Citation: Jiandong Liu, Xin Li, Daxiong Wu, Huaping Wang, Junda Huang, Jianmin Ma. 优化Li||NCM811电池电解液溶剂化和电极电解液界面的阴离子受体添加剂策略[J]. Acta Physico-Chimica Sinica, ;2024, 40(6): 230603. doi: 10.3866/PKU.WHXB202306039 shu

优化Li||NCM811电池电解液溶剂化和电极电解液界面的阴离子受体添加剂策略

Jiandong Liu ¹ ,
Xin Li ¹ ,
Daxiong Wu ¹ ,
Huaping Wang ¹ ,
Junda Huang ¹ ,
Jianmin Ma ^1,2,,

1.
School of Physics and Electronics, Hunan University, Changsha 410082, China;
2.
School of Chemistry, Tiangong University, Tianjin 300387, China

Corresponding author: Jianmin Ma, nanoelechem@hnu.edu.cn
Received Date: 26 June 2023
Revised Date: 1 August 2023
Accepted Date: 16 August 2023

Fund Project: The project was supported by the National Natural Science Foundation of China (51971090, U21A20311).

锂金属电池的循环稳定性和倍率能力受制于多个因素，如阳极/阴极电解液界面的品质和电解液溶剂化特性。在该工作中，我们提出了阴离子受体电解液添加剂策略，通过六氟苯添加剂对Li⁺溶剂化结构进行调控，实现了PF₆^-的稳定性并提高了电解液的导电性，优化了阳极/阴极电解液界面中间相的组分/结构特征，有效抑制了锂枝晶的生长和提升了阴极表面的Li⁺传输，Li||Li对称电池在1 mA·cm^-2的电流密度下实现超过400 h的稳定循环，并且Li||NCM811电池在200 mA·g^-1的电流密度下经过100次循环后的容量保持率达到75%。
- Electrolyte,
- Hexafluorobenzene,
- Anion acceptor,
- Lithium metal battery,
- Lithium anode,
- Anode/cathode electrolyte interphases
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