Citation: Chaolin Mi, Yuying Qin, Xinli Huang, Yijie Luo, Zhiwei Zhang, Chengxiang Wang, Yuanchang Shi, Longwei Yin, Rutao Wang. 电化学置换反应制备石墨烯基纳米无定型锑复合阳极用于高性能钠离子电容器的构筑[J]. Acta Physico-Chimica Sinica, ;2024, 40(5): 230601. doi: 10.3866/PKU.WHXB202306011 shu

电化学置换反应制备石墨烯基纳米无定型锑复合阳极用于高性能钠离子电容器的构筑

Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials, Ministry of Education, School of Materials Science and Engineering, Shandong University, Jinan 250061, China

Received Date: 5 June 2023
Revised Date: 2 July 2023
Accepted Date: 10 July 2023

Fund Project: The project was supported by the National Natural Science Foundation of China (52272224, 5190218), the Innovation Capacity Improvement Project of Small and Medium-Sized Technology-Based Enterprise of Shandong Province (2021TSGC1149), and the Youth Innovation Team Project of Shandong Provincial Education Department (10000082295015).

锑(Sb)，因其具有较高的理论比容量(660 mAh·g^-1)、较低储钠电位(0.5–0.8 V vs. Na/Na⁺)和较高的密度(6.68 g·cm^-3)等特点，被认为是一种理想的钠离子电容器的阳极材料。然而，在Na⁺脱嵌过程中，Sb电极会发生较大的体积变化，导致其容量快速衰减以及倍率性能变差，阻碍了Sb电极的实际应用。因此，本文提出一种可用于制备锚定在具有碳涂层的二维石墨烯表面的无定型Sb纳米颗粒的电化学置换方法。所制备Sb/石墨烯复合材料具有典型的二维复合结构，可大幅增加与电解液界面接触面积，缩短离子扩散路径，促进离子迁移与电子转移。进一步利用该复合材料作为阳极，自制活性炭作为阴极，构建出一种新型钠离子电容器。研究证实，该钠离子电容器工作电压可达4.0 V，可输出140.75 Wh·kg^-1的最大能量密度和12.43 kW·kg^-1的最高功率密度。综上，该研究结果可为钠离子储能器件用高容量锑基阳极材料的优化设计提供可借鉴的思路。
- Graphene,
- Sb anode,
- Galvanic replacement reaction,
- 2D composite,
- Sodium-ion capacitor
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