Citation: Gaopeng Liu, Lina Li, Bin Wang, Ningjie Shan, Jintao Dong, Mengxia Ji, Wenshuai Zhu, Paul K. Chu, Jiexiang Xia, Huaming Li. Construction of Bi Nanoparticles Loaded BiOCl Nanosheets Ohmic Junction for Photocatalytic CO₂ Reduction[J]. Acta Physico-Chimica Sinica, ;2024, 40(7): 230604. doi: 10.3866/PKU.WHXB202306041 shu

Construction of Bi Nanoparticles Loaded BiOCl Nanosheets Ohmic Junction for Photocatalytic CO₂ Reduction

Gaopeng Liu ¹ ,
Lina Li ¹ ,
Bin Wang ^{1, 2} ,
Ningjie Shan ¹ ,
Jintao Dong ¹ ,
Mengxia Ji ¹ ,
Wenshuai Zhu ^1,, ,
Paul K. Chu ² ,
Jiexiang Xia ^1,, ,
Huaming Li ^1,,

1.
Institute for Energy Research, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu Province, China
2.
Department of Physics, Department of Materials Science and Engineering, and Department of Biomedical Engineering, City University of Hong Kong, Hong Kong 999077, China

Corresponding author: Wenshuai Zhu, zhuws@ujs.edu.cn Jiexiang Xia, xjx@ujs.edu.cn Huaming Li, lhm@ujs.edu.cn
Received Date: 26 June 2023
Revised Date: 13 August 2023
Accepted Date: 29 August 2023
Available Online: 1 December 2023
Fund Project: the China Postdoctoral Science Foundation 2022M721380the China Postdoctoral Science Foundation 2020M680065Jiangsu Funding Program for Excellent Postdoctoral Talent 2023ZB214National Natural Science Foundation of China 22108106National Natural Science Foundation of China 22108108Hong Kong Scholar Program XJ2021021City University of Hong Kong Donation Research Grant DON-RMG, 9229021City University of Hong Kong Strategic Research Grant SRG, 7005505City University of Hong Kong Donation Grant 9220061

The continuous increase in the consumption of coal, oil, and natural gas has not only led to the depletion of unsustainable energy sources, but has also caused excessive CO₂ emissions, thus resulting in serious energy crises and climate issues. In such a scenario, it is imperative to explore clean and sustainable energy conversion technologies to address the escalating energy demands and environmental crises. Photocatalytic CO₂ conversion, inspired by natural photosynthesis, utilizes solar energy to convert CO₂ and water into valuable chemicals. After decades of development, artificial photosynthesis has emerged as a green, cost-effective, and sustainable approach to achieving carbon neutrality. However, the challenges of low carrier separation efficiency and insufficient active sites in photocatalysts remain significant hurdles in achieving high-performance CO₂ photoreduction. To address this challenge, the integration of metal nanoparticles with semiconductors to create an Ohmic junction can enhance electron-hole migration by the assist of interfacial electric field (IEF). In this study, an Ohmic junction photocatalyst is constructed by in situ formation of Bi nanoparticles on the surface of BiOCl nanosheets through a solvothermal process. The composition and morphology of the photocatalysts were analyzed using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and transmission electron microscopy (TEM). UV-Vis diffuse reflectance spectroscopy (UV-Vis DRS) was employed to assess the light absorption performance of the photocatalyst. Transient photocurrent response, electrochemical impedance spectroscopy (EIS), and electron spin resonance (ESR) were utilized to evaluate the efficiency of electron-hole transfer. The distinct work function difference between Bi nanoparticles and BiOCl nanosheets leads to favorable charge transfer characteristics within the formed Ohmic junction, significantly improving the utilization efficiency of photogenerated carriers. Besides, the Bi nanoparticles serve as co-catalysts, enhancing the activation of inert CO₂. As a result, the optimized Bi/BiOCl composite (Bi/BiOCl-2) exhibits enhanced generation rates of CO (34.31 µmol·g^-1) and CH₄ (1.57 µmol g^-1) during 4-h of irradiation, which is 2.55 and 4.76 times compared to pristine BiOCl nanosheets, respectively. Isotope tracer experiments suggest that the obtained carbon-based products are generated through CO₂ photoreduction in the presence of water molecule under irradiation. Moreover, in situ Fourier-transform infrared spectroscopy (in situ FTIR) results indicate the formation of *CHO, *CH₃O, b-CO₃^2-, m-CO₃^2-, HCO₃^-, HCOOH, *COOH, and HCOO^- species during the CO₂ reduction process and a possible mechanism for CO₂ photoreduction into CO and CH₄ is proposed based on these findings. After 25-h of CO₂ photoreduction reaction, the yields of CO and CH₄ continue to increase. Furthermore, the stability of the prepared material is confirmed by XRD pattern, XPS analysis, and TEM image. These outcomes underscore an effective strategy for constructing advanced photocatalysts tailored for high-performance solar-driven CO₂ reduction.
- BiOCl nanosheet,
- Bi nanoparticle,
- CO₂ photoreduction,
- Ohmic junction,
- Charge transfer
1. [1]
  Liang, J. X.; Yu, H.; Shi, J. J.; Li, B.; Wu, L. X.; Wang, M. Adv. Mater. 2023, 35, 2209814. doi: 10.1002/adma.202209814 doi: 10.1002/adma.202209814
2. [2]
  Wang, B.; Zhang, W.; Liu, G. P.; Chen, H. L.; Weng, Y. -X.; Li, H. M.; Chu, P. K.; Xia, J. X. Adv. Funct. Mater. 2022, 32, 2202885. doi: 10.1002/adfm.202202885 doi: 10.1002/adfm.202202885
3. [3]
  Wang, J. -C.; Qiao, X.; Shi, W. N.; He, J.; Chen, J.; Zhang, W. Q. Acta Phys. -Chim. Sin. 2023, 39, 2210003. doi: 10.3866/PKU.WHXB202210003 doi: 10.3866/PKU.WHXB202210003
4. [4]
  Yan, P. C.; Ji, F. W.; Zhang, W.; Mo, Z.; Qian, J. C.; Zhu, L. H.; Xu, L. J. Colloid Interface Sci. 2023, 634, 1005. doi: 10.1016/j.jcis.2022.12.063 doi: 10.1016/j.jcis.2022.12.063
5. [5]
  Li, H.; Li, F.; Yu, J. G.; Cao, S. W. Acta Phys. -Chim. Sin. 2021, 37, 2010073. doi: 10.3866/PKU.WHXB202010073 doi: 10.3866/PKU.WHXB202010073
6. [6]
  Yang, J. M.; Jing, L. Q.; Zhu, X. W.; Zhang, W.; Deng J. J.; She, Y. B.; Nie, K. Q.; Wei, Y. C.; Li, H. M.; Xu, H. Appl. Catal. B 2023, 320, 122005. doi: 10.1016/j.apcatb.2022.122005 doi: 10.1016/j.apcatb.2022.122005
7. [7]
  Das, R.; Paul, R.; Parui, A.; Shrotri, A.; Atzori, C.; Lomachenko, K. A.; Singh, A. K.; Mondal, J.; Peter, S. C. J. Am. Chem. Soc. 2023, 145, 422. doi: 10.1021/jacs.2c10351 doi: 10.1021/jacs.2c10351
8. [8]
  Liu, G. P.; Wang, L.; Chen, X.; Zhu, X. W.; Wang, B.; Xu, X. Y.; Chen, Z. R.; Zhu, W. S.; Li, H. M.; Xia, J. X. Green Chem. Eng. 2022, 3, 157. doi: 10.1016/j.gce.2021.11.007 doi: 10.1016/j.gce.2021.11.007
9. [9]
  Li, J.; Yu, X. M.; Xue, W. J.; Nie, L.; Huang, H. L.; Zhong, C. L. AIChE J. 2023, 69, e17906. doi: 10.1002/aic.17906 doi: 10.1002/aic.17906
10. [10]
  Li, S. G.; Chen, F.; Chu, S. Q.; Zhang, Z. Y.; Huang, J. D.; Wang, S. Y.; Feng, Y. B.; Wang, C.; Huang, H. W. Small 2023, 19, 2203559. doi: 10.1002/smll.202203559 doi: 10.1002/smll.202203559
11. [11]
  Dong, Y. -L.; Liu, H. -R.; Wang, S. -M.; Guan, G. -W.; Yang, Q. -Y. ACS Catal. 2023, 13, 2547. doi: 10.1021/acscatal.2c04588 doi: 10.1021/acscatal.2c04588
12. [12]
  Ni, M. M.; Zhu, Y. J.; Guo, C. F.; Chen, D. -L.; Ning, J. Q.; Zhong, Y. J.; Hu, Y. ACS Catal. 2023, 13, 2502. doi: 10.1021/acscatal.2c05577 doi: 10.1021/acscatal.2c05577
13. [13]
  Wei, J. J.; Dong, H. L.; Gao, Y. X.; Su, X.; Tan, H. W.; Li, J. J.; Zhao, Q.; Guan, X. W.; Lu, Z. L.; Ouyang, J.; et al. J. Mater. Chem. A 2023, 11, 4057. doi: 10.1039/d2ta08812f doi: 10.1039/d2ta08812f
14. [14]
  Cheng, S. W.; Sun, Z. H.; Lim, K. H.; Zhang, T. X.; Hondo, E.; Du, T.; Liu, L. Y.; Judd, M.; Cox, N.; Yin, Z. Y.; et al. ACS Appl. Nano Mater. 2023, 6, 3608. doi: 10.1021/acsanm.2c05364 doi: 10.1021/acsanm.2c05364
15. [15]
  Kong, B.; Zeng, T. X.; Wang, W. T. Phys. Chem. Chem. Phys. 2021, 23, 19841. doi: 10.1039/d1cp02794h doi: 10.1039/d1cp02794h
16. [16]
  Chen, C. Y.; Jiang, T.; Hou, J. H.; Zhang, T. T.; Zhang, G. S.; Zhang, Y. C.; Wang, X. Z. J. Mater. Sci. Technol. 2022, 114, 240. doi: 10.1016/j.jmst.2021.12.006 doi: 10.1016/j.jmst.2021.12.006
17. [17]
  Song, Y.; Ye, C. C.; Yu, X.; Tang, J. Y.; Zhao, Y. X.; Cai, W. Appl. Surf. Sci. 2022, 583, 152463. doi: 10.1016/j.apsusc.2022.152463 doi: 10.1016/j.apsusc.2022.152463
18. [18]
  Wang, S. -S.; Liang, X.; Lv, Y. -K.; Li, Y. -Y.; Zhou, R. -H.; Yao, H. -C.; Li, Z. -J. ACS Appl. Energy Mater. 2022, 5, 1149. doi: 10.1021/acsaem.1c03531 doi: 10.1021/acsaem.1c03531
19. [19]
  Gao, M. C.; Yang, J. X.; Sun, T.; Zhang, Z. Z.; Zhang, D. F.; Huang, H. J.; Lin, H. X.; Fang, Y.; Wang, X. X. Appl. Catal. B 2019, 243, 734. doi: 10.1016/j.apcatb.2018.11.020 doi: 10.1016/j.apcatb.2018.11.020
20. [20]
  Zhang, L.; Wang, W. Z.; Jiang, D.; Gao, E. P.; Sun, S. M. Nano Res. 2015, 8, 821. doi: 10.1007/s12274-014-0564-2 doi: 10.1007/s12274-014-0564-2
21. [21]
  Gong, S. W.; Rao, F.; Zhang, W. B.; Hassan, Q. -U.; Liu, Z. Q.; Gao, J. Z.; Lu, J. B.; Hojamberdiev, M.; Zhu, G. Q. Chin. Chem. Lett. 2022, 33, 4385. doi: 10.1016/j.cclet.2021.12.039 doi: 10.1016/j.cclet.2021.12.039
22. [22]
  Yao, D. F.; Liang, K. J.; Chen, G. L.; Qu, Y. D.; Liu, J. Y.; Chilivery, R.; Li, S.; Ji, M. W.; Li, Z.; Zhong, Z. Y.; et al. J. Catal. 2023, 422, 56. doi: 10.1016/j.jcat.2023.04.004 doi: 10.1016/j.jcat.2023.04.004
23. [23]
  Li, Y. -L.; Liu, Y.; Mu, H. -Y.; Liu, R. -H.; Hao, Y. -J.; Wang, X. -J.; Hildebrandt, D.; Liu, X. Y.; Li, F. -T. Nanoscale 2021, 13, 2585. doi: 10.1039/D0NR08314C doi: 10.1039/D0NR08314C
24. [24]
  Liu, X. Y.; Ye, M.; Zhang, S. P.; Huang, G. C.; Li, C. H.; Yu, J. G.; Wong, P. K.; Liu, S. W. J. Mater. Chem. A 2018, 6, 24245. doi: 10.1039/c8ta09661a doi: 10.1039/c8ta09661a
25. [25]
  Yan, F. P.; Wu, Y. H.; Jiang, L. Q.; Xue, X. G.; Lv, J. Q.; Lin, L. Y.; Yu, Y. L.; Zhang, J. Y.; Yang, F. G.; Qiu, Y. ChemSusChem 2020, 13, 876. doi: 10.1002/cssc.201903437 doi: 10.1002/cssc.201903437
26. [26]
  Pan, C.; Mao, Z.; Yuan, X.; Zhang, H. J.; Mei, L.; Ji, X. Y. Adv. Sci. 2022, 9, 2105747. doi: 10.1002/advs.202105747 doi: 10.1002/advs.202105747
27. [27]
  Wang, S. M.; Guan, Y.; Lu, L.; Shi, Z.; Yan, S. C.; Zou, Z. G. Appl. Catal. B 2018, 224, 10. doi: 10.1016/j.apcatb.2017.10.043 doi: 10.1016/j.apcatb.2017.10.043
28. [28]
  Li, Z.; Huang, F.; Xu, Y. F.; Yan, A. H.; Dong, H. M.; Xiong, X.; Zhao, X. H. Chem. Eng. J. 2022, 429, 132476. doi: 10.1016/j.cej.2021.132476 doi: 10.1016/j.cej.2021.132476
29. [29]
  Yang, Q.; Luo, M. L.; Liu, K. W.; Cao, H. M.; Yan, H. J. Chem. Commun. 2019, 55, 5728. doi: 10.1039/c9cc01732a doi: 10.1039/c9cc01732a
30. [30]
  Safardoust-Hojaghan, H.; Salavati-Niasari, M.; Motaghedifard, M. H.; Hosseinpour-Mashkani, S. M. New J. Chem. 2015, 39, 4676. doi: 10.1039/c5nj00532a doi: 10.1039/c5nj00532a
31. [31]
  Li, X. B.; Hu Y.; Dong, F.; Huang, J. T.; Han, L.; Deng, F.; Luo, Y. D.; Xie, Y.; He, C. Z.; Feng, Z. J.; et al. Appl. Catal. B 2023, 325, 122341. doi: 10.1016/j.apcatb.2022.122341 doi: 10.1016/j.apcatb.2022.122341
32. [32]
  Li, X. B.; Kang, B. B.; Dong, F.; Deng, F.; Han, L.; Gao, X. M.; Xu, J. L.; Hou, X. F.; Feng, Z. J.; Chen, Z.; et al. Appl. Surf. Sci. 2022, 593, 153422. doi: 10.1016/j.apsusc.2022.153422 doi: 10.1016/j.apsusc.2022.153422
33. [33]
  Huang, Y. W.; Zhu, Y. S.; Chen, S. J.; Xie, X. Q.; Wu, Z. J.; Zhang, N. Adv. Sci. 2021, 8, 2003626. doi: 10.1002/advs.202003626 doi: 10.1002/advs.202003626
34. [34]
  Gao, F. D.; Zeng, D. W.; Huang, Q. W.; Tian, S. Q.; Xie, C. S. Phys. Chem. Chem. Phys. 2012, 14, 10572. doi: 10.1039/c2cp41045a doi: 10.1039/c2cp41045a
35. [35]
  Peng, Y.; Mao, Y. G.; Kan, P. F.; Liu, J. Y.; Fang, Z. New J. Chem. 2018, 42, 16911. doi: 10.1039/c8nj03323d doi: 10.1039/c8nj03323d
36. [36]
  Wang, B.; Zhu, X. W.; Huang, F. C.; Quan, Y.; Liu, G. P.; Zhang, X. L.; Xiong, F. Y.; Huang, C.; Ji, M. X.; Li, H. M.; et al. Appl. Catal. B 2023, 325, 122304. doi: 10.1016/j.apcatb.2022.122304 doi: 10.1016/j.apcatb.2022.122304
37. [37]
  Wang, L.; Lv, D. D.; Yue, Z. J.; Zhu, H.; Wang, L.; Wang, D. F.; Xu, X.; Hao, W. C.; Dou, S. X.; Du, Y. Nano Energy 2019, 57, 398. doi: 10.1016/j.nanoen.2018.12.071 doi: 10.1016/j.nanoen.2018.12.071
38. [38]
  Wu, Z. X.; Wu, H. B.; Cai, W. Q.; Wen, Z. H.; Jia, B. H.; Wang, L.; Jin, W.; Ma, T. Y. Angew. Chem. Int. Ed. 2021, 60, 12554. doi: 10.1002/anie.202102832 doi: 10.1002/anie.202102832
39. [39]
  Dong, J. T.; Ji, S. N.; Zhang, Y.; Ji, M. X.; Wang, B.; Li, Y. J.; Chen, Z. G.; Xia, J. X.; Li, H. M. Acta Phys. -Chim. Sin. 2023, 39, 2212011. [] doi: 10.3866/PKU.WHXB202212011 doi: 10.3866/PKU.WHXB202212011
40. [40]
  Liu, G. P.; Wang, L.; Wang, B.; Zhu, X. W.; Yang, J. M.; Liu, P. J.; Zhu, W. S.; Chen, Z. R.; Xia, J. X. Chin. Chem. Lett. 2023, 34, 107962. doi: 10.1016/j.cclet.2022.107962 doi: 10.1016/j.cclet.2022.107962
41. [41]
  Liu, J. Y.; Zhu, S. M.; Wang, B.; Yang, R. Z.; Wang, R.; Zhu, X. W.; Song, Y. H.; Yuan, J. J.; Xu, H.; Li., H. M. Chin. Chem. Lett. 2023, 34, 107749. doi: 10.1016/j.cclet.2022.107749 doi: 10.1016/j.cclet.2022.107749
42. [42]
  Zan, Z. Q.; Li, X. B.; Gao, X. M.; Huang, J. T.; Luo, Y. D.; Han, L. Acta Phys. -Chim. Sin. 2023, 39, 2209016. doi: 10.3866/PKU.WHXB202209016 doi: 10.3866/PKU.WHXB202209016
43. [43]
  Yan, X. W.; Wang, B.; Ji, M. X.; Jiang, Q.; Liu, G. P.; Liu, P. J.; Yin, S.; Li, H. M.; Xia, J. X. Chin. J. Struct. Chem. 2022, 41, 2208044. doi: 10.14102/j.cnki.0254-5861.2022-0141 doi: 10.14102/j.cnki.0254-5861.2022-0141
44. [44]
  Yang, J. H.; Hou, Y. P.; Sun, J. L.; Liang, J. X.; Yu, Z. B.; Zhu, H. X.; Wang, S. F. Sep. Purif. Technol. 2022, 299, 121701. doi: 10.1016/j.seppur.2022.121701 doi: 10.1016/j.seppur.2022.121701
45. [45]
  Bai, S.; Li, X. Y.; Kong, Q.; Long, R.; Wang, C. M.; Jiang, J.; Xiong, Y. J. Adv. Mater. 2015, 27, 3444. doi: 10.1002/adma.201501200 doi: 10.1002/adma.201501200
46. [46]
  Gong, S. W.; Zhu, G. Q.; Wang, R.; Rao, F.; Shi, X. J.; Gao, J. Z.; Huang, Y.; He, C. Z.; Hojamberdiev, M. Appl. Catal. B 2021, 297, 120413. doi: 10.1016/j.apcatb.2021.120413 doi: 10.1016/j.apcatb.2021.120413
47. [47]
  Zhu, X. W.; Wang, Z. L.; Zhong, K.; Li, Q. D.; Ding, P. H.; Feng, Z. Y.; Yang, J. M.; Du, Y. S.; Song, Y. H.; Hua, Y. J.; et al. Chem. Eng. J. 2022, 429, 132204. doi: 10.1016/j.cej.2021.132204 doi: 10.1016/j.cej.2021.132204
48. [48]
  Yang, J. M.; Zhu, X. W.; Yu, Q.; He, M. Q.; Zhang, W.; Mo, Z.; Yuan, J. J.; She, Y. B.; Xu, H.; Li, H. M. Chin. J. Catal. 2022, 43, 1286. doi: 10.1016/s1872-2067[21]63954-2 doi: 10.1016/s1872-2067[21]63954-2
49. [49]
  Cai, X. Y.; Du, J. H.; Zhong, G. M.; Zhang, Y. M.; Mao, L.; Lou, Z. Z. Acta Phys. -Chim. Sin. 2023, 39, 2302017. doi: 10.3866/PKU.WHXB202302017 doi: 10.3866/PKU.WHXB202302017
50. [50]
  Mo, Z.; Miao, Z. H.; Yan, P. C.; Sun, P. P.; Wu, G. Y.; Zhu, X. W.; Ding, C.; Zhu, Q.; Lei, Y. C.; Xu, H. J. Colloid Interface Sci. 2023, 645, 525. doi: 10.1016/j.jcis.2023.04.123 doi: 10.1016/j.jcis.2023.04.123
51. [51]
  Li, X. W.; Wang, B.; Yin, W. X.; Di, J.; Xia, J. X.; Zhu, W. S.; Li, H. M. Acta Phys. -Chim. Sin. 2020, 36, 1902001. doi: 10.3866/PKU.WHXB201902001 doi: 10.3866/PKU.WHXB201902001
52. [52]
  Zhang, Y.; Guo, F. Y.; Wang, K. K.; Di, J.; Min, B.; Zhu, H. Y.; Chen, H. L.; Weng, Y. -X.; Dai, J. Y.; She, Y. B.; et al. Chem. Eng. J. 2023, 465, 142663. doi: 10.1016/j.cej.2023.142663 doi: 10.1016/j.cej.2023.142663
53. [53]
  Yu, Y. Y.; Dong, X. A.; Chen, P.; Geng, Q.; Wang, H.; Li, J. Y.; Zhou, Y.; Dong, F. ACS Nano 2021, 15, 14453. doi: 10.1021/acsnano.1c03961 doi: 10.1021/acsnano.1c03961
54. [54]
  Li, D. S.; Zhu, B. C.; Sun, Z. T.; Liu, Q. Q.; Wang, L. L.; Tang, H. Front. Chem. 2021, 9, 804204. doi: 10.3389/fchem.2021.804204 doi: 10.3389/fchem.2021.804204
55. [55]
  Yu, H. B.; Huang, J. H.; Jiang, L. B.; Leng, L. J.; Yi, K. X.; Zhang, W.; Zhang, C. Y.; Yuan, X. Z. Appl. Catal. 2021, 298, 120618. doi: 10.1016/j.apcatb.2021.120618 doi: 10.1016/j.apcatb.2021.120618
56. [56]
  Xu, Y. X.; Jin, X. L.; Ge, T.; Xie, H. Q.; Sun, R. X.; Su, F. Y.; Li, X.; Ye, L. Q. Chem. Eng. J. 2021, 409, 128178. doi: 10.1016/j.cej.2020.128178 doi: 10.1016/j.cej.2020.128178
57. [57]
  Jin, X. L.; Cao, J.; Wang, H. Q.; Lv, C. D.; Xie, H. Q.; Su, F. Y.; Li, X.; Sun, R. X.; Shi, S. K.; Dang, M. F.; et al. Appl. Surf. Sci. 2022, 598, 153758. doi: 10.1016/j.apsusc.2022.153758 doi: 10.1016/j.apsusc.2022.153758
58. [58]
  Meng, J. Z.; Duan, Y. Y.; Jing, S. J.; Ma, J. P.; Wang, K. W.; Zhou, K.; Ban, C. G.; Wang, Y.; Hu, B. H.; Yu, D. M.; et al. Nano Energy 2022, 92, 106671. doi: 10.1016/j.nanoen.2021.106671 doi: 10.1016/j.nanoen.2021.106671
59. [59]
  Sun, Z.; Liu, T. W.; Shen, Q. Q.; Li, H. M.; Liu, X. G.; Jia, H. S.; Xue, J. B. Appl. Surf. Sci. 2023, 616, 156530. doi: 10.1016/j.apsusc.2023.156530 doi: 10.1016/j.apsusc.2023.156530
60. [60]
  Li, X. F.; Li, K. M.; Ding, D.; Yan, J. T.; Wang, C. L.; Carabineiro, S. A. C.; Liu, Y.; Lv, K. L. Sep. Purif. Technol. 2023, 309, 123054. doi: 10.1016/j.seppur.2022.123054 doi: 10.1016/j.seppur.2022.123054
61. [61]
  Di, J.; Zhao, X. X.; Lian, C.; Ji, M. X.; Xia, J. X.; Xiong, J.; Zhou, W.; Cao, X. Z.; She, Y. B.; Liu, H. L.; et al. Nano Energy 2019, 61, 54. doi: 10.1016/j.nanoen.2019.04.029 doi: 10.1016/j.nanoen.2019.04.029
62. [62]
  Wang, J. Q.; Cheng, H.; Wei, D. Q.; Li, Z. H. Chin. J. Catal. 2022, 43, 2606. doi: 10.1016/S1872-2067[22]64091-9 doi: 10.1016/S1872-2067[22]64091-9
63. [63]
  Si, S. H.; Shou, H. W.; Mao, Y. Y.; Bao, X. L.; Zhai, G. Y.; Song, K. P.; Wang, Z. Y.; Wang, P.; Liu, Y. Y.; Zheng, Z. K.; et al. Angew. Chem. Int. Ed. 2022, 61, e202209446. doi: 10.1002/anie.202209446 doi: 10.1002/anie.202209446
64. [64]
  Ji, M. X.; Feng, J.; Zhao, J. Z.; Zhang, Y.; Wang, B.; Di, J.; Xu, X. Y.; Chen, Z. R.; Xia, J. X.; Li, H. M. ACS Appl. Nano Mater. 2022, 5, 17226. doi: 10.1021/acsanm.2c04232 doi: 10.1021/acsanm.2c04232
65. [65]
  Li, X. D.; Sun, Y. F.; Xu, J. Q.; Shao, Y. J.; Wu, J.; Xu, X. L.; Pan, Y.; Ju, H. X.; Zhu, J. F.; Xie, Y. Nat. Energy 2019, 4, 690. doi: 10.1038/s41560-019-0431-1 doi: 10.1038/s41560-019-0431-1
66. [66]
  Wang, J. Y.; Bo, T. T.; Shao, B. Y.; Zhang, Y. Z.; Jia, L. X.; Tan, X.; Zhou, W.; Yu, T. Appl. Catal. B 2021, 297, 120498. doi: 10.1016/j.apcatb.2021.120498 doi: 10.1016/j.apcatb.2021.120498
67. [67]
  Xu, J. Q.; Ju, Z. Y.; Zhang, W.; Pan, Y.; Zhu, J. F.; Mao, J. W.; Zheng, X. L.; Fu, H. Y.; Yuan, M. L.; Chen, H.; et al. Angew. Chem. Int. Ed. 2021, 60, 8705. doi:10.1002/anie.202017041 doi: 10.1002/anie.202017041
1. [1]
  Jianyu Qin , Yuejiao An , Yanfeng Zhang . In Situ Assembled ZnWO₄/g-C₃N₄ S-Scheme Heterojunction with Nitrogen Defect for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408002-0. doi: 10.3866/PKU.WHXB202408002
2. [2]
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6. [6]
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8. [8]
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9. [9]
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10. [10]
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11. [11]
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15. [15]
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16. [16]
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17. [17]
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18. [18]
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19. [19]
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20. [20]
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Construction of Bi Nanoparticles Loaded BiOCl Nanosheets Ohmic Junction for Photocatalytic CO2 Reduction

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通讯作者: 陈斌, bchen63@163.com

Construction of Bi Nanoparticles Loaded BiOCl Nanosheets Ohmic Junction for Photocatalytic CO₂ Reduction