Citation: Chaolin Mi, Yuying Qin, Xinli Huang, Yijie Luo, Zhiwei Zhang, Chengxiang Wang, Yuanchang Shi, Longwei Yin, Rutao Wang. 电化学置换反应制备石墨烯基纳米无定型锑复合阳极用于高性能钠离子电容器的构筑[J]. Acta Physico-Chimica Sinica, ;2024, 40(5): 230601. doi: 10.3866/PKU.WHXB202306011 shu

电化学置换反应制备石墨烯基纳米无定型锑复合阳极用于高性能钠离子电容器的构筑

Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials, Ministry of Education, School of Materials Science and Engineering, Shandong University, Jinan 250061, China

Received Date: 5 June 2023
Revised Date: 2 July 2023
Accepted Date: 10 July 2023

Fund Project: The project was supported by the National Natural Science Foundation of China (52272224, 5190218), the Innovation Capacity Improvement Project of Small and Medium-Sized Technology-Based Enterprise of Shandong Province (2021TSGC1149), and the Youth Innovation Team Project of Shandong Provincial Education Department (10000082295015).

锑(Sb)，因其具有较高的理论比容量(660 mAh·g^-1)、较低储钠电位(0.5–0.8 V vs. Na/Na⁺)和较高的密度(6.68 g·cm^-3)等特点，被认为是一种理想的钠离子电容器的阳极材料。然而，在Na⁺脱嵌过程中，Sb电极会发生较大的体积变化，导致其容量快速衰减以及倍率性能变差，阻碍了Sb电极的实际应用。因此，本文提出一种可用于制备锚定在具有碳涂层的二维石墨烯表面的无定型Sb纳米颗粒的电化学置换方法。所制备Sb/石墨烯复合材料具有典型的二维复合结构，可大幅增加与电解液界面接触面积，缩短离子扩散路径，促进离子迁移与电子转移。进一步利用该复合材料作为阳极，自制活性炭作为阴极，构建出一种新型钠离子电容器。研究证实，该钠离子电容器工作电压可达4.0 V，可输出140.75 Wh·kg^-1的最大能量密度和12.43 kW·kg^-1的最高功率密度。综上，该研究结果可为钠离子储能器件用高容量锑基阳极材料的优化设计提供可借鉴的思路。
- Graphene,
- Sb anode,
- Galvanic replacement reaction,
- 2D composite,
- Sodium-ion capacitor
1. [1]
  (1) Vaalma, C.; Buchholz, D.; Weil, M.; Passerini, S. Nat. Rev. Mater. 2018, 3, 18013. doi: 10.1038/natrevmats.2018.13
2. [2]
  (2) Chayambuka, K.; Mulder, G.; Danilov, D. L.; Notten, P. H. L. Adv. Energy Mater. 2020, 10, 2001310. doi: 10.1002/aenm.202001310
3. [3]
  (3) Zhang, Z. H.; Gu, Z. H.; Zhang, C. G.; Li, J. B.; Wang, C. Y. Batteries Supercaps 2021, 4, 1680. doi: 10.1002/batt.202100042
4. [4]
  (4) Cai, P.; Zou, K. Y.; Deng, X. L.; Wang, B. W.; Zheng, M.; Li, L. H.; Hou, H. S.; Zou, G. Q.; Ji, X. B. Adv. Energy Mater. 2021, 11, 2003804. doi: 10.1002/aenm.202003804
5. [5]
  (5) Wang, H. W.; Zhu, C. R.; Chao, D. L.; Yan, Q. Y.; Fan, H. J. Adv. Mater. 2017, 29, 1702093. doi: 10.1002/adma.201702093
6. [6]
  (6) Chang, X. Q.; Huang, T. Y.; Yu, J. Y.; Li, J. B.; Wang, J.; Wei, Q. L. Batteries Supercaps 2021, 4, 1567. doi: 10.1002/batt.202100043
7. [7]
  (7) Ding, J.; Hu, W. B.; Paek, E.; Mitlin, D. Chem. Rev. 2018, 118, 6457. doi: 10.1021/acs.chemrev.8b00116
8. [8]
  (8) Zhu, C. Y.; Yu, W. Q.; Zhang, S. X.; Chen, J. C.; Liu, Q. Y.; Li, Q. Y.; Wang, S. J.; Hua, M. H.; Lin, X. H.; Yin, L. W.; et al. Adv. Mater. 2023, 35, 2211611. doi: 10.1002/adma.202211611
9. [9]
  (9) Yu, W. Q.; Zhu, C. Y.; Wang, R. T.; Chen, J. C.; Liu, Q. Y.; Zhang, S. X.; Zhang, S. B.; Sun, J. F.; Yin, L. W. Energy Environ. Mater. 2023, 6, 12337. doi: 10.1002/eem2.12337
10. [10]
  (10) Zhang, H.; Hasa, I.; Passerini, S. Adv. Energy Mater. 2018, 8, 1702582. doi: 10.1002/aenm.201702582
11. [11]
  (11) Lao, M. M.; Zhang, Y.; Luo, W. B.; Yan, Q. Y.; Sun, W. P.; Dou, S. X. Adv. Mater. 2017, 29, 1700622. doi: 10.1002/adma.201700622
12. [12]
  (12) Hou, H. S.; Qiu, X. Q.; Wei, W. F.; Zhang, Y.; Ji, X. B. Adv. Energy Mater. 2017, 7, 1602898. doi: 10.1002/aenm.201602898
13. [13]
  (13) Yu, W. Q.; Zhu, C. Y.; Wang, R. T.; Chen, J. C.; Liu, Q. Y.; Zhang, S. X.; Gao, Z. J.; Wang, C. X.; Zhang, Z. W.; Yin, L. W. Rare Metals 2022, 41, 3360. doi: 10.1007/s12598-022-02015-z
14. [14]
  (14) Yin, J.; Qi, L.; Wang, H. Y. ACS Appl. Mater. Interfaces 2012, 4, 2762. doi: 10.1021/am300385r
15. [15]
  (15) Yuan, J.; Qiu, M.; Hu, X.; Liu, Y. J.; Zhong, G. B.; Zhan, H. B.; Wen, Z. H. ACS Nano 2022, 16, 14807. doi: 10.1021/ acsnano.2c05662
16. [16]
  (16) Ma, Y.; Zhang, L. Y.; Yan, Z. X.; Cheng, B.; Yu, J. G.; Liu, T. Adv. Energy Mater. 2022, 12, 2103820. doi: 10.1002/aenm. 202103820
17. [17]
  (17) Liu, C.; Zhang, M. X.; Zhang, X.; Wan, B.; Li, X. N.; Gou, H. Y.; Wang, Y. X. Yin, F. X.; Wang, G. K. Small 2020, 16, 2004457. doi: 10.1002/smll.202004457
18. [18]
  (18) Zhao, R. Z.; Di, H. X.; Wang, C. X.; Hui, X. B.; Zhao, D. Y.; Wang, R. T.; Zhang, L. Y.; Yin, L. W. ACS Nano 2020, 14, 13938. doi: 10.1021/acsnano.0c06360.
19. [19]
  (19) Li, Q. H.; Zhang, W.; Peng, J.; Zhang, W.; Liang, Z. X.; Wu, J. W.; Feng, J. J.; Li, H. X.; Huang, S. M. ACS Nano 2021, 15, 15104. doi: 10.1021/acsnano.1c05458
20. [20]
  (20) Yang, K. X.; Tang, J. F.; Liu, Y.; Kong, M.; Zhou, B.; Shang, Y. C.; Zhang, W. H. ACS Nano 2020, 14, 5728. doi: 10.1021/acsnano.0c00366
21. [21]
  (21) Liu, Z. M.; Yu, X. Y.; Lou, X. W.; Paik, U. Energy Environ. Sci. 2016, 9, 2314. doi:10.1039/c6EE01501H
22. [22]
  (22) He, M.; Kravchyk, K.; Walter, M.; Kovalenko, M. V. Nano Lett. 2014, 14, 1255. doi: 10.1021/nl404165c
23. [23]
  (23) Liu, J.; Yu, L. T.; Wu, C.; Wen, Y. R.; Yin, K. B.; Chiang, F. K.; Hu, R. Z.; Liu, J. W.; Sun, L. T.; Gu, L.; et al. Nano Lett. 2017, 17, 2034. doi: 10.1021/acs. nanolett.7b00083
24. [24]
  (24) Liu, Y.; Zhou, B.; Liu, S.; Ma, Q. S.; Zhang, W. H. ACS Nano 2019, 13, 5885. doi: 10.1021/acsnano. 9b01660
25. [25]
  (25) Hou, Z. G.; Zhang, X. Q.; Chen, J. W.; Qian, Y. T.; Chen, L. F.; Lee, P. S. Adv. Energy Mater. 2022, 12, 210453. doi: 10.1002/aenm.202104053
26. [26]
  (26) Bi, X. Y.; Li, M. C.; Zhou, G. Q.; Liu, C. Z.; Huang, R. Z.; Shi, Y.; Xu, B. B.; Guo, Z. H.; Fan, W.; Algadi, H.; et al. Nano Res. 2023, 16, 7696. doi: 10.1007/s12274-023-5586-1
27. [27]
  (27) Duan, J.; Zhang, W.; Wu, C.; Fan, Q. J.; Zhang, W. X.; Hu, X. L.; Huang, Y. H. Nano Energy 2015, 16, 479. doi: 10.1016/j.nanoen.2015.07.021
28. [28]
  (28) Xiao, B.; Sun, Z.; Zhang, H.; Wu, Y.; Li, J.; Cui, J.; Han, J.; Li, M.; Zheng, H.; Chen, J.; et al. Energy Environ. Sci. 2023, 16, 2153. doi: 10.1039/D2EE03970B
29. [29]
  (29) Li, H. M.; Wang, K. L.; Zhou, M.; Li, W.; Tao, H. W.; Wang, R. X.; Cheng, S. J.; Jiang, K. ACS Nano 2019, 13, 9533. doi: 10.1021/acsnano.9b04520
30. [30]
  (30) Chen, B. C.; Qin, H. Y.; Li, K.; Zhang, B.; Liu, E. Z.; Zhao, N. Q.; Shi, C. S.; He, C. N. Nano Energy 2019, 66, 104133. doi: 10.1016/j.nanoen.2019.104133
31. [31]
  (31) Guo, X.; Gao, H.; Wang, S. J.; Yang, G.; Zhang, X. Y.; Zhang, J. Q.; Liu, H.; Wang, G. X. Nano Lett. 2022, 22, 1225. doi: 10.1021/acs.nanolett.1c04389
32. [32]
  (32) Dong, W. X.; Qu, Y. F.; Liu, X.; Chen, L. F. Flatchem 2023, 37, 100467. doi: 10.1016/j.flatc.2022.100467
33. [33]
  (33) Yao, J. J.; Li, F. Z.; Zhou, R. Y.; Guo, C. C.; Liu, X. R.; Zhu, Y. R.; Chin. Chem. Lett. 2023, 108354. doi: 10.1016/j.cclet.2023.108354
34. [34]
35. [35]
  (35) Shao, M. J.; Li, C. X.; Li, T.; Yu, W. Q.; Wang, R. T.; Zhang, J.; Yin, L. W. Adv. Funct. Mater. 2020, 30, 2006561. doi: 10.1002/adfm.202006561
36. [36]
  (36) Tang, T.; Jiang, W. J.; Liu, X. Z.; Deng, J.; Niu, S.; Wang, B.; Jin, S. F.; Zhang, Q.; Gu, L.; Hu, J. S.; et al. J. Am. Chem. Soc. 2020, 142, 7116. doi: 10.1021/jacs.0c01349
37. [37]
  (37) Pu, B.; Liu, Y.; Bai, J.; Chu, X.; Zhou, X. F.; Qing, Y.; Wang, Y. B.; Zhang, M. Z.; Ma, Q. S.; Xu, Z.; et al. ACS Nano 2022, 16, 18746. doi: 10.1021/acsnano.2c07472
38. [38]
  (38) Chen, Z.; Augustyn, V.; Jia, X. L.; Xiao, Q. F.; Dunn, B.; Lu, Y. F. ACS Nano 2012, 6, 4319. doi: 10.1021/nn300920e
39. [39]
  (39) Kirubasankar, B.; Vijayan, S.; Angaiah, S. Sustain. Energy Fuels 2019, 3, 467. doi: 10.1039/C8SE00446C
40. [40]
  (40) Li, H, X.; Lang, S. L.; Chen, J. T.; Wang, K. J.; Liu, L. Y.; Zhang, T. Y.; Liu, W. S.; Yan, X. B. Adv. Funct. Mater. 2018, 28, 1800757. doi: 10.1002/adfm.201800757
41. [41]
  (41) Fan, Z. D.; Wei, C. H.; Yu, L. H.; Xia, Z.; Cai, J. S.; Tian, Z. N.; Zou, G. F.; Dou, S. X.; Sun, J. Y. ACS Nano 2020, 14, 867. doi: 10.1021/acsnano.9b08030
42. [42]
  (42) Wang, S. J.; Wang, R. T.; Zhang, Y. B.; Jin, D. D.; Zhang, L. J. Power Sources 2018, 379, 33. doi: 10.1016/j.jpowsour.2018.01.019
43. [43]
  (43) Dong, S. Y.; Shen, L. F.; Li, H. S.; Pang, G.; Dou, H.; Zhang, X.G. Adv. Funct. Mater. 2016, 26, 3703. doi: 10.1002/adfm.201600264
44. [44]
  (44) Gao, J. Y.; Li, Y. P.; Liu, Y.; Jiao, S. H.; Li, J.; Wang, G. R.; Zeng, S. Y.; Zhang, G. Q. J. Mater. Chem. A 2019, 7, 10028. doi: 10.1039/C9TA05666A
45. [45]
  (45) Chao, H. X.; Qin, H. Q.; Zhang, M. D.; Huang, Y. C.; Gao, L. F.; Gu, H. L.; Wang, K.; Teng, X. L.; Cheng, J. K.; Lu, Y. K.; et al. Adv. Funct. Mater. 2021, 31, 2007636. doi: 10.1002/adfm.20200636
46. [46]
  (46) Le, Z. Y.; Liu, F.; Nie, P.; Li, X. R.; Liu, X. Y.; Bian, Z. F.; Chen, G.; Wu, H. B.; Lu, Y. F. ACS Nano 2017, 11, 2952. doi: 10.1021/acsnano.6b08332
47. [47]
  (47) Song, Z. R.; Zhang, G. Y.; Deng, X. L.; Tian, Y.; Xiao, X. H.; Deng, W. T.; Hou, H. S.; Zou, G. Q.; Ji, X. B. Adv. Funct. Mater. 2022, 32, 2205453. doi: 10.1002/ adfm.202205453
48. [48]
  (48) Liu, Q. Y.; Chen, J. C.; Du, D. N.; Zhang, S. X.; Zhu, C. Y.; Zhang, Z. W.; Wang, C. X.; Yin, L. W.; Wang, R. T. J. Mater. Chem. A 2023, doi: 10.1039/D3TA01098H
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