key Laboratory of Chemical Resource Engineering, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China

Corresponding author: Xiangtong Meng, Jieshan Qiu,
Received Date: 3 July 2023
Revised Date: 4 August 2023
Accepted Date: 5 August 2023

Fund Project: The project was supported by the National Natural Science Foundation of China (52002014, U2003216), the Natural Science Foundation of Guangxi (2021GXNSFAA220018), and the Shenzhen Science and Technology Program (CJGJZD20210408092801005).

铁硫化物因其较高的理论容量，被认为是一种很有前途的钠离子电池负极材料。然而，铁硫化物在充放电过程中存在较大的体积变化，导致其倍率性能和稳定性较差。本文通过简单的一步法策略，制备了一种具有三维簇状结构的硫掺杂碳包覆的Fe_0.95S_1.05纳米球（Fe_0.95S_1.05@SC），并研究了其储钠性能。硫掺杂碳层可提高材料的导电率，缓解Fe_0.95S_1.05纳米球在反应过程中产生的体积膨胀，故提升了材料的稳定性。Fe_0.95S_1.05@SC的相互贯通的簇状结构，为电子和离子的传输提供了通道，使材料具备优异的倍率性能。在半电池体系中，Fe_0.95S_1.05@SC在0.1 A·g^-1下循环100圈后，保留614.7 mAh·g^-1的高比容量，10 A·g^-1下比容量仍可以达到235.7 mAh·g^-1。在全电池体系中，在0.1和10 A·g^-1时，Fe_0.95S_1.05@SC的可逆容量分别为482.8和288.3 mAh·g^-1。该材料具有良好电化学性能，在钠离子电池中具有广阔的应用前景。
- Sodium ion battery,
- Anode,
- Sulfur-doped carbon,
- Fe_0.95S_1.05@SC electrode
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硫掺杂碳包覆Fe0.95S1.05纳米球复合材料的储钠性能

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硫掺杂碳包覆Fe_0.95S_1.05纳米球复合材料的储钠性能